2-烯丙基-2-环己基丙二腈 | 119752-27-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 2-烯丙基-2-环己基丙二腈
• 英文名称: 2-Allyl-2-cyclohexyl-malononitrile
• 英文别名: 2-Allyl-2-cyclohexylmalononitrile；2-cyclohexyl-2-prop-2-enylpropanedinitrile
• CAS: 119752-27-1
• 化学式: C₁₂H₁₆N₂
• 分子量: 188.272
• InChiKey: UYSBRYKEGSVNJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-环己基亚己基丙二腈 、 烯丙基三甲基硅烷 生成 2-烯丙基-2-环己基丙二腈
  参考文献：
  名称：

  MIZUNO, K.;NAKANISHI, K.;CHOSA, J.;OTSUJI, Y., CHEM. FUNCT. DYES: 1ST INT. SYMP., OSAKA, JUNE 5TH-9TH, 1989, TOKYO,(1989+

  摘要：

  DOI：

文献信息

• Dual Regioselectivity in the Photoallylation of Electron-Deficient Alkenes by Allylic Silanes
  作者：Kazuhiko Mizuno、Munehiro Ikeda、Yoshio Otsuji

  DOI：10.1246/cl.1988.1507

  日期：1988.9.5

  The photoreaction of 1-aryl-2,2-dicyanoethenes with allylic silanes in the presence of phenanthrene gave 4-aryl-5,5-dicyano-1-pentenes in high yields. In this photoreaction, the allylic groups were introduced regioselectively at the β-position to cyano group. In contrast, the photoreaction of alkylidenepropanedinitriles with allylic silanes gave products allylated at the α-position to cyano group along with their reduction products.

  1-芳基-2,2-二氰基乙烯与烯丙基硅烷在菲存在下进行光反应，以高产率生成4-芳基-5,5-二氰基-1-戊烯。在该光反应中，烯丙基被区域选择性地引入氰基的β位。相反，亚烷基丙二腈与烯丙基硅烷的光反应得到在α位上烯丙基化为氰基的产物及其还原产物。
• Photoallylation and Photoreduction of Cyclohexylidenepropanedinitrile by Use of Allyltrimethylsilane via Photoinduced Electron Transfer:  Control of the Product Ratio Depending on p<i>K</i>_a Values of Additives
  作者：Tomoo Hayamizu、Munehiro Ikeda、Hajime Maeda、Kazuhiko Mizuno

  DOI：10.1021/ol000386i

  日期：2001.5.1

  [GRAPHICS]Irradiation of an acetonitrile solution containing cyclohexylidenepropanedinitrile (1) and allyltrimethylsilane (2) in the presence of phenanthrene afforded two kinds of allylated products (3, 4) and a reduction product (5). The product ratio of 3, 4, and 5 dramatically changed depending on the pK(a) values of additives.
• MIZUNO, KAZUHIKO;IKEDA, MUNEHIRO;OTSUJI, YOSHIO, CHEM. LETT.,(1988) N 9, C. 1507-1510
  作者：MIZUNO, KAZUHIKO、IKEDA, MUNEHIRO、OTSUJI, YOSHIO

  DOI：——

  日期：——