Cyclododecanon-azin | 1890-13-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Cyclododecanon-azin
• 英文别名: Cyclododecanonazin；Dicyclododecylazin；Cyclododecanazin；N-(cyclododecylideneamino)cyclododecanimine
• CAS: 1890-13-7
• 化学式: C₂₄H₄₄N₂
• 分子量: 360.627
• InChiKey: MTIYWYGVHDRHCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Cyclododecanon-azin 在 copper chromite 氢气 作用下， 生成 Azocyclododecan
  参考文献：
  名称：

  Meister,H., Justus Liebigs Annalen der Chemie, 1964, vol. 679, p. 83 - 94

  摘要：

  DOI：
• 作为产物：
  描述：

  cyclododecanone tosylhydrazone 在 sodium methylate 作用下， 以 二乙二醇二甲醚 为溶剂， 生成 Cyclododecanon-azin
  参考文献：
  名称：

  Casanova,J.; Waegell,B., Bulletin de la Societe Chimique de France, 1971, # 4, p. 1289 - 1295

  摘要：

  DOI：

文献信息

• Process for producing azine compounds and oxime compounds
  申请人：——

  公开号：US20030204084A1

  公开（公告）日：2003-10-30

  A process comprising allowing a peroxide compound represented by following Formula (2): 1 wherein R a , R b , R c and R d are the same or different and are each a hydrogen atom or a hydrocarbon group, and wherein R a and R b , R c and R d may be combined to form a ring together with the adjacent carbon atom, respectively, to react with ammonia and water to yield an azine compound represented by following Formula (3): 2 wherein R a , R b , R c and R d have the same meanings as defined above, or oxime compounds represented by following Formulae (4 a ) and/or (4 b ): 3 wherein R a , R b , R c and R d have the same meanings as defined above, in the presence of a nitrogen-containing cyclic compound constitutively having a skeleton represented by following Formula (A) in its ring: 4 wherein X is one of an oxygen atom and an —OR group, and wherein R is one of a hydrogen atom and a hydroxyl-protecting group. This process can produce an oxime compound or an azine compound useful as a material for oxime compounds from low-cost materials by easy and simple procedures.

  一种过程包括允许由以下式（2）表示的过氧化物化合物：其中Ra、Rb、Rc和Rd相同或不同，每个都是氢原子或烃基，且Ra和Rb、Rc和Rd可以分别与相邻的碳原子结合形成环，以与氨和水反应生成由以下式（3）表示的偶氮化合物：其中Ra、Rb、Rc和Rd的含义与上述定义相同，或者在具有以下式（A）中的环中具有骨架的含氮环化合物的存在下生成由以下式（4a）和/或（4b）表示的肟化合物：其中Ra、Rb、Rc和Rd的含义与上述定义相同，在X为氧原子和-OR基团之一，R为氢原子和羟基保护基团之一的情况下。该过程可以通过简单易行的步骤从低成本材料中产生用作肟化合物材料的肟化合物或偶氮化合物。
• Ionic hydrogenation of azines: An efficient synthesis of 1,2-dialkylhydrazines
  作者：Dario Perdicchia

  DOI：10.1016/j.tet.2023.133432

  日期：2023.6

  An efficient synthetic method of ionic hydrogenation of azine to the corresponding 1,2-dialkylhydrazines was accomplished. Reaction time was fast and isolation and purification of the 1,2-dialkylhydrazines were operationally simple. Yields were almost quantitative for most of the products with good functional group tolerance. Moreover, the byproduct of reduction gave the opportunity for the selective

  实现了吖嗪离子氢化为相应的 1,2-二烷基肼的有效合成方法。反应时间快，1,2-二烷基肼的分离和纯化操作简单。大多数具有良好官能团耐受性的产品的产量几乎是定量的。此外，还原的副产物为单酰肼的原位选择性合成提供了机会，从而扩展了所述合成方法的潜力。
• Functionalized polymers
  申请人：Bridgestone Corporation

  公开号：EP1803740A1

  公开（公告）日：2007-07-04

  A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer, and (ii) reacting the reactive polymer with an azine compound.

  一种制备官能化聚合物的方法，该方法包括以下步骤：(i) 使用镧系催化剂使共轭二烯单体聚合，形成反应聚合物；(ii) 使反应聚合物与偶氮化合物反应。
• Casanova,J.; Waegell,B., Bulletin de la Societe Chimique de France, 1971, # 4, p. 1289 - 1295
  作者：Casanova,J.、Waegell,B.

  DOI：——

  日期：——
• Method for preparing functionalized polymers
  申请人：Bridgestone Corporation

  公开号：EP1803740B1

  公开（公告）日：2009-03-18