2-(pent-2-yn-1-yloxy)acetonitrile | 1307725-84-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(pent-2-yn-1-yloxy)acetonitrile
• 英文别名: 2-Pent-2-ynoxyacetonitrile；2-pent-2-ynoxyacetonitrile
• CAS: 1307725-84-3
• 化学式: C₇H₉NO
• 分子量: 123.155
• InChiKey: SMWHRVVTORHOFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-癸炔 、 2-(pent-2-yn-1-yloxy)acetonitrile 在 (E,E)-N,N'-(pyridine-2,6-diylbis(methanylylidene))bis(4-(benzyloxy)-2,6-diisopropylaniline) 、 iron(II) acetate 、 锌 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.17h， 以41%的产率得到2,3-dibutyl-4-ethyl-5,7-dihydrofuro[3,4-b]pyridine
  参考文献：
  名称：

  Iron-Catalyzed Cycloaddition of Alkynenitriles and Alkynes

  摘要：

  The combination of Fe(OAc)(2) and an electron-donating, sterically hindered pyridyl bisimine ligand catalyzes the cycloaddition of alkynenitriles and alkynes. A variety of substituted pyridines were obtained in good yields.

  DOI：

  10.1021/ol2009939
• 作为产物：
  描述：

  2-戊炔-1-醇 、 溴乙腈 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以42%的产率得到2-(pent-2-yn-1-yloxy)acetonitrile
  参考文献：
  名称：

  Iron-Catalyzed Cycloaddition of Alkynenitriles and Alkynes

  摘要：

  The combination of Fe(OAc)(2) and an electron-donating, sterically hindered pyridyl bisimine ligand catalyzes the cycloaddition of alkynenitriles and alkynes. A variety of substituted pyridines were obtained in good yields.

  DOI：

  10.1021/ol2009939

文献信息

• NON-AQUEOUS ELECTROLYTE ADDITIVE, AND NON-AQUEOUS ELECTROLYTE FOR LITHIUM SECONDARY BATTERY COMPRISING THE SAME AND LITHIUM SECONDARY BATTERY
  申请人：LG Chem, Ltd.

  公开号：US20180198157A1

  公开（公告）日：2018-07-12

  The present invention relates to a non-aqueous electrolyte additive, and a non-aqueous electrolyte for a lithium secondary battery including the same and a lithium secondary battery, and particularly, to a non-aqueous electrolyte additive having a nitrile group and a propargyl group, and a non-aqueous electrolyte for a lithium secondary battery and a lithium secondary battery, which include the non-aqueous electrolyte additive so that capacity and cycle lifespan characteristics at high temperature can be improved.
• Iron-Catalyzed Cycloaddition of Alkynenitriles and Alkynes
  作者：Brendan R. D’Souza、Timothy K. Lane、Janis Louie

  DOI：10.1021/ol2009939

  日期：2011.6.3

  The combination of Fe(OAc)(2) and an electron-donating, sterically hindered pyridyl bisimine ligand catalyzes the cycloaddition of alkynenitriles and alkynes. A variety of substituted pyridines were obtained in good yields.