2-甲基-N-[4-(苯基氨基)苯基]-2-丙烯酰胺 | 41543-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-甲基-N-[4-(苯基氨基)苯基]-2-丙烯酰胺
• 英文名称: N-(4-anilinophenyl)-methacrylamide
• 英文别名: N-(4-anilinophenyl) methacrylamide；N-(4-anilinophenyl)methacrylamide；2-Propenamide, 2-methyl-N-[4-(phenylamino)phenyl]-；N-(4-anilinophenyl)-2-methylprop-2-enamide
• CAS: 41543-92-4
• 化学式: C₁₆H₁₆N₂O
• 分子量: 252.316
• InChiKey: GFSJJVJWCAMZEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  41.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  末端脱氧核苷酸转移酶 、 2-甲基-N-[4-(苯基氨基)苯基]-2-丙烯酰胺 、 氢氧化钾 以 乙醇 为溶剂， 反应 7.0h， 生成 N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide
  参考文献：
  名称：

  N,N-bis(4-anilinophenyl)-4,7-dithia-5-methyldecanediamide and related

  摘要：

  N,N'-双(4-苯胺基苯基)-4,7-二硫-5-甲基癸二酰胺及相关抗氧化剂被用于保护未硫化和硫化聚合物。当硫化丁腈橡胶暴露在高温老化条件下时，它们特别有效。

  公开号：

  US03975414A1
• 作为产物：
  描述：

  对氨基二苯胺 生成 2-甲基-N-[4-(苯基氨基)苯基]-2-丙烯酰胺
  参考文献：
  名称：

  BUYSCH, H. -J.;SZENTIVANYI, Z.;WITTE, J.

  摘要：

  DOI：

文献信息

• Benzoxazines, thermosetting resins comprised thereof, and methods for use thereof
  申请人：Loctite Corporation

  公开号：US20030125551A1

  公开（公告）日：2003-07-03

  In accordance with the present invention, there are provided novel benzoxazine compounds and thermosetting resin compositions prepared therefrom. Invention compositions are particularly useful for increasing adhesion at interfaces within microelectronic packages. Invention benzoxazines are useful for the preparation of invention compositions with properties which are associated with increased adhesion at interfaces, such as, for example, low shrinkage on cure and low coefficient of thermal expansion (CTE). In another aspect of the invention, there are provided die-attach pastes having increased interfacial adhesion. Invention die-attach pastes include benzoxazine-containing thermosetting resin compositions. In further aspects of the invention, there are provided methods for enhancing adhesive strength of thermosetting resin compositions and methods for enhancing adhesion of a substrate bound to a metallic surface by a thermosetting resin composition.

  根据本发明，提供了新型苯并噁嗪化合物和由此制备的热固性树脂组合物。发明组合物特别适用于提高微电子封装内界面的粘附性。发明的苯并噁嗪化合物可用于制备具有与增强界面粘附相关的性质的发明组合物，例如，固化后的低收缩率和低热膨胀系数（CTE）。在本发明的另一个方面，提供了具有增强界面粘附的贴片膏。发明的贴片膏包括含苯并噁嗪的热固性树脂组合物。在本发明的进一步方面，提供了增强热固性树脂组合物粘接强度的方法，以及增强通过热固性树脂组合物将基板粘接到金属表面的粘附力的方法。
• Transition metal P-N complexes as polymerization catalysts
  申请人：LANXESS Deutschland GmbH

  公开号：EP2641909A1

  公开（公告）日：2013-09-25

  The present invention provides new metal complexes which can be advantageously used for homo- or copolymerization of at least one diene monomer optionally in the presence of one or more copolymerisable comonomers and which in particular provide cis-polydienes starting from conjugated dienes.

  本发明提供了新的金属配合物，可以优势地用于至少一种二烯单体的同聚或共聚反应，可选地在一种或多种可共聚的共聚单体的存在下进行，并且特别是从共轭二烯起始提供顺式聚二烯。
• Process for preparing aromatic amide antioxidants
  申请人：The Goodyear Tire & Rubber Company

  公开号：US04322551A1

  公开（公告）日：1982-03-30

  A process for the preparation of aromatic amide antioxidants from a simple aliphatic or aromatic ester and primary amine in the presence of a metal alkoxide and an alcohol. Unsaturated products produced using this process are sufficiently pure to use as comonomers in the preparation of elastomers.

  一种制备芳香酰胺抗氧化剂的方法，该方法使用简单的脂肪族或芳香族酯和一级胺，在金属烷氧基和醇的存在下进行。使用此方法产生的不饱和产物足够纯净，可用作弹性体制备中的共聚单体。
• Process for the preparation of antioxidant amides
  申请人：The Goodyear Tire & Rubber Company

  公开号：US04286105A1

  公开（公告）日：1981-08-25

  An inexpensive and nonhazardous process for the preparation of an amide wherein an organic acid reacting with an aryl amine to form an intermediate hydroxy aryl amide and then dehydrating the hydroxy aryl amide to form a .alpha., .beta. unsaturated amide.

  一种制备酰胺的廉价且无危险的方法，其中有机酸与芳基胺反应以形成中间体羟基芳基酰胺，然后通过脱水羟基芳基酰胺形成α，β-不饱和酰胺。
• Free radically polymerizable coupling agents
  申请人：Henkel Loctite Corporation

  公开号：US20040006166A1

  公开（公告）日：2004-01-08

  In accordance with the present invention, there are provided novel coupling agents which are compatible with a wide variety of adhesive formulations and which provide substantial adhesion enhancement relative to base formulations to which they are added. Invention compounds comprise at least one free-radically polymerizable group (other than acrylate) and at least one reactive moiety which forms covalent bond(s) with substrates having free hydroxyl groups on the surface thereof. Thus, invention compounds are covalently linked to adhesive formulations upon free radical cure, while at the same time providing “residual” functionality which is capable of undergoing reaction with any substrate having reactive (e.g., hydroxyl) groups in the surface thereof.

  根据本发明，提供了新型耦合剂，这些耦合剂与各种胶粘剂配方兼容，并且相对于它们所添加的基础配方，提供了实质性的粘附增强。发明化合物至少包括一个自由基聚合基团（不包括丙烯酸酯）和至少一个反应性基团，该反应性基团与表面具有自由羟基的底物形成共价键。因此，发明化合物在自由基固化时与胶粘剂配方共价连接，同时提供“残留”功能，能够与表面具有反应性（例如羟基）基团的任何底物发生反应。