Described herein is a composition comprising: a polymer derived from
(a) a fluorinated olefin monomer;
(b) a highly fluorinated sulfur-containing monomer of the formula:
CX1X2=CX3[(CX4X5)w-O-R1-SO2Y]
where each X1, X2, X3, X4 , and X5 is independently selected from H, Cl, or F; w is 0 or 1; R1 is a fluorinated divalent carbon-containing group, optionally comprising oxygen atoms; and Y is selected from F, Cl, Br, I, or OM, where M is a cation; and
(c) a polyfunctional monomer, comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof, wherein the composition further comprises an additive, wherein the additive comprises at least one of a manganese and cerium.
本文所述的组合物包括:一种聚合物,由以下物质衍生而来
(a)
氟化烯烃单体;
(b) 式中的高
氟化含
硫单体:
CX1X2=CX3[(CX4X5)w-O-R1-SO2Y]
其中每个 X1、X2、X3、X4 和 X5 独立选自 H、Cl 或 F;w 为 0 或 1;R1 为含
氟的二价含碳基团,任选包括氧原子;Y 选自 F、Cl、Br、I 或 OM,其中 M 为阳离子;以及
(c) 包含至少两个官能团的多官能团单体,其中官能团选自由以下组成的组:(i)
氟乙烯基醚基团,(ii)
氟烯丙基醚基团,(iii)
氟化烯烃基团,和 (iv) 其组合,其中组合物进一步包含添加剂,其中添加剂包含
锰和
铈中的至少一种。