bis(trimethylsiloxyethyl)phenylamine | 113849-59-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(trimethylsiloxyethyl)phenylamine
• 英文别名: N,N-Bis{2-[(trimethylsilyl)oxy]ethyl}aniline；N,N-bis(2-trimethylsilyloxyethyl)aniline
• CAS: 113849-59-5
• 化学式: C₁₆H₃₁NO₂Si₂
• 分子量: 325.599
• InChiKey: FSPFOBQRWZUFAU-UHFFFAOYSA-N

物化性质

• 沸点：
  144-145 °C(Press: 1 Torr)
• 密度：
  0.947±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  21
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  正硅酸甲酯 、 bis(trimethylsiloxyethyl)phenylamine 在 sodium methylate 作用下， 以 甲醇 为溶剂， 以36%的产率得到4,12-diphenyl-1,7,9,15-tetraoxa-4,12-diaza-8-silaspiro<7,7>pentadecane
  参考文献：
  名称：

  Urtane, I. P.; Zelchan, G. I.; Lukevits, E., Journal of general chemistry of the USSR, 1988, vol. 58, # 9, p. 1902 - 1910

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-二羟乙基苯胺 、 六甲基二硅氮烷 反应 9.0h， 以87%的产率得到bis(trimethylsiloxyethyl)phenylamine
  参考文献：
  名称：

  The transannular interaction germanium–nitrogen in germocanes: The influence of substituents

  摘要：

  The reaction of RN(CH2CH2OH)(CHRCRROH)-C-1-R-2-O-3 (1-8) with a stoichiometric amount of tetrachloro(bromo)germane leads to the corresponding RN(CH2CH2O)((CHRCRRO)-C-1-R-2-O-3)GeHal(2) (9-21). Difluorenylgermocane 22 was prepared by treatment of diethoxydifluorenylgermane with N-methyldiethanolamine. Different dialkanolamines were found to be successive precursors of dimethylgermocanes, RN(CH2CH2O)((CHRCRRO)-C-1-R-2-O-3)GeMe2 (23-26). The chemical properties of simple and easy to access germocanes RN(CH2CH2O)(2)GeX2 [X=OH, Br (28), Cl (29)] were studied and the difluoro (27), haloalkoxy (30-32), and dialkoxy (33, 34) derivatives were prepared. The structures of the compounds 16, 20-22, and 26 were confirmed by X-ray diffraction and the structural features in solution of 23 and 26 were studied by NMR spectroscopy (NOES). The relationship between the nature of substituents at different positions of the germocane skeleton and the strength of the intramolecular Ge <- N bond is discussed. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.011

文献信息

• Robert, Dominique; Gawad, Hoda Abdel; Riess, Jean G., Bulletin de la Societe Chimique de France, 1987, # 3, p. 511 - 516
  作者：Robert, Dominique、Gawad, Hoda Abdel、Riess, Jean G.

  DOI：——

  日期：——
• Lermontova, Elmira Kh.; Selina, Anastasia A.; Karlov, Sergey S., Journal of Organometallic Chemistry, 2006, vol. 691, p. 5710 - 5724
  作者：Lermontova, Elmira Kh.、Selina, Anastasia A.、Karlov, Sergey S.、Churakov, Andrei V.、Howard, Judith A. K.、et al.

  DOI：——

  日期：——
• URTANE, I. P.;ZELCHAN, G. I.;LUKEVICS, E., Z. ANORG. UND ALLG. CHEM., 1985, 520, N 1, 179-195
  作者：URTANE, I. P.、ZELCHAN, G. I.、LUKEVICS, E.

  DOI：——

  日期：——
• ROBERT D.; GAWAD H. A.; RIESS J. G., BULL. SOC. CHIM. FR.,(1987) N 3, 511-516
  作者：ROBERT D.、 GAWAD H. A.、 RIESS J. G.

  DOI：——

  日期：——
• YPTAHE, I. P.;ZELCHAN, G. I.;LUKEVITS, EH.;MAZHEJKA, I. B.;GUXMAN, A. P., ZH. OBSHCH. XIMII, 58,(1988) N 9, S. 2135-2144
  作者：YPTAHE, I. P.、ZELCHAN, G. I.、LUKEVITS, EH.、MAZHEJKA, I. B.、GUXMAN, A. P.

  DOI：——

  日期：——