Dibutyl(methyl)sulfanium | 62312-65-6

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: Dibutyl(methyl)sulfanium
• CAS: 62312-65-6
• 化学式: C9H21S+
• 分子量: 161.33
• InChiKey: JOBJJBNPNCZOSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• OXONIUM AND SULFONIUM SALTS
  申请人：Ignatyev Nikolai (Mykola)

  公开号：US20090036628A1

  公开（公告）日：2009-02-05

  The present invention relates to oxonium salts having [(R o ) 3 O] + cations and sulfonium salts having [(R o ) 3 S] + cations, where R o denotes straight-chain or branched alkyl groups having 1-8 C atoms or phenyl which is unsubstituted or substituted by R o , OR o , N(R o ) 2 , CN or halogen, and anions selected from the group of [PF x (C y F 2y+1−z H z ) 6−x ] − anions, where 2≦x≦5, 1≦y≦8 and 0≦z≦2y+1, or anions selected from the group of [BF n (CN) 4−n ] − anions, where n=0, 1 , 2 or 3, or anions selected from the group of [(R f1 SO 2 ) 2 N] − anions or anions selected from the group of [BF w R f2 4−w ] − anions, to processes for the preparation thereof, and to the use thereof, in particular for the preparation of ionic liquids.

  本发明涉及具有[(Ro)3O]+阳离子和[(Ro)3S]+阳离子的氧化铵盐和磺化铵盐，其中Ro表示直链或支链烷基基团，含有1-8个碳原子，或者未被Ro，ORo，N(Ro)2，CN或卤素取代的苯基，并且阴离子选自[PFx(CyF2y+1−zHz)6−x]−阴离子组，其中2≦x≦5，1≦y≦8，0≦z≦2y+1，或者选自[BFn(CN)4−n]−阴离子组，其中n=0, 1, 2或3，或者选自[(Rf1SO2)2N]−阴离子组或选自[BFwRf24−w]−阴离子组，以及其制备方法和用途，特别是用于制备离子液体。
• Salt suitable for an acid generator and a chemically amplified positive resist composition containing the same
  申请人：Harada Yukako

  公开号：US20080081293A1

  公开（公告）日：2008-04-03

  The present invention provides a salt represented by the formula (I): wherein P 1 , P 2 and P 3 each independently represent a C1-C30 alkyl group which may be substituted with at least one selected from a hydroxyl group, a C3-C12 cyclic hydrocarbon group and a C1-C12 alkoxy group, or a C3-C30 cyclic hydrocarbon group which may be substituted with at least one selected from a hydroxyl group and a C1-C12 alkoxy group, provided that all of P 1 , P 2 and P 3 are not simultaneously phenyl groups which may be substituted, Q 1 and Q 2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and R represents a group represented by the formula: wherein A 1 represents —OH or —Y 1 —OH, n represents an integer of 1 to 9, and Y 1 represents a divalent C1-C6 saturated aliphatic hydrocarbon group; a group represented by the formula: wherein ring X 1 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which one —CH 2 — group is substituted with —CO—, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group; a group represented by the formula: wherein ring X 2 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which a hydrogen atom of one —CH 2 — group is substituted with a hydroxyl group, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group; a group represented by the formula: wherein ring X 3 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which one —CH 2 — group is substituted with —COO—, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group, and m represents an integer of 0 to 12; or a group represented by the formula: wherein ring X 4 represents a C6-C30 polycyclic hydrocarbon group having tricycle or more, and at least one hydrogen atom in the polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group or a cyano group, and l represents an integer of 1 to 12. The present invention further provides a chemically amplified resist composition comprising the salt represented by the above-mentioned formula (I).

  本发明提供了一种盐，其表示为公式（I）：其中P1、P2和P3各自独立地表示一个C1-C30烷基基团，该基团可以被至少一个羟基、一个C3-C12环烃基团和一个C1-C12烷氧基中的至少一个取代，或者一个C3-C30环烃基团，该基团可以被至少一个羟基和一个C1-C12烷氧基中的至少一个取代，前提是P1、P2和P3均不同时为可以被取代的苯基；Q1和Q2各自独立地表示氟原子或者C1-C6全氟烷基基团，R表示由以下公式表示的一个基团：其中A1表示—OH或—Y1—OH，n表示1到9之间的整数，Y1表示二价的C1-C6饱和脂肪族碳氢基团；一个由以下公式表示的基团：其中环X1表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团被—CO—取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代；一个由以下公式表示的基团：其中环X2表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团的氢原子被羟基取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代；一个由以下公式表示的基团：其中环X3表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团被—COO—取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代，m表示0到12之间的整数；或者一个由以下公式表示的基团：其中环X4表示一个具有三环或更多的C6-C30多环碳氢基团，多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团或氰基取代，l表示1到12之间的整数。本发明还提供了一种化学增感抗蚀组合物，其包含上述公式（I）表示的盐。
• CRYSTALLINE ORGANIC-INORGANIC HALIDE PEROVSKITE THIN FILMS AND METHODS OF PREPARATION
  申请人：Cornell University

  公开号：US20160251303A1

  公开（公告）日：2016-09-01

  A film comprising a crystalline halide perovskite composition having the following formula: AMX 3 (1) wherein: A is an organic cation selected from the group consisting of methylammonium, tetramethylammonium, formamidinium, and guanidinium; M is at least one divalent metal; and X is independently selected from halide atoms; wherein the crystalline film of the halide perovskite composition possesses at least one of an average grain size of at least 30 microns, substantial crystal orientation evidenced in an ordering parameter of at least 0.6, and a level of crystallinity of at least 90%. Methods for producing films of these halide perovskite compositions using ionic liquids instead of volatile organic solvents are also described herein.

  一种晶态卤化物钙钛矿组成的电影，其化学式为：AMX3（1），其中：A是从甲基铵，四甲基铵，甲酰胺铵和胍铵组成的有机阳离子；M是至少一种二价金属；X是独立选择的卤素原子；其中，卤化物钙钛矿组成的晶体薄膜具有至少以下的其中一项：平均晶粒尺寸至少为30微米，具有明显的晶体取向，表现为至少0.6的有序参数，晶体度至少为90％。本文还描述了使用离子液体而不是挥发性有机溶剂制备这些卤化物钙钛矿组成的薄膜的方法。
• PROCESS FOR THE PREPARATION OF ONIUM SALTS WITH A TETRAFLUOROBORATE ANION HAVING A REDUCED HALIDE CONTENT
  申请人：Ignatyev Nikolai (Mykola)

  公开号：US20090253912A1

  公开（公告）日：2009-10-08

  The invention relates to a method for producing onium salts with tetrafluoroborate anion by reacting an onium halide with an oxonium tetrafluoroborate, sulfonium tetrafluoroborate, or triphenylcarbonium tetrafluoroborate.

  本发明涉及一种通过将onium卤化物与氧离子四氟硼酸盐、磺离子四氟硼酸盐或三苯基碳离子四氟硼酸盐反应来制备四氟硼酸盐onium盐的方法。
• Trialkylsulf(ox)onium salts of N-phosphonomethylglycine, production thereof, their use as plant growth regulators and herbicides and compositions containing them
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0057317A1

  公开（公告）日：1982-08-11

  Novel tri-mixed alkylsulfonium salts of N-phosphonomethylglycine are disclosed herein, having the formula in which R1, R2, and R3 represent C1-C5 alkyl and n is zero or one, wherein no more than two of R1, R2 or R3 are identical. The compounds are useful in regulating the natural growth or development of plants and as herbicides.

  本文公开了 N-膦酰甲基甘氨酸的新型三混合烷基锍盐，其式为 其中 R1、R2 和 R3 代表 C1-C5 烷基，n 为 0 或 1，其中 R1、R2 或 R3 中相同的不超过两个。这些化合物可用于调节植物的自然生长或发育，也可用作除草剂。