9-phenyl-fluoren-9-yl hydroperoxide | 101937-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-phenyl-fluoren-9-yl hydroperoxide
• 英文别名: 9-Phenyl-fluoren-9-ylhydroperoxid；9-Hydroperoxy-9-phenyl-fluoren；9-Hydroperoxy-9-phenylfluorene
• CAS: 101937-03-5
• 化学式: C₁₉H₁₄O₂
• 分子量: 274.319
• InChiKey: NINXVPIRPCZVEF-UHFFFAOYSA-N

物化性质

• 熔点：
  53-55 °C
• 沸点：
  452.5±45.0 °C(Predicted)
• 密度：
  1.29±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-phenyl-fluoren-9-yl hydroperoxide 在 硫酸 、 溶剂黄146 作用下， 生成 bis(9-phenyl-9-fluorenyl) peroxide
  参考文献：
  名称：

  Bassey et al., Journal of the Chemical Society, 1955, p. 2550

  摘要：

  DOI：
• 作为产物：
  描述：

  9-苯基芴 在 氧气 、 苄基三甲基氢氧化铵 作用下， 以 吡啶 为溶剂， 生成 9-phenyl-fluoren-9-yl hydroperoxide
  参考文献：
  名称：

  一种新的6-苯基-和6-邻甲苯基-二苯并[ b，d ]高氯酸吡啶酯的合成

  摘要：

  通过9-氢过氧化物的酸催化重排，将9-苯基-和9-邻甲苯基芴分别转化为6-苯基-和6-邻甲苯基-二苯并[ b，d ]高氯酸吡啶鎓。

  DOI：

  10.1039/j39690000361

文献信息

• A novel synthesis of 6-phenyl- and 6-o-tolyl-dibenzo[b,d]pyrylium perchlorates
  作者：C. C. Barker

  DOI：10.1039/j39690000361

  日期：——

  9-Phenyl- and 9-o-tolyl-fluorene are converted into 6-phenyl- and 6-o-tolyl-dibenzo[b,d]pyrylium perchlorates, respectively, by acid-catalysed rearrangement of the 9-hydroperoxides.

  通过9-氢过氧化物的酸催化重排，将9-苯基-和9-邻甲苯基芴分别转化为6-苯基-和6-邻甲苯基-二苯并[ b，d ]高氯酸吡啶鎓。
• Reactions of Active Methylene Compounds in Pyridine Solution. I. The Ionic Autoxidation of Fluorene and its Derivatives¹
  作者：Yaër Sprinzak

  DOI：10.1021/ja01553a033

  日期：1958.10
• [EN] METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS<br/>[FR] CATALYSEURS DE MÉTATHÈSE ET RÉACTIONS UTILISANT LES CATALYSEURS
  申请人：XIMO AG

  公开号：WO2014139679A2

  公开（公告）日：2014-09-18

  The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1 : 500 or less, and the conversion of the first or the second olefin to said olefin is at least 50 %, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6-X-, wherein X = O and R6 is aryl, optionally substituted; or X = S and R6 is aryl, optionally substituted; or X = O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X = O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
• Bassey et al., Journal of the Chemical Society, 1955, p. 2550
  作者：Bassey et al.

  DOI：——

  日期：——
• GLOVER, S. A.;GOOSEN, A.;MCCLELAND, C. W.;TALJAARD, B.;VOGEL, F. R., S. AFR. J. CHEM., 1985, 38, N 4, 203-206
  作者：GLOVER, S. A.、GOOSEN, A.、MCCLELAND, C. W.、TALJAARD, B.、VOGEL, F. R.

  DOI：——

  日期：——