bis(5-(tert-butyl)-3-((diphenylphosphino)methyl)-2-methoxyphenyl)methane | 912631-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(5-(tert-butyl)-3-((diphenylphosphino)methyl)-2-methoxyphenyl)methane
• 英文别名: BDMMphos；[5-Tert-butyl-3-[[5-tert-butyl-3-(diphenylphosphanylmethyl)-2-methoxyphenyl]methyl]-2-methoxyphenyl]methyl-diphenylphosphane；[5-tert-butyl-3-[[5-tert-butyl-3-(diphenylphosphanylmethyl)-2-methoxyphenyl]methyl]-2-methoxyphenyl]methyl-diphenylphosphane
• CAS: 912631-85-7
• 化学式: C₄₉H₅₄O₂P₂
• 分子量: 736.914
• InChiKey: AVPFTVRBPRICKL-UHFFFAOYSA-N

物化性质

• 沸点：
  750.2±60.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  53
• 可旋转键数：
  14
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 bis(5-(tert-butyl)-3-((diphenylphosphino)methyl)-2-methoxyphenyl)methane 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Extended Calix[4]arene Analogues by Two P−Cu^I−P Bridges and Anion Encapsulation

  摘要：

  Two novel extended calix[4]arene analogues by two P-Cu-1-P bridges have been synthesized. The molecular structures and anion encapsulation ability for ClO4- and BF4- have been studied by X-ray analysis.

  DOI：

  10.1021/ic060892p
• 作为试剂：
  描述：

  、 silver perchlorate 在 bis(5-(tert-butyl)-3-((diphenylphosphino)methyl)-2-methoxyphenyl)methane 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以75%的产率得到
  参考文献：
  名称：

  Gold(I) and silver(I) complexes of a diphosphine analog of a half-calix[4]arene moiety

  摘要：

  The diphosphine ligand bis(5-(tert-butyl)-3-((diphenylphosphino)methyl)-2-methoxyphenyemethane (BDMMphos) has been metallated with the transition metal complexes Ag(CH3CN)(4)BF4 and Au(Me2S)Cl to yield the corresponding diphosphine metal complexes (BDMMphos)AgBF4 (1), (BDMMphos)(AuCl)(2) (2) and (BDMMphos)AuClO4 (3). All of the complexes were characterized by elemental analyses, H-1, P-31 and C-13 NMR spectroscopies and X-ray structure determination. The diphosphine ligand BDMMphos displayed versatile coordination properties. In complexes I and 3, BDMMphos chelated metal ions to form stable 12-membered ring complexes with large bite angles, while in complex 2, BDMMphos simply coordinated to two AuCl units as a bridging ligand. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.036

文献信息

• Extended Calix[4]arene Analogues by Two P−Cu^I−P Bridges and Anion Encapsulation
  作者：Xiang-Tai Meng、Qing-Shan Li、Feng-Bo Xu、Hai-Bin Song、Christopher E. Anson、Zheng-Zhi Zhang

  DOI：10.1021/ic060892p

  日期：2006.10.1

  Two novel extended calix[4]arene analogues by two P-Cu-1-P bridges have been synthesized. The molecular structures and anion encapsulation ability for ClO4- and BF4- have been studied by X-ray analysis.
• Gold(I) and silver(I) complexes of a diphosphine analog of a half-calix[4]arene moiety
  作者：Xiang-Tai Meng、Rong-Hua Xu、Qing-Shan Li、Feng-Bo Xu

  DOI：10.1016/j.poly.2012.11.036

  日期：2013.2

  The diphosphine ligand bis(5-(tert-butyl)-3-((diphenylphosphino)methyl)-2-methoxyphenyemethane (BDMMphos) has been metallated with the transition metal complexes Ag(CH3CN)(4)BF4 and Au(Me2S)Cl to yield the corresponding diphosphine metal complexes (BDMMphos)AgBF4 (1), (BDMMphos)(AuCl)(2) (2) and (BDMMphos)AuClO4 (3). All of the complexes were characterized by elemental analyses, H-1, P-31 and C-13 NMR spectroscopies and X-ray structure determination. The diphosphine ligand BDMMphos displayed versatile coordination properties. In complexes I and 3, BDMMphos chelated metal ions to form stable 12-membered ring complexes with large bite angles, while in complex 2, BDMMphos simply coordinated to two AuCl units as a bridging ligand. (C) 2012 Elsevier Ltd. All rights reserved.