1,3-Bis-(2-fluorphenyl)-1-triazen | 68574-39-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-Bis-(2-fluorphenyl)-1-triazen
• 英文别名: 2-fluoro-N-[(2-fluorophenyl)diazenyl]aniline
• CAS: 68574-39-0
• 化学式: C₁₂H₉F₂N₃
• 分子量: 233.22
• InChiKey: FIHRSZZERFSLPY-UHFFFAOYSA-N

物化性质

• 沸点：
  307.3±52.0 °C(Predicted)
• 密度：
  1.23±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,3-Bis-(2-fluorphenyl)-1-triazen 以 乙醇 为溶剂， 反应 1.0h， 生成 4,6-O-ethylidene-N-((2',3-difluoro)-4-azobenzyl)-β-D-glucopyranosylamine
  参考文献：
  名称：

  Synthesis and Properties of Amphiphilic Photoresponsive Gelators for Aromatic Solvents

  摘要：

  A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partial trans-cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel-sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.

  DOI：

  10.1021/ol203294v
• 作为产物：
  描述：

  2-氟苯胺 在 盐酸 、 sodium acetate 、 sodium nitrite 作用下， 以 水 为溶剂， 生成 1,3-Bis-(2-fluorphenyl)-1-triazen
  参考文献：
  名称：

  Synthesis and Properties of Amphiphilic Photoresponsive Gelators for Aromatic Solvents

  摘要：

  A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partial trans-cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel-sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.

  DOI：

  10.1021/ol203294v

文献信息

• PERINGER P., MONATSH. CHEM., 1979, 110, NO 5, 1123-1126
  作者：PERINGER P.

  DOI：——

  日期：——
• JPH051007A
  申请人：——

  公开号：JPH051007A

  公开（公告）日：1993-01-08
• Synthesis and Properties of Amphiphilic Photoresponsive Gelators for Aromatic Solvents
  作者：Ramanathan Rajaganesh、Anesh Gopal、Thangamuthu Mohan Das、Ayyappanpillai Ajayaghosh

  DOI：10.1021/ol203294v

  日期：2012.2.3

  A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partial trans-cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel-sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.