Hg(C6H4-2-CH2NMe2)2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Hg(C6H4-2-CH2NMe2)2
• 英文别名: Hg(2-dimethylaminomethylphenyl-C'N)2
• 化学式: C₁₈H₂₄HgN₂
• 分子量: 468.992
• InChiKey: MTVYWFSHQXOURC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.09
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [RuCl2(benzene)]2 、 Hg(C6H4-2-CH2NMe2)2 以 乙腈 为溶剂， 以85%的产率得到[Ru(η6-C6H6)(2-(CH2NMe2-κN)-C6H4-κC(1))]Cl
  参考文献：
  名称：

  钌（II）配合物介导的碳-碳和碳-氮键形成：（1H）-异喹啉鎓衍生物的合成

  摘要：

  New cycloruthenated complexes can be obtained by transmetalation of [(eta6-arene)RuCl2]2 (arene = C6H6 or i-PrC6H4Me-1,4) with several mercury- or zinc-metalated [ (N,N-dimethylamino)methyl]benzene derivatives. Intramolecular C-H activation using these amines with [eta6-C6H6)RuCl2]2 affords the same cycloruthenated complexes though in lower yield. The resulting complexes are of the type (eta6-arene)RuCl(C,N) [(C,N) = C6H4CH2NMe2-2, (R)-(+)-C6H4CH-(Me)NMe2-2, C6H2(OCH2O-2,3)CH2NMe2-6] and have a rigid structure containing a five-membered Ru-C-C-C-N chelate ring, both in the solid state and in solution. Reaction of the cycloruthenated complexes with internal alkynes can lead to the formation of novel Ru(0) sandwich complexes of the type [(eta6-arene)Ru(eta4-C6H4CH(R)NMe2CR1=CR2-1,2)]+[PF6]- (R = H, Me; R1, R2 = alkyl, aryl, or carboxyalkyl). The formation of the heterocyclic units occurs with good chemo- and regioselectivities, asymmetric alkynes being incorporated in such a way that the acetylene carbon with the sterically least demanding substituent becomes attached to the nitrogen atom of the arylamine. Oxidative demetalation induced by CuBr2 allows the isolation of the free organic (1H)-isoquinolium derivatives [C6H4CH2NMe2CR1=R2-1,2]+[PF6]- (R1 = R2 = Et, Ph; R1 = CO2Et, R2 = Ph) under mild conditions and in reasonable yields.

  DOI：

  10.1021/om00035a034
• 作为产物：
  描述：

  、 mercury dichloride 以 苯 为溶剂， 以26%的产率得到Hg(C6H4-2-CH2NMe2)2
  参考文献：
  名称：

  Arylmercury(II) compounds involving intramolecular coordination via 2-Me2NCH2- and chiral (S)-2-Me2NCHMe-ring substituents

  摘要：

  DOI：

  10.1016/s0022-328x(00)85654-5

文献信息

• Synthesis of the first hydroxomonoaryltin(<scp>IV</scp>) complexes. Crystal and molecular structure of [{Sn[C₆H₃(NNC₆H₄Me-4′)-2,Me-5]Cl₂(µ-OH)}₂]
  作者：José Vicente、María-Teresa Chicote、María-del-Carmen Ramírez-de-Arellano、Peter G. Jones

  DOI：10.1039/dt9920001839

  日期：——

  MeO (mopap)] to give metallic mercury and [SnLCl3](L = mpap 1 or mopap 2). Complex 1 reacts with Cl–, dimethyl sulfoxide or [Hg(dmap)2](dmap = C6H4CH2NMe2-2) to give, respectively, [Sn(mpap)Cl4]–3, [Sn(mpap)Cl3(OSMe2)]4 or [Sn(mpap)(dmap)Cl2]5. Several types of hydrolytic process occur when 1, 2 or [Sn(mpap)Ph2Cl] react with various ligands. Thus, [Hg(dmap)Cl] reacts with 1 or 2 as a base to give [SnLCl2(µ-OH)}2](L

  氯化锡（II）在回流的二甲苯中与[HgLCl] [L = C 6 H 3（N NC 6 H 4 R-4'）-2，R-5反应；R ＝ Me（mpap）或MeO（mopap）]得到金属汞和[SnLCl 3 ]（L ＝ mpap 1或mopap 2）。配合物1与Cl –，二甲基亚砜或[Hg（dmap）2 ]（dmap = C 6 H 4 CH 2 NMe 2 -2）反应，分别得到[Sn（mpap）Cl 4 ] – 3，[Sn（ mpap）Cl 3（OSMe 2）]4或[Sn（mpap）（dmap）Cl 2 ] 5。当1、2或[Sn（mpap）Ph 2 Cl]与各种配体反应时，会发生几种类型的水解过程。因此，[Hg（dmap）Cl]与1或2作为碱反应，得到[SnLCl 2（μ-OH）} 2 ]（L ＝ mpap 6或mopap 7）和Hg（Hdmap）Cl 2。类似地，PhCH 2 NMe 2（bdma）与1（1：1
• Importance of steric effects upon the synthesis of {(η6-arene)RuCl}-C,N-cyclometallated amines
  作者：Michel Pfeffer、Jean-Pascal Sutter、Esteban P. Urriolabeitia

  DOI：10.1016/0020-1693(96)05030-x

  日期：1996.8

  Abstract The transmetallation reaction between [( η 6 -arene)RuCl 2 ] 2 ( η 6 -arene = C 4 H 6 (benzene) ( 1 ); 1-Me-4- 1 Pr-C 6 H 4 (cymene) ( 2 ); 1,2,4,5-Me 4 -C 6 H 2 (durene) ( 3 ); 1,2,3,5-Me 4 -C 6 H 2 (isodurene) ( 4 ) and the aminoaryl-mercury derivatives HgQ-dmba} 2 (Q-dmba = 1-C 6 H 3 -3-F-6-CH 2 NMe 2 } ( a ); 1-C 6 H 3 -6-CH 2 NMe 2 } ( b ); 1-C 6 H 2 -2,3-OCH 2 OCH 2 -6-CH 2 NMe 2

  摘要[（η6-芳烃）RuCl 2] 2（η6-芳烃= C 4 H 6（苯）（1）; 1-Me-4- 1 Pr-C 6 H 4（苏木）（ 2）; 1,2,4,5-Me 4 -C 6 H 2（二烯）（3）; 1,2,3,5-Me 4 -C 6 H 2（异二烯）（4）和氨基芳基-汞衍生物Hg Q-dmba} 2（Q-dmba = 1- C 6 H 3 -3-F-6-CH 2 NMe 2}（a）; 1- C 6 H 3 -6-CH 2 NMe 2}（b）; 1- C 6 H 2 -2,3-OCH 2 OCH 2 -6-CH 2 NMe 2}（c）1- C 6 H02,4-（MeO）2 -6-CH 2 NMe 2}（b）; 1- C 6 H 4 CH 2 NMe 2}（e）得到相应的C，N-环钌化的配合物[η6-芳烃）RuCl Q-dmba}。通过1 H和13 C 1 H} NMR进
• Aspects of transmetallation reactions of 2-Me2NCH2C6H4- and 2,6-(Me2NCH2)C6H3-Metal (Pd, Pt, Hg, Tl) complexes with metal carboxylates and low-valent metal (Pd, Pt) complexes
  作者：Antonius F.M.J. Van Der Ploeg、Gerard Van Koten、Kees Vrieze

  DOI：10.1016/s0022-328x(00)89024-5

  日期：1981.12

  cis-[(2-Me2NCH2C6H4)2Pd] with Pd(O2CR)2 gave the dimeric compound [(2-Me2NCH2C6H4)Pd(O2CR)}2]. cis-[(2-Me2NCH2C6H4)2Pt] did not react with Pd(O2CMe)2, while reaction of trans-[(2-Me2NCH2C6H4)2Pt] or cis-[(2-Me2NC6H4CH2)2Pt] with Pd(O2CMe)2 resulted in decomposition. Upon heating, trans-[(2-Me2NCH2C6H4)2Pt] was isomerized to cis-isomer. A redox reaction between [(2-Me2NCH2C6H4)2Hg] and [Pt(COD)2] (COD  1,5-cyclo-octadiene)

  已经对涉及包含邻-Me 2 NCH 2取代的芳基配体的有机金属化合物的反应进行了研究。新化合物[（2-Me 2 NCH 2 C 6 H 4）2 TlCl]，[[（（S）-2-Me 2 NCH（Me）C 6 H 4 } 2 TlCl]，[ （S）-2-Me 2 NCH（Me）C 6 H 4 } TlCl 2 ]，[2,6-（Me 2 NCH 2）2 C 6 H描述了3 } TlClBr]和[2,6-（Me 2 NCH 2）2 C 6 H 3 } HgCl]。对于C-手性th化合物，已经建立了在低温下稳定的内部NT1配位。其他Tl和Hg化合物与[（2-Me 2 NCH 2 C 6 H 4）2 Hg]与Pd（O 2 CMe）2的反应，以及顺式-[（2-Me 2 NCH 2 C 6 H 4）2 Pd]和Hg（O 2 CR）2或Tl（O 2 CR）3，使一种有机配体发生金属转移并生成单一的
• Synthesis and solution behavior of some bis[2-{(dimethylamino)methyl}phenyl]gold(III) complexes
  作者：José Vicente、Maria Dolores Bermúdez、Maria José Sánchez-Santano、Jorge Payá

  DOI：10.1016/s0020-1693(00)80277-7

  日期：1990.8

  in the presence of an excess of [Me4N]Cl to give [Au(2-C6H4CH2NMe2)2Cl] (1) which reacts with KCN or AgClO4 to give [Au(2- C6H4CH2-NMe2)2CN] (2) or [Au(2-C6H4CH2- NME2)2]ClO4 (3), respectively. The solution behavior of these complexes is studied by NMR spectroscopy.

  摘要[Au（2-C6H4CH2NMe2）Cl2]与[Hg（2-C6H4CH2NMe2）2]（2/1）或与[Hg（2-C6H4CH2-NMe2）Cl]（1/1）均在过量的[Me4N] Cl得到[Au（2-C6H4CH2NMe2）2Cl]（1），它与KCN或AgClO4反应得到[Au（2- C6H4CH2-NMe2）2CN]（2）或[Au（2-C6H4CH2- NME2）2] ClO4（3）。通过NMR光谱研究了这些配合物的溶液行为。
• Arylmercury(II) compounds involving intramolecular coordination via 2-Me2NCH2- and chiral (S)-2-Me2NCHMe-ring substituents
  作者：Antonius F.M.J. Van Der Ploeg、Cornelus E.M. Van Der Kolk、Gerard Van Koten

  DOI：10.1016/s0022-328x(00)85654-5

  日期：1981.6