tris{4-[2-(diphenethylphosphorothioyl)ethyl]benzyl}phosphine oxide | 1402851-37-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris{4-[2-(diphenethylphosphorothioyl)ethyl]benzyl}phosphine oxide
• 英文别名: 2-[4-[Bis[[4-[2-[bis(2-phenylethyl)phosphinothioyl]ethyl]phenyl]methyl]phosphorylmethyl]phenyl]ethyl-bis(2-phenylethyl)-sulfanylidene-lambda5-phosphane；2-[4-[bis[[4-[2-[bis(2-phenylethyl)phosphinothioyl]ethyl]phenyl]methyl]phosphorylmethyl]phenyl]ethyl-bis(2-phenylethyl)-sulfanylidene-λ5-phosphane
• CAS: 1402851-37-9
• 化学式: C₇₅H₈₄OP₄S₃
• 分子量: 1221.58
• InChiKey: ZWDHHBOQSHNCRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19
• 重原子数：
  83
• 可旋转键数：
  33
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris{4-[2-(diphenethylphosphorothioyl)ethyl]benzyl}phosphine oxide 在 氧气 、 sodium 作用下， 以 甲苯 为溶剂， 反应 4.42h， 生成 tris{4-[2-(2-diphenethylphosphoryl)ethyl]benzyl}phosphine oxide
  参考文献：
  名称：

  One-pot synthesis of ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides

  摘要：

  Ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides have been synthesized by the exhaustive regioselective addition of secondary phosphines, phosphine sulfides and phosphine selenides to available tris(4-vinylbenzyl)phosphine oxide under free-radical conditions (UV irradiation or AIBN) in good to excellent yields. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.08.091
• 作为产物：
  描述：

  bis(2-phenethyl)phosphine 在 sulfur 作用下， 以 苯 为溶剂， 反应 3.5h， 生成 tris{4-[2-(diphenethylphosphorothioyl)ethyl]benzyl}phosphine oxide
  参考文献：
  名称：

  One-pot synthesis of ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides

  摘要：

  Ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides have been synthesized by the exhaustive regioselective addition of secondary phosphines, phosphine sulfides and phosphine selenides to available tris(4-vinylbenzyl)phosphine oxide under free-radical conditions (UV irradiation or AIBN) in good to excellent yields. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.08.091

文献信息

• One-pot synthesis of ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides
  作者：Nina K. Gusarova、Vladimir A. Kuimov、Svetlana F. Malysheva、Nataliya A. Belogorlova、Alexander I. Albanov、Boris A. Trofimov

  DOI：10.1016/j.tet.2012.08.091

  日期：2012.11

  Ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides have been synthesized by the exhaustive regioselective addition of secondary phosphines, phosphine sulfides and phosphine selenides to available tris(4-vinylbenzyl)phosphine oxide under free-radical conditions (UV irradiation or AIBN) in good to excellent yields. (C) 2012 Elsevier Ltd. All rights reserved.