9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-one guanidinium | 1402947-10-7

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-one guanidinium
• 英文别名: Guanidine;6-hydroxybenzo[c][2,1]benzoxaphosphinine 6-oxide；guanidine;6-hydroxybenzo[c][2,1]benzoxaphosphinine 6-oxide
• CAS: 1402947-10-7
• 化学式: CH₅N₃*C₁₂H₉O₃P
• 分子量: 291.246
• InChiKey: UHFXKJQRTJADNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  122
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 双氧水 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 12.5h， 生成 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-one guanidinium
  参考文献：
  名称：

  AMMONIUM SALTS OF 9,10-DIHYDRO-10-HYDROXY-9-OXA-10-PHOSPHA-PHENANTHRENE-10-ONE

  摘要：

  该发明涉及公式I的9,10-二氢-10-羟基-9-氧杂-10-磷酸菲-10-酮或-10-氧化物（DOPO-OH）的铵盐，其中X选自氨、三聚氰胺和胍，以及根据以下公式II的开环水解物：其中X定义如上。

  公开号：

  US20120292582A1

文献信息

• Flame-retardant expandable polymers
  申请人：SUNPOR KUNSTSTOFF GESELLSCHAFT M.B.H.

  公开号：US10035892B2

  公开（公告）日：2018-07-31

  The present relates to flame-retardant expandable polymers and to polymer foams and to the use thereof. These flame-retardant expandable polymers and polymer foams can be contained in one or several pressurized containers. According to the present, at least one of the following phosphorus compounds is used as a flame retardant: phosphorus compound according to formula (Ia): (Ia) 10-hydroxy-9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-OH); or the salts thereof according to formula (Ib): (Ib) (DOPO-OR); or the ring-opened hydrolysates thereof according to formula (Ic): (Ic).

  本发明涉及阻燃性可膨胀聚合物和聚合物泡沫及其用途。这些阻燃性可膨胀聚合物和聚合物泡沫可以装在一个或多个加压容器中。根据本发明，以下至少一种磷化合物可用作阻燃剂：根据式（Ia）的磷化合物：(Ia)10-羟基-9，10-二氢-9-氧杂-10-磷菲-10-氧化物(DOPO-OH)；或根据式(Ib)的其盐：(Ib)(DOPO-OR)；或根据式(Ic)的其开环水解物：(Ic).
• FLAME-RETARDANT EXPANDABLE POLYMERS
  申请人：SUNPOR KUNSTSTOFF GESELLSCHAFT M.B.H.

  公开号：US20170044342A1

  公开（公告）日：2017-02-16

  The present relates to flame-retardant expandable polymers and to polymer foams and to the use thereof. These flame-retardant expandable polymers and polymer foams can be contained in one or several pressurized containers. According to the present, at least one of the following phosphorus compounds is used as a flame retardant: phosphorus compound according to formula (Ia): (Ia) 10-hydroxy-9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-OH); or the salts thereof according to formula (Ib): (Ib) (DOPO-OR); or the ring-opened hydrolysates thereof according to formula (Ic): (ilc).