Perfluor-2,2'-dichlor-triethylamin | 63419-66-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Perfluor-2,2'-dichlor-triethylamin
• 英文别名: N,N-bis(2-chloro-1,1,2,2-tetrafluoroethyl)-1,1,2,2,2-pentafluoroethanamine
• CAS: 63419-66-9
• 化学式: C₆Cl₂F₁₃N
• 分子量: 403.958
• InChiKey: UCDFEZZRDRIQDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  N,N-二乙基(2-氯-1,1,2-三氟乙基)胺 在 氢氟酸 作用下， 以7.3 mol的产率得到全氟三乙胺
  参考文献：
  名称：

  Mechanistic studies on the electrochemical fluorination of trialkylamines and tetraalkylammonium salts

  摘要：

  The comparative electrochemical fluorination (ECF) of selected trialkylamines and tetraalkylammonium salts was studied in order to obtain experimental data allowing a precise valuation of the ECF mechanism. The results of the investigation favour the ECF mechanism already proposed by Simons, via oxidation of F-(HF)(n) to F- and nHF, as probably the only relevant electrochemical process at the anode. For the first time some experimental proof has been obtained that a direct electrochemical oxidation of the substrate can be ruled out as a decisive step in ECF. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-1139(96)03550-6

文献信息

• Mechanistic studies on the electrochemical fluorination of trialkylamines and tetraalkylammonium salts
  作者：A. Dimitrov、D. Pfeifer、U. Jonethal、St. Rüdiger、K. Seppelt

  DOI：10.1016/s0022-1139(96)03550-6

  日期：1997.5

  The comparative electrochemical fluorination (ECF) of selected trialkylamines and tetraalkylammonium salts was studied in order to obtain experimental data allowing a precise valuation of the ECF mechanism. The results of the investigation favour the ECF mechanism already proposed by Simons, via oxidation of F-(HF)(n) to F- and nHF, as probably the only relevant electrochemical process at the anode. For the first time some experimental proof has been obtained that a direct electrochemical oxidation of the substrate can be ruled out as a decisive step in ECF. (C) 1997 Elsevier Science S.A.