(6-chlorohexyl)diphenylphosphine oxide | 1123881-19-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (6-chlorohexyl)diphenylphosphine oxide
• 英文别名: (6-chloro-n-hex-1-yl)diphenylphosphine oxide；[6-Chlorohexyl(phenyl)phosphoryl]benzene
• CAS: 1123881-19-5
• 化学式: C₁₈H₂₂ClOP
• 分子量: 320.799
• InChiKey: JADNXABYIGHUOP-UHFFFAOYSA-N

物化性质

• 沸点：
  425.0±28.0 °C(predicted)
• 密度：
  1.12±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  6-氯-1-己烯 、 Diphenylphosphine oxide 以99%的产率得到(6-chlorohexyl)diphenylphosphine oxide
  参考文献：
  名称：

  Photoinduced hydrophosphinylation of alkenes with diphenylphosphine oxide

  摘要：

  Photoinduced hydrophosphinylation of alkenes with diphenylphosphine oxide took place regioselectively affording the corresponding phosphine oxide in good yields. This hydrophosphinylation is of simple operation and widely tolerant to a variety of the functionalities. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.11.079

文献信息

• Photoinduced hydrophosphinylation of alkenes with diphenylphosphine oxide
  作者：Shin-ichi Kawaguchi、Akihiro Nomoto、Motohiro Sonoda、Akiya Ogawa

  DOI：10.1016/j.tetlet.2008.11.079

  日期：2009.2

  Photoinduced hydrophosphinylation of alkenes with diphenylphosphine oxide took place regioselectively affording the corresponding phosphine oxide in good yields. This hydrophosphinylation is of simple operation and widely tolerant to a variety of the functionalities. (C) 2008 Elsevier Ltd. All rights reserved.
• Al³⁺ Dopants Induced Mg²⁺ Vacancies Stabilizing Single-Atom Cu Catalyst for Efficient Free-Radical Hydrophosphinylation of Alkenes
  作者：Qi Xu、Chenxi Guo、Beibei Li、Zedong Zhang、Yajun Qiu、Shubo Tian、Lirong Zheng、Lin Gu、Wensheng Yan、Dingsheng Wang、Jian Zhang

  DOI：10.1021/jacs.2c01456

  日期：2022.3.16