4-isocyanato-1,6-heptadiene | 852859-86-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-isocyanato-1,6-heptadiene
• 英文别名: 4-Isocyanatohepta-1,6-diene
• CAS: 852859-86-0
• 化学式: C₈H₁₁NO
• 分子量: 137.181
• InChiKey: HAJJDFVQJROSJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,3-二乙氧基丙酰胺 、 4-isocyanato-1,6-heptadiene 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 14.0h， 以61%的产率得到1-庚-1,6-二烯-4-基嘧啶-2,4-二酮
  参考文献：
  名称：

  4-[(1H,3H)-Pyrimidine-2,4-Dion-1-yl]-和4-[(1H,3H)-5-Methylpyrimidine-2,4-Dion-1-yl]-1的合成,6-庚二烯

  摘要：

  摘要 含有核酸碱基的庚二烯是合成碳环寡核苷酸类似物的重要组成部分。在此，我们报告了 4-[(1H,3H)-pyrimidine-2,4-dion-1-yl]-1,6-庚二烯和 4-[(1H,3H)-5-methylpyrimidine-的替代合成路线2,4-dion-1-yl]-1,6-庚二烯通过利用4-异氰酸根合-1,6-庚二烯中间体构建嘧啶环。

  DOI：

  10.1081/scc-200051721
• 作为产物：
  描述：

  在 magnesium sulfate 作用下， 以35.6 g的产率得到4-isocyanato-1,6-heptadiene
  参考文献：
  名称：

  4-[(1H,3H)-Pyrimidine-2,4-Dion-1-yl]-和4-[(1H,3H)-5-Methylpyrimidine-2,4-Dion-1-yl]-1的合成,6-庚二烯

  摘要：

  摘要 含有核酸碱基的庚二烯是合成碳环寡核苷酸类似物的重要组成部分。在此，我们报告了 4-[(1H,3H)-pyrimidine-2,4-dion-1-yl]-1,6-庚二烯和 4-[(1H,3H)-5-methylpyrimidine-的替代合成路线2,4-dion-1-yl]-1,6-庚二烯通过利用4-异氰酸根合-1,6-庚二烯中间体构建嘧啶环。

  DOI：

  10.1081/scc-200051721

文献信息

• CROSS-LINKING AGENT FOR CROSS-LINKABLE ELASTOMERS AND APPLICATION THEREOF
  申请人：Yamaura Mabuko

  公开号：US20130053520A1

  公开（公告）日：2013-02-28

  The object of the present invention to provide a cross-linking agent for a cross-linkable elastomer which is excellent in the heat resistance and rapid in the cross-linking rate in comparison with triallyl isocyanurate (TAIC). The present invention relates to a cross-linking agent for a cross-linkable elastomer comprising a triazine derivative represented by the general formula (I) or prepolymer thereof. (In the formula (I), at least two of X, Y and Z are each independently a diallylamino group, a mono-allyl amino group or allyl-methylamino group, and the rest is a hydrogen atom or a hydrocarbon group which may be substituted.)

  本发明的目的是提供一种用于可交联弹性体的交联剂，与三烯基异氰酸酯（TAIC）相比，在耐热性和交联速率方面均具有优异的性能。本发明涉及一种交联剂，其包括由通式（I）表示的三嗪衍生物或其预聚物。（在式（I）中，至少有两个X、Y和Z中的每一个独立地是二烯丙氨基基团、单烯丙氨基基团或烯丙基甲基氨基基团，其余的是氢原子或可能被取代的碳氢基团。）
• TRIAZINE DERIVATIVES AND APPLICATION THEREOF
  申请人：Yamaura Mabuko

  公开号：US20130023629A1

  公开（公告）日：2013-01-24

  The object of the present invention is to provide a novel triazine derivative which is excellent in the heat resistance and rapid in the cross-linking rate, and can be suitably used as a crosslinking agent. The present invention relates to a triazine derivative represented by the general formula (I). (In the formula (I), Y and X are each independently, represents a diallylamino group, mono-allylamino group, allyloxy group or methallyloxy group; and Z represents an allyloxy group or methallyloxy group)

  本发明的目的是提供一种新型的三嗪衍生物，其具有良好的耐热性和快速的交联速率，并可适当用作交联剂。本发明涉及一种由通式（I）表示的三嗪衍生物。（在式（I）中，Y和X分别独立地表示二烯基氨基，单烯基氨基，烯丙氧基或甲基烯丙氧基；Z表示烯丙氧基或甲基烯丙氧基）
• CROSS-LINKING AGENT FOR CROSS-LINKABLE ELASTOMER AND APPLICATION THEREOF
  申请人：Yamaura Mabuko

  公开号：US20130041111A1

  公开（公告）日：2013-02-14

  The object of the present invention is to provide a cross-linking agent for a cross-linkable elastomer which is rapid in the cross-linking rate in comparison with triallyl isocyanurate (TAIC). The present invention relates to a cross-linking agent for a cross-linkable elastomer comprising a bis-isocyanurate derivative represented by the general formula (I). (In the formula, X represents the C1 to C12 alkenylene group or C1 to C12 alkylene group, which may contain a carbonyl group, an ether bond or an ester bond in the main chain, and further a substituent in the side chain; at least two of Y 1 , Y 2 , Y 3 and Y 4 are each independently an allyl group which may be substituted, and the rest is a hydrogen atom or a hydrocarbon group which may be substituted.)

  本发明的目的是提供一种用于可交联弹性体的交联剂，其交联速率与三异氰酸三烯丙酯（TAIC）相比更快。本发明涉及一种交联剂，其包括由通式（I）表示的双异氰酸酯衍生物，用于可交联弹性体。（在公式中，X代表C1到C12的烯基或C1到C12的烷基，可能在主链中含有羰基、醚键或酯键，并且在侧链中进一步含有取代基；Y1、Y2、Y3和Y4中至少有两个是各自独立的烯丙基，可以被取代，其余是氢原子或可以被取代的碳氢基。）
• CROSSLINKING AGENT FOR CROSSLINKABLE ELASTOMER, AND APPLICATION THEREOF
  申请人：Nippon Kasei Chemical Company Limited

  公开号：EP2537889A1

  公开（公告）日：2012-12-26

  The object of the present invention is to provide a cross-linking agent for a cross-linkable elastomer which is rapid in the cross-linking rate in comparison with triallyl isocyanurate (TAIC). The present invention relates to a cross-linking agent for a cross-linkable elastomer comprising a bis-isocyanurate derivative represented by the general formula (I). (In the formula, X represents the C1 to C12 alkenylene group or C1 to C12 alkylene group, which may contain a carbonyl group, an ether bond or an ester bond in the main chain, and further a substituent in the side chain; at least two of Y1, Y2, Y3 and Y4 are each independently an allyl group which may be substituted, and the rest is a hydrogen atom or a hydrocarbon group which may be substituted.)

  本发明的目的是提供一种用于可交联弹性体的交联剂，与异氰尿酸三烯丙基酯 （TAIC）相比，该交联剂的交联速度更快。 本发明涉及一种用于可交联弹性体的交联剂，该交联剂由通式 (I) 所代表的双异氰脲酸酯衍生物组成。 (式中，X 代表 C1 至 C12 烯基或 C1 至 C12 亚烷基，其主链中可含有羰基、醚键或酯键，侧链中进一步含有取代基；Y1、Y2、Y3 和 Y4 中至少有两个各自独立地为可被取代的烯丙基，其余为氢原子或可被取代的烃基)。
• TRIAZINE DERIVATIVE, AND APPLICATION THEREOF
  申请人：Nippon Kasei Chemical Company Limited

  公开号：EP2537833A1

  公开（公告）日：2012-12-26

  The object of the present invention is to provide a novel triazine derivative which is excellent in the heat resistance and rapid in the cross-linking rate, and can be suitably used as a crosslinking agent. The present invention relates to a triazine derivative represented by the general formula (I). (In the formula (I), Y and X are each independently, represents a diallylamino group, mono-allylamino group, allyloxy group or methallyloxy group; and Z represents an allyloxy group or methallyloxy group)

  本发明的目的是提供一种新型三嗪衍生物，它具有优异的耐热性和快速的交联率，可适当用作交联剂。 本发明涉及一种由通式（I）表示的三嗪衍生物。 式（I）中，Y 和 X 各自独立地代表二烯丙基氨基、单烯丙基氨基、烯丙基氧基或甲基烯丙基氧基；Z 代表烯丙基氧基或甲基烯丙基氧基）。