biphenyl-4,4'-disulfinic acid | 54076-87-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: biphenyl-4,4'-disulfinic acid
• 英文别名: Biphenyl-4,4'-disulfinsaeure；4-(4-Sulfinophenyl)benzenesulfinic acid
• CAS: 54076-87-8
• 化学式: C₁₂H₁₀O₄S₂
• 分子量: 282.341
• InChiKey: DCSRNHDTEKWRHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  113
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4,4'-联苯二磺酰氯 在 sodium hydroxide 、 sodium sulfite 作用下， 以 水 为溶剂， 反应 1.0h， 以87%的产率得到biphenyl-4,4'-disulfinic acid
  参考文献：
  名称：

  Alov; Nikiforov; Novikov, Russian Journal of Organic Chemistry, 1998, vol. 34, # 8, p. 1160 - 1164

  摘要：

  DOI：

文献信息

• Barber; Smiles, Journal of the Chemical Society, 1928, p. 1148
  作者：Barber、Smiles

  DOI：——

  日期：——
• 4,4'-Bis-(beta-hydroxyethylsulfonyl)-diphenyl und dessen Ester sowie Verfahren zu ihrer Herstellung
  申请人：HOECHST AKTIENGESELLSCHAFT

  公开号：EP0175983B1

  公开（公告）日：1989-08-02
• US4659856A
  申请人：——

  公开号：US4659856A

  公开（公告）日：1987-04-21
• US4672136A
  申请人：——

  公开号：US4672136A

  公开（公告）日：1987-06-09
• [EN] ADSORPTION AND DESORPTION APPARATUS<br/>[FR] APPAREIL D'ADSORPTION ET DE DÉSORPTION
  申请人：COMMW SCIENT IND RES ORG

  公开号：WO2020113281A1

  公开（公告）日：2020-06-11

  An adsorption apparatus and associated method for capturing an target gaseous adsorbate from an atmospheric air based gaseous feed stream. The adsorption apparatus comprises: a housing enclosing at least one adsorption element for adsorbing the target gaseous adsorbate, the at least one adsorption element comprising at least one substrate coated with an adsorptive composite coating that comprises at least 50 wt% metal organic framework and at least one binder, the housing having an inlet through which the gaseous feed stream can flow to the adsorption element and an outlet through which gas can flow out from the housing; and a desorption arrangement in contact with and/or surrounding the at least one adsorption element, the desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to heat, apply a reduced pressure or a combination thereof to the adsorptive composite coating to desorb at least a portion of the adsorbed target gaseous adsorbate from the adsorptive composite coating.