N,N'-dihydromethylorange | 26363-66-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dihydromethylorange
• 英文别名: methylene orange；Sodium;4-[2-[4-(dimethylamino)phenyl]hydrazinyl]benzenesulfonate
• CAS: 26363-66-6
• 化学式: C₁₄H₁₆N₃O₃S*Na
• 分子量: 329.355
• InChiKey: RPOXHQJPUSXDJA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  92.9
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  methyl orange 在 镍 、 维生素 C 作用下， 反应 0.06h， 生成 N,N'-dihydromethylorange
  参考文献：
  名称：

  镍纳米粒子作为电子转移反应的有效催化剂

  摘要：

  在一些电子转移反应中研究了镍纳米颗粒的催化效率。纳米粒子在室温下以高化学选择性在水性介质中快速还原许多硝基芳烃，还有助于加速 Fe(CN)6-3 和 S2O3-2 的氧化还原反应。此外，偶氮染料的微波辅助脱色也获得了有趣的结果。通过紫外-可见光谱监测反应。本研究具有催化剂和水性介质可重复使用性的额外优势。最终目标是评估低成本纳米催化剂在水性条件下进行电子转移反应的适用性。图形摘要

  DOI：

  10.1007/s10562-013-1168-2

文献信息

• A novel approach using plant embryos for green synthesis of silver nanoparticles as antibacterial and catalytic agent
  作者：Minh-Trong Tran、Linh-Phuong Nguyen、Dinh-Truong Nguyen、T. Le Cam-Huong、Chi-Hien Dang、Tran Thi Kim Chi、Thanh-Danh Nguyen

  DOI：10.1007/s11164-021-04548-x

  日期：2021.11

  The plant extract has been used extensively for biosynthesis of noble metallic nanoparticles due to cost efficiency and simple technology. However, influence of plant growth condition can induce changes in composition and content of bioactive compounds, leading to difficulty in reproducing the metallic nanoparticles. In this work, we first utilized the plant embryos (Panax vietnamensis embryos—PVE)

  由于成本效益和技术简单，植物提取物已被广泛用于贵金属纳米粒子的生物合成。然而，植物生长条件的影响会导致生物活性化合物的组成和含量发生变化，导致金属纳米颗粒的再生困难。在这项工作中，我们首先利用植物胚胎（Panax vietnamensis在实验室条件下培养的胚胎 - PVE）作为合成银纳米粒子 (AgNPs) 的生物来源。这种方法可以减少植物中生物活性成分的不必要变化。优化 AgNPs 的形成以提供最好的胶体溶液。使用包括X射线衍射(XRD)、透射电子显微镜(TEM)、选区电子衍射(SAED)、傅里叶变换红外光谱(FTIR)和热性能在内的分析技术表征理化性质。结晶 AgNPs 的尺寸在 3-20 nm 范围内确定，平均尺寸为 10 nm。研究了应用的抗菌和催化作用。生物合成的 AgNPs 对枯草芽孢杆菌表现出很高的抗菌活性，金黄色葡萄球菌和大肠杆菌。研究了 PVE-AgNPs 在还原邻、间
• Facile Transfer Hydrogenation of Azo Compounds to Hydrazo Compounds and Anilines by Using Raney Nickel and Hydrazinium Monoformate
  作者：H. S. Prasad、Shankare Gowda、D. Channe Gowda

  DOI：10.1081/scc-120027231

  日期：2004.12.31

  Abstract Azo compounds are conveniently reduced to either partially reduced hydrazo compounds or completely reduced anilines by employing Raney nickel in presence of hydrazinium monoformate depending upon reaction conditions. The other reducible moieties like ‒COOH and halogens are tolerated. The reduction process is selective, rapid and high yielding.

  摘要 根据反应条件，通过在单甲酸肼鎓存在下使用雷尼镍，可以方便地将偶氮化合物还原为部分还原的偶氮化合物或完全还原的苯胺。可以容忍其他可还原部分，如 ‒COOH 和卤素。还原过程具有选择性、快速和高产。
• Nickel Nanoparticles as Efficient Catalyst for Electron Transfer Reactions
  作者：Puran Singh Rathore、Rajesh Patidar、Sonika Rathore、Sonal Thakore

  DOI：10.1007/s10562-013-1168-2

  日期：2014.3

  was investigated in some electron transfer reactions. The nanoparticles brought about rapid room temperature reduction of a number of nitro aromatics in an aqueous medium with high chemoselectivity and also helped to speed up redox reaction of Fe(CN)6−3 and S2O3−2. In addition, interesting results were obtained for microwave assisted decolourization of azo dye. The reactions were monitored through UV–Vis

  在一些电子转移反应中研究了镍纳米颗粒的催化效率。纳米粒子在室温下以高化学选择性在水性介质中快速还原许多硝基芳烃，还有助于加速 Fe(CN)6-3 和 S2O3-2 的氧化还原反应。此外，偶氮染料的微波辅助脱色也获得了有趣的结果。通过紫外-可见光谱监测反应。本研究具有催化剂和水性介质可重复使用性的额外优势。最终目标是评估低成本纳米催化剂在水性条件下进行电子转移反应的适用性。图形摘要
• A Simple but Efficient Catalytic Approach for the Degradation of Pollutants in Aqueous Media through <i>Cicer arietinum</i> Supported Ni Nanoparticles
  作者：Shahid Ali Khan、Shagufta Rasool、Khaliq Ur Rahman、Shah Hussain、Inamullah Khan、Muhammad Ismail、Aliya Farooq、Sarzamin Khan、Mian Ahmad Raza、Abdullah Muhammad Asiri、Sher Bahadar Khan

  DOI：10.1515/zpch-2018-1297

  日期：2020.12.16

  Plant based materials are considered to have broad applications in the remediation of toxic materials. In this report, we present an environmental friendly and economic Cicer arietinum, named as (CP) supported for the synthesis of Ni nanoparticles (NPs) designated as Ni@CP. The in situ Ni@CP NPs were obtained using aqueous medium in the presence of sodium borohydride (NaBH₄) as a reducing agent. The prepared catalysts were applied for the hydrogenation/degradation of p-nitrophenol (PNP), o-nitrophenol (ONP), and 2,4-dinitrophenol (DNP), as well as congo red (CR), methyl orange (MO), methylene blue (MB) and rhodamine B (RB) dyes. The amount of total metal ions adsorbed onto the CP was evaluated by flame atomic absorption spectroscopy. The Ni@CP catalyst was characterized through PXRD, FTIR, FESEM and EDX analyses.

  植物基材料被认为在有毒材料的修复中具有广泛的应用。在这份报告中，我们介绍了一种环保和经济的鹰嘴豆（CP），用于合成被命名为Ni纳米颗粒（NPs）的Ni@CP。通过在水介质中存在硼氢化钠（NaBH4）作为还原剂，获得了原位Ni@CP NPs。制备的催化剂被应用于对对硝基苯酚（PNP）、邻硝基苯酚（ONP）和2,4-二硝基苯酚（DNP）以及刚果红（CR）、甲基橙（MO）、亚甲基蓝（MB）和罗丹明B（RB）染料的加氢/降解。通过火焰原子吸收光谱法评估了吸附到CP上的总金属离子量。Ni@CP催化剂通过PXRD、FTIR、FESEM和EDX分析进行表征。
• Magnetically Recyclable Fe&lt;SUB&gt;3&lt;/SUB&gt;O&lt;SUB&gt;4&lt;/SUB&gt;@His@Cu Nanocatalyst for Degradation of Azo Dyes
  作者：U. Kurtan、Md. Amir、A. Baykal、H. Sözeri、M. S. Toprak

  DOI：10.1166/jnn.2016.11707

  日期：2016.3.1

  Fe3O4@His@Cu magnetic recyclable nanocatalyst (MRCs) was synthesized by reflux method using L-histidine as linker. The composition, structure and magnetic property of the product were characterized by X-ray powder diffraction (XRD), Scanning electron microscopy (SEM), Fourier Transform infrared spectroscopy (FT-IR) and vibrating sample magnetometry (VSM). Powder XRD, FTIR and EDAX results confirmed that the as-synthesized products has Fe3O4 with spinel structure and Cu nanoparticles with moderate crystallinity without any other impurities. The surface of the Fe3O4@His nanocomposite was covered by tiny Cu nanoparticles.We examine the catalytic activity of Fe3O4@His@Cu MRCs for the degradation of two azo dyes, methyl orange (MO) and methylene blue (MB) as well as their mixture. The reusability of the nanocatalyst was good and sustained even after 3 cycles. Therefore this innovated Fe3O4@His@Cu MRCs has a potential to be used for purification of waste water.

  Fe3O4@His@Cu磁性可回收纳米催化剂（MRCs）通过回流法合成，使用L-组氨酸作为连接剂。通过X射线粉末衍射（XRD）、扫描电子显微镜（SEM）、傅里叶变换红外光谱（FT-IR）和振动样品磁强计（VSM）对产品的成分、结构和磁性进行了表征。粉末XRD、FTIR和EDAX结果证实，合成的产品具有尖晶石结构的Fe3O4和中等结晶度的Cu纳米颗粒，且没有其他杂质。Fe3O4@His纳米复合材料的表面覆盖着微小的Cu纳米颗粒。我们考察了Fe3O4@His@Cu MRCs在降解两种偶氮染料（橙色甲基染料（MO）和美蓝（MB））及其混合物的催化活性。该纳米催化剂的重复使用性良好，即便经过3个循环后仍然保持。因此，这种创新的Fe3O4@His@Cu MRCs具有用于废水净化的潜力。