6,15-dibromo-2,11-dithia[3,3](2,6)pyridinophane | 882175-43-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6,15-dibromo-2,11-dithia[3,3](2,6)pyridinophane
• 英文别名: 7,15-Dibromo-3,11-dithia-17,18-diazatricyclo[11.3.1.15,9]octadeca-1(16),5,7,9(18),13(17),14-hexaene；7,15-dibromo-3,11-dithia-17,18-diazatricyclo[11.3.1.15,9]octadeca-1(16),5,7,9(18),13(17),14-hexaene
• CAS: 882175-43-1
• 化学式: C₁₄H₁₂Br₂N₂S₂
• 分子量: 432.203
• InChiKey: QOHXZBFFOVJMLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-溴-2,6-双(溴甲基)吡啶 在 sodium hydroxide 、 sodium tetrahydroborate 作用下， 以 甲醇 、 乙醇 、 苯 为溶剂， 反应 50.0h， 生成 6,15-dibromo-2,11-dithia[3,3](2,6)pyridinophane
  参考文献：
  名称：

  Synthesis and Characterization of Dithia[3.3](2,6)pyridinophane-Containing Polymers:  Application to the Palladium-Catalyzed Heck Reaction

  摘要：

  We synthesized zigzag polymers consisting of dithia[3.3](2,6)pyridinophane units that were flipped rapidly as a result of syn-[anti]-syn isomerization. Pyridinophane units were fixed in the syn form by complexation with palladium, and the resulting polymer complex exhibited a high catalytic activity for the Heck coupling reaction.

  DOI：

  10.1021/ol0529290

文献信息

• Synthesis and Characterization of Dithia[3.3](2,6)pyridinophane-Containing Polymers:  Application to the Palladium-Catalyzed Heck Reaction
  作者：Yasuhiro Morisaki、Tamao Ishida、Yoshiki Chujo

  DOI：10.1021/ol0529290

  日期：2006.3.1

  We synthesized zigzag polymers consisting of dithia[3.3](2,6)pyridinophane units that were flipped rapidly as a result of syn-[anti]-syn isomerization. Pyridinophane units were fixed in the syn form by complexation with palladium, and the resulting polymer complex exhibited a high catalytic activity for the Heck coupling reaction.