triethyl-(3-furan-2-yl-propoxy)-silane | 2385-50-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: triethyl-(3-furan-2-yl-propoxy)-silane
• 英文别名: Triethyl-3-(2-furyl)propoxysilane；triethyl-[3-(furan-2-yl)propoxy]silane
• CAS: 2385-50-4
• 化学式: C₁₃H₂₄O₂Si
• 分子量: 240.418
• InChiKey: FAQUZJLOJNHAKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.23
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  22.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三乙基硅烷 、 反-3-(2-呋喃基)丙烯醛 在 chloro(1,5-cyclooctadiene)rhodium(I) dimer 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 triethyl-(3-furan-2-yl-propoxy)-silane 、 、 triethyl-[(E)-3-(furan-2-yl)prop-1-enoxy]silane
  参考文献：
  名称：

  Hydrosilylation of unsaturated (hetero)aromatic aldehydes and related compounds catalyzed by transition metal complexes

  摘要：

  [Rh(COD)CI](2) has been found to be a more active catalyst than Ir, Ru, Pt and Pd complexes for the hydrosilylation of unsaturated furan and aromatic aldehydes with HSiEt3. 1,4- and 1,2-addition reactions giving unsaturated silyl ethers in cis- and trans-configurations occurred as well as the hydrogenation reactions which produce the corresponding saturated silyl ethers. The migration of the ethyl group was observed in the hydrosilylation of 3-ethyl-3-(5-nitrofuryl)acrolein. The dehydrogenative silylation occurred in the reactions of cinnamyl alcohol and furan-2-acrylic acid. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00431-8

文献信息

• Hydrosilylation of unsaturated (hetero)aromatic aldehydes and related compounds catalyzed by transition metal complexes
  作者：Irina Iovel、Juris Popelis、Alexander Gaukhman、Edmunds Lukevics

  DOI：10.1016/s0022-328x(98)00431-8

  日期：1998.5

  [Rh(COD)CI](2) has been found to be a more active catalyst than Ir, Ru, Pt and Pd complexes for the hydrosilylation of unsaturated furan and aromatic aldehydes with HSiEt3. 1,4- and 1,2-addition reactions giving unsaturated silyl ethers in cis- and trans-configurations occurred as well as the hydrogenation reactions which produce the corresponding saturated silyl ethers. The migration of the ethyl group was observed in the hydrosilylation of 3-ethyl-3-(5-nitrofuryl)acrolein. The dehydrogenative silylation occurred in the reactions of cinnamyl alcohol and furan-2-acrylic acid. (C) 1998 Elsevier Science S.A. All rights reserved.