diphenyl-[(E)-1-phenyl-2-phenylselanylethenyl]phosphane | 1121857-52-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenyl-[(E)-1-phenyl-2-phenylselanylethenyl]phosphane
• CAS: 1121857-52-0
• 化学式: C₂₆H₂₁PSe
• 分子量: 443.387
• InChiKey: VDDJBGDMUGANTG-YYADALCUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.15
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  二苯基二硒醚 、 苯乙炔 、 四苯基二膦 以 氘代氯仿 为溶剂， 反应 2.0h， 生成 、 diphenyl-[(E)-1-phenyl-2-phenylselanylethenyl]phosphane
  参考文献：
  名称：

  Highly Regioselective Simultaneous Introduction of Phosphino and Seleno Groups into Unsaturated Bonds by the Novel Combination of (Ph₂P)₂ and (PhSe)₂ upon Photoirradiation

  摘要：

  A novel combination of tetraphenyldiphosphine and diphenyl diselenide under photoirradiation conditions attains simultaneous introduction of diphenylphosphino and phenylseleno groups into carbon-carbon unsaturated bonds such as terminal alkynes or allenes, regioselectively.

  DOI：

  10.1021/jo8020067

文献信息

• Highly Regioselective Simultaneous Introduction of Phosphino and Seleno Groups into Unsaturated Bonds by the Novel Combination of (Ph₂P)₂ and (PhSe)₂ upon Photoirradiation
  作者：Shin-ichi Kawaguchi、Takamune Shirai、Takashi Ohe、Akihiro Nomoto、Motohiro Sonoda、Akiya Ogawa

  DOI：10.1021/jo8020067

  日期：2009.2.20

  A novel combination of tetraphenyldiphosphine and diphenyl diselenide under photoirradiation conditions attains simultaneous introduction of diphenylphosphino and phenylseleno groups into carbon-carbon unsaturated bonds such as terminal alkynes or allenes, regioselectively.