p-Propoxy-phenylmethylsulfon | 19760-89-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-Propoxy-phenylmethylsulfon
• 英文别名: 1-Methylsulfonyl-4-propoxybenzene
• CAS: 19760-89-5
• 化学式: C₁₀H₁₄O₃S
• 分子量: 214.285
• InChiKey: AUSZTHIRHGTZJV-UHFFFAOYSA-N

物化性质

• 沸点：
  362.7±34.0 °C(Predicted)
• 密度：
  1.138±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  丙醇 、 4-氯苯基甲基砜 在 sodium n-propoxide 作用下， 生成 p-Propoxy-phenylmethylsulfon
  参考文献：
  名称：

  Shein,S.M. et al., Journal of Organic Chemistry USSR (English Translation), 1968, vol. 4, p. 632 - 636

  摘要：

  DOI：

文献信息

• Organic Compounds
  申请人：Sandham David Andrew

  公开号：US20080312229A1

  公开（公告）日：2008-12-18

  There are provided according to the invention compounds of formula (I) in free or salt form, wherein R 1 , R 2 , R 4 , R 5 , R 6 , A, D, X, W, m and n are as described in the specification, process for preparing them, and their use as pharmaceuticals.

  根据本发明，提供了化合物(I)的自由或盐形式，其中R1、R2、R4、R5、R6、A、D、X、W、m和n如说明书所述，以及制备它们的方法和它们作为药物的用途。
• Carbon Nitride with <scp>Single‐Atom</scp> Nickel as <scp>Co‐Catalyst</scp> for <scp>Visible‐Light</scp> Promoted C—O Coupling^†
  作者：En Zhao、Lijie Chen、Qi Zhu、Zhaohui Chen、Yanping Wei、Wenjun Zhang、Lin Dong、Weiwei Fang、Zupeng Chen

  DOI：10.1002/cjoc.202300329

  日期：2023.12

  cross-coupling reactions by dual nickel/photocatalysis under mild conditions have received considerable attention. However, the existing photo/nickel dual catalytic cross-coupling reactions require the addition of expensive photosensitizers and organic ligands, and the catalytic activity is inadequate. Herein, we report a nickel single-atom heterogeneous catalyst supported on mesoporous carbon nitride for photocatalytic

  在温和条件下通过双镍/光催化进行的太阳能驱动的交叉偶联反应受到了相当多的关注。然而，现有的光/镍双催化交叉偶联反应需要添加昂贵的光敏剂和有机配体，催化活性不足。在此，我们报道了一种负载在介孔氮化碳上的镍单原子多相催化剂，用于4-溴苯甲腈和乙醇之间的光催化CO偶联反应，与半多相催化体系相比，以优异的产率提供4-乙氧基苯甲腈。该催化体系具有广泛的底物范围，包括酮、醛、酯和酰胺。这项工作提出了一种简单且经济高效的策略，将金属单原子锚定到氮化碳上，为芳基醚化合物的高性能光催化生产提供了一个新平台。
• INK SET
  申请人：Seiko Epson Corporation

  公开号：US20160032125A1

  公开（公告）日：2016-02-04

  There is provided an ink set including at least: a yellow ink; a magenta ink; and a cyan ink, in which the yellow ink includes one or more kinds selected from a group consisting of coloring materials represented by the following Formulae (Y-1) and (Y-2), the magenta ink includes one or more kinds selected from a group consisting of coloring materials represented by the following Formulae (M-1) and (M-2), and the cyan ink includes one or more kinds selected from a group consisting of coloring materials represented by the following Formulae (C-1) and (C-2).
• APJ RECEPTOR AGONISTS AND USES THEREOF
  申请人：AMGEN INC.

  公开号：US20160067347A1

  公开（公告）日：2016-03-10

  The application is directed to APJ receptor agonist analogs having increased stability relative to the wild type apelin-13 and methods of using the agonist analogs. The analogs can be used, inter alia, in cardiac disorders such as heart failure.
• APELIN POLYPEPTIDES
  申请人：AMGEN INC.

  公开号：US20170107255A1

  公开（公告）日：2017-04-20

  The invention provides modified apelin polypeptides having increased stability, circulating half-life, and/or potency relative to the native apelin-13 polypeptide. Compositions comprising the modified apelin polypeptides and methods of using the polypeptides for treating cardiac disorders, such as heart failure, are also disclosed.