4-[5-[5-[5-(2,6-Dipyridin-2-ylpyridin-4-yl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-2,6-dipyridin-2-ylpyridine | 1263305-62-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-[5-[5-[5-(2,6-Dipyridin-2-ylpyridin-4-yl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-2,6-dipyridin-2-ylpyridine
• 英文别名: 4-[5-[5-[5-(2,6-dipyridin-2-ylpyridin-4-yl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-2,6-dipyridin-2-ylpyridine
• CAS: 1263305-62-9
• 化学式: C₄₂H₂₆N₆S₃
• 分子量: 710.907
• InChiKey: UDJZTZHRCIIKEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  51
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  162
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  2,5-二硼酸噻吩 、 4'-(5-bromo-thiophen-2-yl)-[2,2';6',2'']terpyridine 在 [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropiridyl)palladium(II) dichloride 、 potassium carbonate 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 18.0h， 以85%的产率得到4-[5-[5-[5-(2,6-Dipyridin-2-ylpyridin-4-yl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-2,6-dipyridin-2-ylpyridine
  参考文献：
  名称：

  Synthesis and photophysical properties of α,ω-bis(terpyridine)oligothiophenes

  摘要：

  Four novel fully pi-conjugated alpha,omega-bis(terpyridine)oligothiophenes characterized by NMR, IR, and HR-mass spectroscopy are presented and their electronic absorption/emission and redox properties are described based on both experiments and theoretical calculations. These compounds can be potentially utilized as building blocks for preparation of conjugated metallo-supramolecular polymers or dynamers and related functional materials. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.11.039

文献信息

• Synthesis and photophysical properties of α,ω-bis(terpyridine)oligothiophenes
  作者：Jan Svoboda、Pavla Štenclová、Filip Uhlík、Jiří Zedník、Jiří Vohlídal

  DOI：10.1016/j.tet.2010.11.039

  日期：2011.1

  Four novel fully pi-conjugated alpha,omega-bis(terpyridine)oligothiophenes characterized by NMR, IR, and HR-mass spectroscopy are presented and their electronic absorption/emission and redox properties are described based on both experiments and theoretical calculations. These compounds can be potentially utilized as building blocks for preparation of conjugated metallo-supramolecular polymers or dynamers and related functional materials. (C) 2010 Elsevier Ltd. All rights reserved.