5-amino-3-(1-naphthyl)biphenyl | 104581-17-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-amino-3-(1-naphthyl)biphenyl
• 英文别名: 5-(Naphthalen-1-yl)[1,1'-biphenyl]-3-amine；3-naphthalen-1-yl-5-phenylaniline
• CAS: 104581-17-1
• 化学式: C₂₂H₁₇N
• 分子量: 295.384
• InChiKey: DWCFIVNFRKBKBJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-amino-5-(1-naphthyl)biphenyl-2,4-dicarbonitrile 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以68%的产率得到5-amino-3-(1-naphthyl)biphenyl
  参考文献：
  名称：

  Elimination of the nitrile group from o-aminonitriles—IV

  摘要：

  DOI：

  10.1016/s0040-4020(01)96775-4

文献信息

• Copper-Catalyzed Synthesis of Substituted Primary Arylamines from Cyclohexenone Oxime Esters
  作者：Yong-Jie Kuang、Yan Yu、Min Zhou、Yu-Cheng Yin、Tian Cai、Qun-Li Luo

  DOI：10.1021/acs.orglett.3c03501

  日期：2023.12.8

  A novel protocol has been developed for the Cu-catalyzed synthesis of primary arylamines with meta-substituents using cyclohexenone oxime esters. Mechanistic insights suggest that the reaction proceeds via an intermolecular 1,5-H hydrogen atom transfer of an imine radical intermediate. This approach features high efficiency, a readily available catalyst system, and broad functional group tolerance

  开发了一种使用环己烯酮肟酯铜催化合成具有间位取代基的伯芳胺的新方案。机理研究表明该反应通过亚胺自由基中间体的分子间 1,5-H 氢原子转移进行。这种方法具有高效率、易于使用的催化剂系统和广泛的官能团耐受性的特点。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE THE ORGANOMETALLIC COMPOUND, AND DIAGNOSTIC COMPOSITION INCLUDING THE ORGANOMETALLIC COMPOUND
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3560940A1

  公开（公告）日：2019-10-30

  Provided are an organometallic compound represented by Formula 1, an organic light-emitting device including the organometallic compound, and a diagnostic composition including the organometallic compound:               M(L1)n1(L2)n2 M, L1, L2, n1 and n2 are each independently the same as defined in the specification.

  本文提供了一种由式 1 表示的有机金属化合物、一种包括该有机金属化合物的有机发光器件和一种包括该有机金属化合物的诊断组合物： M(L1)n1(L2)n2 M、L1、L2、n1 和 n2 各自独立地与本说明书中定义的相同。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND ELECTRONIC APPARATUS INCLUDING THE ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3705483A1

  公开（公告）日：2020-09-09

  Provided are an organometallic compound represented by Formula 1, an organic light-emitting device including the same, and an electronic apparatus comprising the organic light-emitting device:               M(L1)n1(L2)n2 wherein, in Formula 1, M, L1, L2, n1, and n2 are the same as described in the detailed description of the specification.

  本文提供了一种由式 1 表示的有机金属化合物、一种包括该有机金属化合物的有机发光器件以及一种包括该有机发光器件的电子设备： M(L1)n1(L2)n2 其中，式 1 中的 M、L1、L2、n1 和 n2 与说明书的详细说明中所述的相同。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING SAME, AND DIAGNOSTIC COMPOSITION INCLUDING SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3772517A1

  公开（公告）日：2021-02-10

  An organometallic compound represented by Formula 1, wherein M1 is beryllium, magnesium, aluminum, calcium, titanium, manganese, cobalt, copper, zinc, gallium, germanium, zirconium, ruthenium, rhodium, palladium, silver, rhenium, platinum, or gold; A1 to A3 are each independently a C5-C30 carbocyclic group or a C1-C30 heterocyclic group; A4 is a 5-membered heterocyclic group; A5 is a C7-C30 carbocyclic group of at least two rings comprising a 6-membered carbocyclic group, or A5 is a C1-C30 heterocyclic group of at least two rings comprising a 6-membered carbocyclic group or a 6-membered heterocyclic group; X10, X20, X30, and X40 to X44 are each independently C or N; T1 to T3 are each independently a single bond, *-N[(L1)a1-(R1)b1]-*', *-B(R1)-*', *-P(R1)-*', *-C(R1)(R2)-*', *-Si(R1)(R2)-*', *-Ge(R1)(R2)-*', *-S-*', *-Se-*', *-O-*', *-C(=O)-*', *-S(=O)-*', *-S(=O)2-*', *-C(R1)=C(R2)-*', *-C(=S)-*', or *-C≡C-*'; and wherein the other substituents may be understood by referring to the detailed description.

  一种由式1表示的有机金属化合物，其中M1是铍、镁、铝、钙、钛、锰、钴、铜、锌、镓、锗、锆、钌、铑、钯、银、铼、铂或金；A1至A3各自独立地是C5-C30碳环基团或C1-C30杂环基团；A4 是 5 元杂环基团； A5 是至少由两个环组成的 C7-C30 碳环基团，其中包括一个 6 元碳环基团，或 A5 是至少由两个环组成的 C1-C30 杂环基团，其中包括一个 6 元碳环基团或一个 6 元杂环基团；X10、X20、X30 和 X40 至 X44 各自独立地为 C 或 N；T1 至 T3 各自独立地为单键、*-N[(L1)a1-(R1)b1]-*'、*-B(R1)-*'、*-P(R1)-*'、*-C(R1)(R2)-*'、*-Si(R1)(R2)-*'、*-Ge(R1)(R2)-*'、*-S-*'、*-Se-*'、*-O-*'、*-C(=O)-*'、*-S(=O)-*'、*-S(=O)2-*'、*-C(R1)=C(R2)-*'、*-C(=S)-*'或*-C≡C-*'；其中其他取代基可参阅详细说明。
• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3831819A1

  公开（公告）日：2021-06-09

  Provided are a heterocyclic compound represented by Formula 1 and having an asymmetric structure and an organic light-emitting device including the heterocyclic compound: wherein, in Formula 1, X1 is O or Se, Ar1 is a group represented by Formula 1A, and Ar2 is a group represented by Formula 1B, and the other substituents are understood as described in connection with the detailed description.

  本文提供了一种由式 1 表示且具有不对称结构的杂环化合物，以及一种包括该杂环化合物的有机发光器件： 其中，在式 1 中，X1 是 O 或 Se，Ar1 是式 1A 所代表的基团，Ar2 是式 1B 所代表的基团、 其他取代基与详细说明中所述的相同。