3,3'-(2,5-dimethoxy-p-phenylene)-di-propionic acid | 40995-85-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 英文名称: 3,3'-(2,5-dimethoxy-p-phenylene)-di-propionic acid
• 英文别名: 3,3'-(2,5-Dimethoxy-p-phenylen)-di-propionsaeure；1,4-Bis-(2-carboxy-aethyl)-2,5-dimethoxy-benzol；2,5-Bis-(2-carboxy-ethyl)-hydrochinon-dimethylether；3-(4-(2-Carboxy-ethyl)-2,5-dimethoxy-phenyl)-propionic acid；3-[4-(2-carboxyethyl)-2,5-dimethoxyphenyl]propanoic acid
• CAS: 40995-85-5
• 化学式: C₁₄H₁₈O₆
• 分子量: 282.293
• InChiKey: WTAOZPNHCQMGGI-UHFFFAOYSA-N

物化性质

• 熔点：
  200-201 °C
• 沸点：
  477.7±40.0 °C(Predicted)
• 密度：
  1.252±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  20
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3,3'-(2,5-dimethoxy-p-phenylene)-di-propionic acid 在 lithium aluminium tetrahydride 、 硫酸 作用下， 以 四氢呋喃 为溶剂， 生成 3,3'-(2,5-Dimethoxy-1,4-phenylen)di-1-propanol
  参考文献：
  名称：

  Schill,G., Justus Liebigs Annalen der Chemie, 1966, vol. 691, p. 79 - 87

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-双(氯甲基)-2,5-二甲氧基苯 在 镍 哌啶 、 聚合甲醛 、 一水合肼 作用下， 以 吡啶 、 sodium hydroxide 、 乙醇 、 二氯甲烷 、 水 为溶剂， 反应 60.0h， 生成 3,3'-(2,5-dimethoxy-p-phenylene)-di-propionic acid
  参考文献：
  名称：

  Leighton, Philip; Sanders, Jeremy K. M., Journal of the Chemical Society. Perkin transactions I, 1987, p. 2385 - 2394

  摘要：

  DOI：

文献信息

• Schill,G., Justus Liebigs Annalen der Chemie, 1966, vol. 691, p. 79 - 87
  作者：Schill,G.

  DOI：——

  日期：——
• Vinylidene Cyanide. V. The Aluminum Chloride Catalyzed Reaction of Vinylidene Cyanide and Aromatic Compounds
  作者：J. C. Westfahl、T. L. Gresham

  DOI：10.1021/ja01633a043

  日期：1954.2
• LEIGHTON, PHILIP;SANDERS, JEREMY K. M., J. CHEM. SOC. PERKIN TRANS.,(1987) N 11, 2385-2393
  作者：LEIGHTON, PHILIP、SANDERS, JEREMY K. M.

  DOI：——

  日期：——
• SALTS OF PAROXETINE
  申请人：SMITHKLINE BEECHAM PLC

  公开号：EP1091958A1

  公开（公告）日：2001-04-18
• ORGANIC FILM TRANSISTOR, ORGANIC SEMICONDUCTOR FILM, ORGANIC SEMICONDUCTOR MATERIAL AND APPLICATION OF THESE
  申请人：FUJIFILM Corporation

  公开号：US20160126459A1

  公开（公告）日：2016-05-05

  An organic film transistor containing a compound, which is composed of n repeating units represented by Formula (1-1), (1-2), or (101), in a semiconductor active layer is an organic film transistor using a compound that results in high carrier mobility when being used in the semiconductor active layer of the organic film transistor and exhibits high solubility in an organic solvent. (Each of R 1 and R 2 represents a hydrogen atom or a substituent; each of Ar 1 and Ar 2 independently represents a heteroarylene group or an arylene group; V 1 represents a divalent linking group; m represents an integer of 0 to 6; cy represents a naphthalene ring or an anthracene ring; each of R 3 and R 4 represents a hydrogen atom or a substituent; each of Ar 3 and Ar 4 represents a heterocyclic aromatic ring or an aromatic ring; V 2 represents a divalent linking group; p represents an integer of 0 to 6; n represents an integer of equal to or greater than 2; A is a divalent linking group represented by Formula (101′); each of R A1 to R A6 represents a hydrogen atom, a substituent, or a direct bond with Ar 101 or Ar 102 in Formula (101); and among the groups represented by R A1 to R A6 , two different groups are direct bonds with Ar 101 and Ar 102 in Formula (101) respectively.)