2-methoxycarbonyl-5-dimethylaminopyridine | 29681-40-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-methoxycarbonyl-5-dimethylaminopyridine
• 英文别名: methyl 5-dimethylaminopyridine-2-carboxylate；2-Methoxycarbonyl-5-dimethylaminopyridin；Methyl-5-dimethylamino-picolinat；5-dimethylamino-pyridine-2-carboxylic acid methyl ester；methyl 5-(dimethylamino)pyridine-2-carboxylate
• CAS: 29681-40-1
• 化学式: C₉H₁₂N₂O₂
• 分子量: 180.206
• InChiKey: HXVUVEMKPVPVSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-methoxycarbonyl-5-dimethylaminopyridine 生成 5-二甲氨基吡啶-2-羧酸
  参考文献：
  名称：

  LOS, MARINUS

  摘要：

  DOI：
• 作为产物：
  描述：

  5-氨基吡啶-2-甲酸甲酯 生成 2-methoxycarbonyl-5-dimethylaminopyridine
  参考文献：
  名称：

  LOS, MARINUS

  摘要：

  DOI：

文献信息

• Light-Emitting Material
  申请人：Jin Sung Ho

  公开号：US20090200920A1

  公开（公告）日：2009-08-13

  This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [ĈN] 2 ML, comprising chelate monoionic ligands (L), also called ancillary ligands. It has been surprisingly found that when the ancillary ligand comprises a substituted aromatic ring bearing a substituent possessing adequate electron-donating properties, said ligand (L) advantageously participates in the emission process, significantly shifting emission towards higher energies (blue-shift) and enabling appreciable improvement of the emission efficiency of complexes [ĈN] 2 ML. Still objects of the invention are the use of said light emitting materials and organic light emitting device comprising said light emitting material.

  这项发明涉及包含新型正金属化过渡金属配合物[ĈN]2ML的发光材料，包括螯合单离子配体（L），也称为辅助配体。令人惊讶地发现，当辅助配体包含带有足够电子给体性质的取代芳香环的取代基时，所述配体（L）有利地参与发射过程，显著将发射转移到更高能量（蓝移），并能够显著改善配合物[ĈN]2ML的发射效率。本发明还涉及使用所述发光材料和包括所述发光材料的有机发光器件。
• Koldobskii, A. B.; Lunin, V. V.; Voznesenskii, S. A., Journal of Organic Chemistry USSR (English Translation), 1992, vol. 28, # 4.2, p. 620 - 634
  作者：Koldobskii, A. B.、Lunin, V. V.、Voznesenskii, S. A.

  DOI：——

  日期：——
• LOS, MARINUS
  作者：LOS, MARINUS

  DOI：——

  日期：——
• Synthesis of 2-ethoxyprop-2-enal dimethylhydrazone and its Diels-Alder reactions
  作者：N. A. Keiko、T. A. Kuznetsova、L. I. Larina、Yu. A. Chuvashev、T. A. Klepikova、L. V. Sherstyannikova

  DOI：10.1134/s1070428006100010

  日期：2006.10

  Conditions were found for the preparation of 2-ethoxyprop-2-enal dimethylhydrazone by reaction of 2-ethoxypropenal with N,N-dimethylhydrazine. 2-Ethoxyprop-2-enal dimethylhydrazone reacted with methyl vinyl ketone and methyl acrylate according to the [4+2]-cycloaddition pattern with regioselective formation of substituted tetrahydropyridines. The major product in the reaction of 2-ethoxyprop-2-enal dimethylhydrazone with 1,4-benzoquinone was 5-hydroxy-1-benzofuran-2-carbaldehyde dimethylhydrazone formed as a result of [3+2]-cycloaddition; a small amount of the corresponding [4+2]-cycloaddition product was also obtained. Some spontaneous transformations of the primary cycloaddition products were revealed.
• US4638068A
  申请人：——

  公开号：US4638068A

  公开（公告）日：1987-01-20