S-p-(2-methylbutyloxycarbonyl)benzoyl chloride | 91577-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-p-(2-methylbutyloxycarbonyl)benzoyl chloride
• 英文别名: 4-[(S)-2-methylbutoxycarbonyl]benzoyl chloride；[(2S)-2-methylbutyl] 4-carbonochloridoylbenzoate
• CAS: 91577-97-8
• 化学式: C₁₃H₁₅ClO₃
• 分子量: 254.713
• InChiKey: SEHIAGPQAYPGNU-VIFPVBQESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  S-p-(2-methylbutyloxycarbonyl)benzoyl chloride 、 4-hydroxy-4'-decyloxybiphenyl 生成 4'-n-decyloxy-4-biphenylyl S-p-(2-methylbutoxycarbonyl)benzoate
  参考文献：
  名称：

  INUKAI, TAKASI;FURUKAVA, KEHNDZI;TEHRADZIMA, KANEHTSUGU;SAJTO, SINITI;ISO+

  摘要：

  DOI：
• 作为产物：
  描述：

  4-[(S)-2-methylbutoxycarbonyl]benzoic acid 生成 S-p-(2-methylbutyloxycarbonyl)benzoyl chloride
  参考文献：
  名称：

  INUKAI, TAKASI;FURUKAVA, KEHNDZI;TEHRADZIMA, KANEHTSUGU;SAJTO, SINITI;ISO+

  摘要：

  DOI：

文献信息

• Ferroelectric liquid crystal compounds and liquid crystal compositions
  申请人：Hitachi, Ltd.

  公开号：US04576732A1

  公开（公告）日：1986-03-18

  The present invention is characterized by a smectic liquid crystal compound represented by the following formula: ##STR1## wherein R is selected from alkyl and alkoxy groups; X from ##STR2## m and n are natural numbers; and R* is an optically active group containing an asymmetric carbon atom, and a liquid crystal composition containing said compound as a component. This compound is excellent in optical stability and high-speed response.

  本发明的特征在于由以下公式表示的一种膦相液晶化合物：其中，R选自烷基和烷氧基；X选自；m和n为自然数；R*是含有不对称碳原子的光学活性基团，以及含有该化合物作为组分的液晶组合物。该化合物在光学稳定性和高速响应方面表现出色。
• Lactic acid derivatives and liquid crystal compositions containing the
  申请人：Dainippon Ink and Chemicals, Inc.

  公开号：US05324451A1

  公开（公告）日：1994-06-28

  A compound represented by formula (I): ##STR1## wherein R.sub.1 represents an alkyl group having from 1 to 18 carbon atoms; R.sub.2 represents an alkyl group having from 2 to 16 carbon atoms; rings A, B, C, and D each represents a 1,4-phenylene group or a 1,4-phenylene group having one or two halogen atoms; Y represents a single bond, ##STR2## m and n each represents 0 or 1; p represents 0, 1, or 2; q represents 0 or an integer of from 1 to 6; and C* and C** each represents an asymmetric carbon atom in an (S)- or (R)-configuration, and a liquid crystal composition containing the compound of formula (I). The compound of formula (I) is a chiral liquid crystal compound exhibiting large spontaneous polarization, a long helical pitch, an SC* phase in a broad temperature range including room temperature, satisfactory orientation, and a high rate of response.

  化合物的化学式为(I)：##STR1## 其中，R.sub.1代表具有1到18个碳原子的烷基；R.sub.2代表具有2到16个碳原子的烷基；环A、B、C和D分别代表1,4-苯基或带有一或两个卤素原子的1,4-苯基；Y代表单键，##STR2## m和n各自代表0或1；p代表0、1或2；q代表0或1到6的整数；C*和C**各自代表(S)-或(R)-构型的不对称碳原子，以及含有化合物(I)的液晶组合物。化合物(I)是一种手性液晶化合物，具有大的自发极化、长的螺旋周期、在包括室温在内的广泛温度范围内的SC*相、令人满意的取向和高响应速率。
• Novel lactic acid derivatives and liquid crystal compositions containing the same
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0329153A2

  公开（公告）日：1989-08-23

  compound represented by formula (I): wherein R1 represents an alkyl group having from 1 to 18 carbon atoms; R2 represents an alkyl group having from 2 to 16 carbon atoms; rings A, B, C, and D each represents a 1,4-phenylene group or a 1,4-phenylene group having one or two halogen atoms; Y represents a single bond, m and n each represents 0 or 1; p represents 0, 1, or 2; q represents 0 or an integer of from 1 to 6; and C* and C" each represents an asymmetric carbon atom in an (S)- or (R)-configuration, and a liquid crystal composition containing the compound of formula (I). The compound of formula (I) is a chiral liquid crystal compound exhibiting large spontaneous polarization, a long helical pitch, an SC* phase in a broad temperature range including room temperature, satisfactory orientation, and a high rate of response.

  式 (I) 所代表的化合物： 其中 R1 代表具有 1 至 18 个碳原子的烷基；R2 代表具有 2 至 16 个碳原子的烷基；环 A、B、C 和 D 各代表 1，4-亚苯基或具有一个或两个卤素原子的 1，4-亚苯基；Y 代表单键、 m和n各自代表0或1；p代表0、1或2；q代表0或1至6的整数；以及C*和C "各自代表(S)-或(R)-构型的不对称碳原子，以及含有式(I)化合物的液晶组合物。式（I）化合物是一种手性液晶化合物，具有较大的自发偏振、较长的螺旋间距、在包括室温在内的较宽温度范围内的 SC* 相、令人满意的取向性和较高的响应速度。
• INUKAI, TAKASI;FURUKAVA, KEHNDZI;TEHRADZIMA, KANEHTSUGU;SAJTO, SINITI;ISO+
  作者：INUKAI, TAKASI、FURUKAVA, KEHNDZI、TEHRADZIMA, KANEHTSUGU、SAJTO, SINITI、ISO+

  DOI：——

  日期：——
• Smectic liquid crystal compounds and liquid crystal compositions
  申请人：HITACHI, LTD.

  公开号：EP0110299B1

  公开（公告）日：1988-06-29