1-phenylethenyl 2-methylpropanoate | 57767-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenylethenyl 2-methylpropanoate
• 英文别名: 1-phenylvinyl 2-methyl propanoate；1-Phenyl-1-vinyl-isobutyrat
• CAS: 57767-09-6
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: MXBFGIIOURQRDF-UHFFFAOYSA-N

物化性质

• 沸点：
  275.8±19.0 °C(Predicted)
• 密度：
  1.008±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Te-phenacyl 1-methylethanecarbotelluroate 反应 5.0h， 以40%的产率得到1-phenylethenyl 2-methylpropanoate
  参考文献：
  名称：

  Te-1-Acylmethyl and Te-1-Iminoalkyl Telluroesters: Synthesis and Thermolysis Leading to 1,3-Diketones and O-Alkenyl and O-Imino Esters

  摘要：

  A series of Te-1-acylmethyl carbotelluroates was prepared in good isolated yields from the reaction of potassium carbotelluroates with -haloketones in acetonitrile. Thermolysis of the telluroesters afforded vinyl esters in 20-50% yields, while treatment of the carbotellurorates with potassium t-butanolate led to 1,3-diketones in 30-75% yields with the liberation of black tellurium. The reaction of potassium carbotelluroates with -haloaceto oximes gave O-acyl oximes in 50-70% yields via Te-1-iminomethylcarbotelluroates.

  DOI：

  10.1080/10426501003769728

文献信息

• Synthesis of Enol Esters and Dimerization of Terminal Alkynes Catalyzed by Neutral and Cationic Vinylidene Ruthenium Complexes
  作者：Francis Verpoort、Tom Opstal

  DOI：10.1055/s-2003-37106

  日期：——

  In the current study Ru(II) vinylidene complexes of the general type: Cl 2 Ru=C=C(H)R}(PR' 3 )L (R = Ph, SiMe 3 , R'=Ph, Cyclohexyl (Cy) and L = phosphine or N-heterocyclic carbene) are synthesized and tested for the addition of carboxylic acids to terminal alkynes. A careful choice of the catalytic system, substrate and carboxylic acid gives access to alk-1-en-2-yl esters, alk-1-en-1-yl esters or

  在目前的研究中，一般类型的 Ru(II) 亚乙烯基配合物：Cl 2 Ru=C=C(H)R}(PR' 3 )L (R = Ph, SiMe 3 , R'=Ph, Cyclohexyl (Cy ) 和 L = 膦或 N-杂环卡宾) 被合成并测试羧酸与末端炔烃的加成。仔细选择催化体系、底物和羧酸可以获得 alk-1-en-2-yl 酯、alk-1-en-1-yl 酯或 enyne 二聚产物。此外，通过用 AgBF 4 处理其中一种配合物，对合成类似的 14 电子物种进行了扩展，并研究了其对催化活性和选择性的影响。
• Utilization of unsaturated esters as perfuming ingredients
  申请人：——

  公开号：US20030144173A1

  公开（公告）日：2003-07-31

  A compound of formula 1 wherein the symbol R′ represents a linear or branched, unsaturated or saturated hydrocarbon group having from 1 to 5 carbon atoms; R 1 , R 2 , R 3 , R 4 and R 5 represent, independently of each other, a hydrogen atom, a methyl, an ethyl or a methoxy group; R 6 and R 7 represent, independently of each other, a hydrogen atom, a methyl, ethyl, n-propyl or iso-propyl group; and wherein R 5 and R 6 , when taken together with the carbon atoms to which they are bound, may form a six-membered ring, is useful as perfuming ingredient for the preparation of perfuming compositions and perfumed products, to which it imparts odor notes of the floral and indol type without coloring problems in the final product.

  化合物1的化学式为：其中符号R'代表具有1至5个碳原子的线性或支链、不饱和或饱和的烃基；R1、R2、R3、R4和R5独立地代表氢原子、甲基、乙基或甲氧基基团；R6和R7独立地代表氢原子、甲基、乙基、正丙基或异丙基基团；当R5和R6与它们所连接的碳原子一起形成一个六元环时，该化合物可用作香料成分，用于制备香料组合物和带有花卉和吲哚型气味的香氛产品，不会在最终产品中出现着色问题。
• Acylation of β-oxoalkyltetracarbonylferrate(o). A novel route to enol ester
  作者：Take-aki Mitsudo、Yoshihisa Watanabe、Teruhiko Sasaki、Hiroshi Nakanishi、Masakazu Yamashita、Yoshinobu Takegami

  DOI：10.1016/s0040-4039(00)91484-9

  日期：——
• US7129206B2
  申请人：——

  公开号：US7129206B2

  公开（公告）日：2006-10-31
• <i>Te</i>-1-Acylmethyl and <i>Te</i>-1-Iminoalkyl Telluroesters: Synthesis and Thermolysis Leading to 1,3-Diketones and <i>O</i>-Alkenyl and <i>O</i>-Imino Esters
  作者：Shoho Nakaiida、Shinzi Kato、Osamu Niyomura、Masaru Ishida、Fumio Ando、Jugo Koketsu

  DOI：10.1080/10426501003769728

  日期：2010.5.27

  A series of Te-1-acylmethyl carbotelluroates was prepared in good isolated yields from the reaction of potassium carbotelluroates with -haloketones in acetonitrile. Thermolysis of the telluroesters afforded vinyl esters in 20-50% yields, while treatment of the carbotellurorates with potassium t-butanolate led to 1,3-diketones in 30-75% yields with the liberation of black tellurium. The reaction of potassium carbotelluroates with -haloaceto oximes gave O-acyl oximes in 50-70% yields via Te-1-iminomethylcarbotelluroates.