6-Phenylhexa-2,5-dienoic acid | 76969-01-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6-Phenylhexa-2,5-dienoic acid
• 英文别名: 6-Phenyl-2,5-hexadiensaeure
• CAS: 76969-01-2
• 化学式: C₁₂H₁₂O₂
• 分子量: 188.226
• InChiKey: RJMKQAKJRNXGQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-Phenylhexa-2,5-dienoic acid 在 盐酸 、 五氯化磷 、 盐酸羟胺 、 sodium acetate 作用下， 以 苯 为溶剂， 反应 12.5h， 生成 (E)-4-Hydroxyamino-2-[(Z)-hydroxyimino]-7-phenyl-hept-6-enoic acid
  参考文献：
  名称：

  Kidwai, Mazahir M.; Khan, Naseem H., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1980, vol. 19, # 9, p. 802 - 803

  摘要：

  DOI：

文献信息

• PHOTOSENSITIVE RESIN COMPOSITION, PHOTOSENSITIVE ELEMENT COMPRISING THE SAME, PROCESS FOR PRODUCING RESIST PATTERN, AND PROCESS FOR PRODUCING PRINTED CIRCUIT BOARD
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP1174767A1

  公开（公告）日：2002-01-23

  A photosensitive resin composition comprising (A) a carboxyl group-containing binder polymer which contains styrene or a styrene derivative as a copolymerized constituent, (B) a photo-polymerization initiator, and (C) a photo-polymerizable compound which has in its molecule at least one polymerizable ethylenically unsaturated bond and comprises a compound represented by the general formula (I) wherein R1 is a hydrogen atom or a methyl group, A is an alkylenoxy group, Z1 is a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, an amino group, an alkylamino group, a dialkylamino group, a nitro group, a cyano group, a mercapto group, an alkylmercapto group, an allyl group, a hydroxyalkyl group, a carboxyalkyl group, an acyl group, an alkoxy group or a group containing an heterocyclic group, m is an integer of 4 to 20, and n is an integer of 0 to 5.

  一种光敏树脂组合物，包括(A)含羧基的粘合剂聚合物，该聚合物含有苯乙烯或苯乙烯衍生物作为共聚成分；(B)光聚合引发剂；和(C)光可聚合化合物，该化合物分子中至少有一个可聚合的乙烯基不饱和键，并包括通式(I)表示的化合物 其中 R1 是氢原子或甲基，A 是烷基苯氧基，Z1 是卤素原子、烷基、环烷基、芳基、氨基、烷基氨基、二烷基氨基、硝基、氰基巯基、烷基巯基、烯丙基、羟基烷基、羧基烷基、酰基、烷氧基或含有杂环基的基团，m 为 4 至 20 的整数，n 为 0 至 5 的整数。
• THERMOPLASTIC RESIN FILM AND PROCESS FOR PRODUCING THE SAME
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP1460101A1

  公开（公告）日：2004-09-22

  A heat-shrinkable resin film which has heat shrinkage in the maximum shrinkage direction of 20% or higher when a 10 cm × 10 cm square sample cut out thereof is immersed in hot water at 85°C for 10 seconds, pulled out, subsequently immersed in water at 25°C for 10 seconds, and then pulled out, characterized in that a content of nitrogen atoms in a surface of the film is 0.1% to 3.0% and the surface of the film has wet tension of 36 mN/m or higher; and a film roll obtained by winding up the heat-shrinkable resin film characterized in that when the rolled film is sampled at a first sampling part located up to 2 m apart from the end of the rolled film and at other sampling parts located after the first sampling part at intervals of about 100 m and an average content of nitrogen atoms of each sample is calculated, then the content of nitrogen atoms of each sample is within the ±0.8% range based on the above average content of nitrogen atoms.

  1.一种热收缩树脂薄膜，将其剪下的10厘米×10厘米的正方形样品浸入85℃的热水中10秒钟，捞出，然后浸入25℃的水中10秒钟，再捞出，其在最大收缩方向上的热收缩率为20％或更高，其特征在于薄膜表面的氮原子含量为0.1％至3.0% ，且薄膜表面的湿张力为 36 mN/m 或更高；以及通过卷绕热收缩树脂薄膜而得到的薄膜卷，其特征在于，当在距离卷绕薄膜末端最多 2 米的第一取样部位和位于第一取样部位之后、间隔约 100 米的其他取样部位对卷绕薄膜进行取样，并计算每个取样的氮原子平均含量时，根据上述氮原子平均含量，每个取样的氮原子含量均在±0.8%范围内。
• RESIN COMPOSITION, MOLDED ARTICLE, AND RESIN MODIFIER
  申请人：Kuraray Co., Ltd.

  公开号：EP3081593A1

  公开（公告）日：2016-10-19

  A resin composition including a hydrogenated block copolymer (A) including a polymer block (a) consisting of a structural unit derived from an aromatic vinyl compound and a polymer block (b) containing 1 to 100% by mass of a structural unit (b1) derived from farnesene and containing 99 to 0% by mass of a structural unit (b2) derived from a conjugated diene other than farnesene, 50 mol% or more of a carbon-carbon double bond in the polymer block (b) being hydrogenated; and at least one resin (B) selected from the group consisting of a polyphenylene ether-based resin, a styrene-based resin, an acrylic resin, a polycarbonate-based resin, and a polyamide-based resin.

  一种树脂组合物，包括氢化嵌段共聚物 (A)，其中聚合物嵌段 (a) 由衍生自芳香乙烯基化合物的结构单元和聚合物嵌段 (b) 组成，聚合物嵌段 (b) 含有 1% 至 100% 质量的衍生自茴香烯的结构单元 (b1)，以及 99% 至 0% 质量的衍生自茴香烯以外的共轭二烯的结构单元 (b2)，聚合物嵌段 (b) 中 50 mol% 或更多的碳碳双键被氢化；以及至少一种树脂 (B)，选自由聚苯醚基树脂、苯乙烯基树脂、丙烯酸树脂、聚碳酸酯基树脂和聚酰胺基树脂组成的组。
• MULTI-BLOCK COPOLYMER COMPOSITION OBTAINED BY MODIFICATION TREATMENT, AND FILM
  申请人：Zeon Corporation

  公开号：EP3677645A1

  公开（公告）日：2020-07-08

  A main purpose of the present invention is to provide a multi-block copolymer composition having good elasticity and excellent stress relaxation properties, as well as low permanent elongation. The present invention achieves the purpose by providing a multi-block copolymer composition obtained by a modification treatment, the composition including a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond to a block copolymer A; wherein the block copolymer A includes a block copolymer A1 having a specific primary structure and a block copolymer A2 having a specific primary structure, and the mass ratio (A1/A2) of the block copolymer A1 and the block copolymer A2 is 100/0 to 50/50.

  本发明的主要目的是提供一种多嵌段共聚物组合物，该组合物具有良好的弹性和优异的应力松弛性能，以及较低的永久伸长率。本发明通过提供一种通过改性处理获得的多嵌段共聚物组合物来实现上述目的，该组合物包括通过引入能够与嵌段共聚物 A 形成非共价键的官能团而形成的嵌段共聚物 B；其中嵌段共聚物 A 包括具有特定一级结构的嵌段共聚物 A1 和具有特定一级结构的嵌段共聚物 A2，嵌段共聚物 A1 和嵌段共聚物 A2 的质量比（A1/A2）为 100/0 至 50/50。
• Thermoplastic resin film and process for producing the same
  申请人：Hayakawa Satoshi

  公开号：US20050095379A1

  公开（公告）日：2005-05-05

  A heat-shrinkable resin film which has heat shrinkage in the maximum shrinkage direction of 20% or higher when a 10 cm×10 cm square sample cut out thereof is immersed in hot water at 85° C. for 10 seconds, pulled out, subsequently immersed in water at 25° C. for 10 seconds, and then pulled out, characterized in that a content of nitrogen atoms in a surface of the film is 0.1% to 3.0% and the surface of the film has wet tension of 36 mN/m or higher; and a film roll obtained by winding up the heat-shrinkable resin film characterized in that when the rolled film is sampled at a first sampling part located up to 2 m apart from the end of the rolled film and at other sampling parts located after the first sampling part at intervals of about 100 m and an average content of nitrogen atoms of each sample is calculated, then the content of nitrogen atoms of each sample is within the ±0.8% range based on the above average content of nitrogen atoms.

  一种热收缩树脂薄膜，将其剪下的 10 cm×10 cm 的正方形样品在 85℃的热水中浸泡 10 秒钟，捞出，然后在 25℃的水中浸泡 10 秒钟，再捞出，其在最大收缩方向上的热收缩率为 20% 或更高，其特征在于薄膜表面的氮原子含量为 0.1% 至 3.0% ，且薄膜表面的湿张力为 36 mN/m 或更高；以及通过卷绕热收缩树脂薄膜而得到的薄膜卷，其特征在于，当在距离卷绕薄膜末端最多 2 米的第一取样部位和位于第一取样部位之后、间隔约 100 米的其他取样部位对卷绕薄膜进行取样，并计算每个取样的氮原子平均含量时，根据上述氮原子平均含量，每个取样的氮原子含量在 ±0.8% 的范围内。