N,N',N"-tris(3-hydroxy-6-methyl-2-pyridylmethyl)-1,4,7-triazacyclononane | 133762-61-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N,N',N"-tris(3-hydroxy-6-methyl-2-pyridylmethyl)-1,4,7-triazacyclononane
• 英文别名: N,N',N''-tris(3-hydroxy-6-methyl-2-pyridylmethyl)-1,4,7-triazacyclononane；1,4,7-tris(3-hydroxy-6-methyl-2-pyridylmethyl)-1,4,7-triazacyclononane；2-[[4,7-Bis[(3-hydroxy-6-methylpyridin-2-yl)methyl]-1,4,7-triazonan-1-yl]methyl]-6-methylpyridin-3-ol
• CAS: 133762-61-5
• 化学式: C₂₇H₃₆N₆O₃
• 分子量: 492.621
• InChiKey: HAVLDNRTHSLMCO-UHFFFAOYSA-N

物化性质

• 沸点：
  761.7±55.0 °C(Predicted)
• 密度：
  1.258±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  109
• 氢给体数：
  3
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  3-羟基-6-甲基吡啶 、 聚合甲醛 、 1,4,7-三氮杂环壬烷 以 乙醇 为溶剂， 反应 24.0h， 以46%的产率得到N,N',N"-tris(3-hydroxy-6-methyl-2-pyridylmethyl)-1,4,7-triazacyclononane
  参考文献：
  名称：

  含羟基丙烯酰基供体基团的多齿配体的合成

  摘要：

  有效的合成描述了三个新的含3-羟基-6-甲基-2-吡啶基供体基团的多齿配体。N，N′-双（3-羟基-6-甲基-2-吡啶基甲基）乙二胺-N，N′-二乙酸，N，N″-双（3-羟基-6-甲基-2-吡啶基甲基）二亚乙基三胺- N，N′，N″-三乙酸，和N，N′，N″-三（3-羟基-6-甲基-2-吡啶基甲基）-1，4，7-三氮杂环壬烷。

  DOI：

  10.1016/s0040-4020(01)90495-8

文献信息

• Nanotube solution treated with molecular additive, nanotube film having enhanced adhesion property, and methods for forming the nanotube solution and the nanotube film
  申请人：Nantero Inc.

  公开号：US11072714B2

  公开（公告）日：2021-07-27

  The present disclosure provides a nanotube solution being treated with a molecular additive, a nanotube film having enhanced adhesion property due to the treatment of the molecular additive, and methods for forming the nanotube solution and the nanotube film. The nanotube solution includes a liquid medium, nanotubes in the liquid medium, and a molecular additive in the liquid medium, wherein the molecular additive includes molecules that provide source elements for forming a group IV oxide within the nanotube solution. The molecular additive can introduce silicon (Si) and/or germanium (Ge) in the liquid medium, such that nominal silicon and/or germanium concentrations of the nanotube solution ranges from about 5 ppm to about 60 ppm.

  本公开提供了一种用分子添加剂处理过的纳米管溶液、一种由于分子添加剂的处理而具有增强粘附性的纳米管薄膜，以及形成纳米管溶液和纳米管薄膜的方法。纳米管溶液包括液体介质、液体介质中的纳米管和液体介质中的分子添加剂，其中分子添加剂包括为在纳米管溶液中形成 IV 族氧化物提供源元素的分子。分子添加剂可在液体介质中引入硅 (Si) 和/或锗 (Ge)，从而使纳米管溶液中硅和/或锗的标称浓度在约 5 ppm 至约 60 ppm 之间。
• SHAMPOO COMPOSITION WITH ASSOCIATIVE THICKENERS
  申请人：The Procter & Gamble Company

  公开号：US20140348884A1

  公开（公告）日：2014-11-27

  A shampoo composition with improved in use hair feel, comprising associative thickeners and liquid crystals formed from anionic surfactants and polyDADMAC and wherein the liquid crystals have a particle size greater than about 1 micrometer.
• Nanotube Solution Treated with Molecular Additive, Nanotube Film Having Enhanced Adhesion Property, and Methods for Forming the Nanotube Solution and the Nanotube Film
  申请人：Nantero Inc.

  公开号：US20170226352A1

  公开（公告）日：2017-08-10

  The present disclosure provides a nanotube solution being treated with a molecular additive, a nanotube film having enhanced adhesion property due to the treatment of the molecular additive, and methods for forming the nanotube solution and the nanotube film. The nanotube solution includes a liquid medium, nanotubes in the liquid medium, and a molecular additive in the liquid medium, wherein the molecular additive includes molecules that provide source elements for forming a group IV oxide within the nanotube solution. The molecular additive can introduce silicon (Si) and/or germanium (Ge) in the liquid medium, such that nominal silicon and/or germanium concentrations of the nanotube solution ranges from about 5 ppm to about 60 ppm.
• US7521408B2
  申请人：——

  公开号：US7521408B2

  公开（公告）日：2009-04-21
• Syntheses of multidentate ligands containing hydroxypryidyl donor groups
  作者：Yizhen Sun、Arthur E. Martell、Joseph H. Reibenspies、Michael J. Welch

  DOI：10.1016/s0040-4020(01)90495-8

  日期：1991.1

  Efficient syntheses are described for three new multidentate ligands containing 3-hydroxy-6-methyl-2-pyridyl donor groups; N,N′-bis(3-hydroxy-6-methyl-2-pyridylmethyl)ethylenediamine-N,N′ -diacetic acid, N,N″-bis(3-hydroxy-6-methyl-2-pyridylmethyl)diethylenetriamine-N,N′ ,N″-triacetic acid, and N,N′ ,N″-tris (3-hydroxy-6-methyl-2-pyridylmethyl) -1,4,7- triazacyclononane.

  有效的合成描述了三个新的含3-羟基-6-甲基-2-吡啶基供体基团的多齿配体。N，N′-双（3-羟基-6-甲基-2-吡啶基甲基）乙二胺-N，N′-二乙酸，N，N″-双（3-羟基-6-甲基-2-吡啶基甲基）二亚乙基三胺- N，N′，N″-三乙酸，和N，N′，N″-三（3-羟基-6-甲基-2-吡啶基甲基）-1，4，7-三氮杂环壬烷。