triphenyltin hydrosulfide | 33364-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenyltin hydrosulfide
• 英文别名: Sulfanide;triphenylstannanylium；sulfanide;triphenylstannanylium
• CAS: 33364-67-9
• 化学式: C₁₈H₁₆SSn
• 分子量: 383.101
• InChiKey: OJBQHWODCCVDIQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.93
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  硫光气 、 三苯基氢氧化锡 在 Et₃N 、 H₂O 作用下， 以 苯 为溶剂， 以10%的产率得到triphenyltin hydrosulfide
  参考文献：
  名称：

  Synthesis of triphenyltin(IV) hydrosulfide

  摘要：

  Compounds of the type R3SnSH are believed to be unstable (unless sterically protected by very bulky R groups) because of their facile condensation into the corresponding sulfide, (R3Sn)(2)S. One such compound, Ph3SnSH has been synthesized by an one pot reaction of triphenyltin hydroxide with thiophosgene followed by the hydrolysis of the intermediate triphenyltin chlorothioformate. The product, triphenyltin hydrosulfide has been characterized by IR, H-1, C-13 and Sn-119 NMR spectral techniques. Single crystal X-ray analysis revealed that the molecule is a discrete monomer containing tin atom at the centre of a distorted tetrahedron. Plausible reaction mechanism for the formation of the molecule has also been reported. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.014

文献信息

• Synthesis of triphenyltin(IV) hydrosulfide
  作者：Suryabhan Singh、Subrato Bhattacharya

  DOI：10.1016/j.ica.2010.12.014

  日期：2011.2

  Compounds of the type R3SnSH are believed to be unstable (unless sterically protected by very bulky R groups) because of their facile condensation into the corresponding sulfide, (R3Sn)(2)S. One such compound, Ph3SnSH has been synthesized by an one pot reaction of triphenyltin hydroxide with thiophosgene followed by the hydrolysis of the intermediate triphenyltin chlorothioformate. The product, triphenyltin hydrosulfide has been characterized by IR, H-1, C-13 and Sn-119 NMR spectral techniques. Single crystal X-ray analysis revealed that the molecule is a discrete monomer containing tin atom at the centre of a distorted tetrahedron. Plausible reaction mechanism for the formation of the molecule has also been reported. (C) 2010 Elsevier B.V. All rights reserved.