2,2-Dimethyl-3-(2-phenyl-vinyl)-cyclopropanecarboxylic acid ethyl ester | 62217-59-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-Dimethyl-3-(2-phenyl-vinyl)-cyclopropanecarboxylic acid ethyl ester
• 英文别名: Ethyl 2,2-dimethyl-3-(β-phenylvinyl)-cyclopropanecarboxylate；3-Styryl-2,2-dimethylcyclopropancarbonsaeureethylester；ethyl 2,2-dimethyl-3-[(E)-2-phenylethenyl]cyclopropane-1-carboxylate
• CAS: 62217-59-8；66476-91-3；66476-92-4
• 化学式: C₁₆H₂₀O₂
• 分子量: 244.334
• InChiKey: XSAJYMAJZHKKMK-ZHACJKMWSA-N

物化性质

• 沸点：
  320.1±31.0 °C(Predicted)
• 密度：
  1.091±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2-Dimethyl-3-(2-phenyl-vinyl)-cyclopropanecarboxylic acid ethyl ester 在 盐酸 、 sodium hydroxide 作用下， 以 乙醚 、 乙醇 、 水 、 苯 为溶剂， 生成 2,2-dimethyl-3-(β-phenylvinyl)-cyclopropanecarboxylic acid
  参考文献：
  名称：

  Insecticidal (.beta.-phenylvinyl)cyclopropanecarboxylates

  摘要：

  描述了一种新的杀虫剂(.beta.-苯基乙烯基)环丙烷羧酸酯，阐述了它们的制备和杀虫效用。

  公开号：

  US04157397A1
• 作为产物：
  描述：

  苄基三苯基氯化膦 在 正丁基锂 作用下， 以 正己烷 、 苯 为溶剂， 生成 2,2-Dimethyl-3-(2-phenyl-vinyl)-cyclopropanecarboxylic acid ethyl ester
  参考文献：
  名称：

  Insecticidal (.beta.-phenylvinyl)cyclopropanecarboxylates

  摘要：

  描述了一种新的杀虫剂(.beta.-苯基乙烯基)环丙烷羧酸酯，阐述了它们的制备和杀虫效用。

  公开号：

  US04157397A1

文献信息

• Combating arthropods with 3-phenoxybenzyl
  申请人：Bayer Aktiengesellschaft

  公开号：US04276306A1

  公开（公告）日：1981-06-30

  3-Phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates of the formula ##STR1## in which R, R.sup.1 and R.sup.2 each independently is hydrogen or halogen, R.sup.3 is phenyl, phenylthio, or phenyl or phenylthio carrying at least one alkyl group or halogen atom, Y is hydrogen or cyano, n is 1, 2, 3, 4 or 5, and m is 1, 2, 3 or 4, which possess arthropodicidal properties.

  公式为##STR1##的3-苯氧基苄基2,2-二甲基-3-乙烯基环丙烷羧酸酯，其中R、R.sup.1和R.sup.2各自独立地是氢或卤素，R.sup.3是苯基、苯硫基、或携带至少一个烷基或卤素原子的苯基或苯硫基，Y是氢或氰基，n为1、2、3、4或5，m为1、2、3或4，具有杀虫作用。
• Process for the preparation of carboxylic acid esters
  申请人：Souda Hiroshi

  公开号：US20050113581A1

  公开（公告）日：2005-05-26

  There is provided a process for preparing a carboxylic acid ester of formula (3): R 2 COOR 1 (3) wherein R 1 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, and R 2 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted, a heteroaryl which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, which process is characterized by the steps of reacting a monohydroxy compound of formula (1): R 1 OH   (1) wherein R 1 is as defined above, with a zirconium compound of formula (6): Zr(OR 8 ) 4 (6) wherein R 8 is an alkyl group or an aryl group which may be substituted and is not the same as R 1 , to prepare a zirconium catalyst, and reacting a carboxylic acid of formula (2): R 2 COOH   (2) wherein R 2 is as defined above, with the monohydroxy compound of formula (1) in the presence of the zirconium catalyst.

  提供了一种制备化学式为(3)的羧酸酯的方法：R2COOR1 (3)，其中R1是可以被取代的烷基、可以被取代的烯基、可以被取代的炔基、可以被取代的芳基或可以被取代的杂芳基烷基，R2是可以被取代的烷基、可以被取代的烯基、可以被取代的炔基、可以被取代的芳基、可以被取代的杂芳基、可以被取代的芳基烷基或可以被取代的杂芳基烷基。该方法的特征在于将化学式为(1)的单羟基化合物：R1OH (1)（其中R1如上定义）与化学式为(6)的锆化合物反应：Zr(OR8)4 (6)（其中R8是可以被取代的烷基或芳基，且不同于R1），制备锆催化剂，然后在锆催化剂存在的情况下，将化学式为(2)的羧酸：R2COOH (2)（其中R2如上定义）与化学式为(1)的单羟基化合物反应。
• PROCESS FOR PRODUCTION OF (1-ALKENYL)CYCLOPROPANES
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1728781A1

  公开（公告）日：2006-12-06

  A method for producing a (1-alkenyl)cyclopropane compound represented by the formula (2): wherein R1 and R2 are the same or different, and independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted aryl group or an optionally substituted aralkyl group, which comprises bringing a (2-formyl-1-alkenyl)cyclopropane compound represented by the formula (1): wherein R1 and R2 are the same as defined above, into contact with a palladium catalyst.

  一种生产由式（2）代表的（1-烯基）环丙烷化合物的方法： 其中 R1 和 R2 相同或不同，并各自代表氢原子、任选取代的烷基、任选取代的烯基、任选取代的炔基、任选取代的芳基或任选取代的芳烷基、 其中包括加入由式（1）代表的（2-甲酰基-1-烯基）环丙烷化合物： 其中 R1 和 R2 与上述定义相同，与钯催化剂接触。
• EP1547995B1
  申请人：——

  公开号：EP1547995B1

  公开（公告）日：2014-05-07
• Method for producing (1-alkenyl) cyclopropane compound
  申请人：YOSHIKAWA Koji

  公开号：US20070197818A1

  公开（公告）日：2007-08-23

  A method for producing a (1-alkenyl)cyclopropane compound represented by the formula (2): wherein R 1 and R 2 are the same or different, and independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted aryl group or an optionally substituted aralkyl group, which comprises bringing a (2-formyl-1-alkenyl)cyclopropane compound represented by the formula (1): wherein R 1 and R 2 are the same as defined above, into contact with a palladium catalyst.