N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethylethylenodiamine | 205391-45-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethylethylenodiamine
• 英文别名: N-(2-hydroxybenzyl)-N'-(2-hydroxyethyl)-N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine；2-[[2-[2-Hydroxyethyl(pyridin-2-ylmethyl)amino]ethyl-(pyridin-2-ylmethyl)amino]methyl]phenol；2-[[2-[2-hydroxyethyl(pyridin-2-ylmethyl)amino]ethyl-(pyridin-2-ylmethyl)amino]methyl]phenol
• CAS: 205391-45-3
• 化学式: C₂₃H₂₈N₄O₂
• 分子量: 392.501
• InChiKey: NUAPZQDZMSAIDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  29
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  72.7
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  manganese(II) perchlorate hexahydrate 、 N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethylethylenodiamine 在 三乙胺 、 sodium perchlorate monohydrate 作用下， 以 乙醇 为溶剂， 反应 1.08h， 以52.6%的产率得到N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethylethylenodiamine manganese(II) perchlorate
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity toward dye decolorization by manganese (II) mononuclear complexes

  摘要：

  Manganese(II) perchlorate reacts with L1=N,N,N'-tris(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine and L2=N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine in ethanol to form the corresponding complexes [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. Both complexes crystallize in the monoclinic system and space group P 2(1)/n. In [MnL1(H2O)](2+) and [MnL2](+) the manganese(II) ion is heptacoordinated and hexacoordinated, respectively. FTIR, elemental analysis and conductance measurements were all in accordance with the molecular structures of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. The ability of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4 to catalyze the oxidation of the dyes methyl orange and reactive orange 16 was studied in aqueous alkaline solution (carbonate/bicarbonate buffer). Both complexes were active catalysts promoting significant enhancement of dye solution decolorization in comparison to control reactions. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2012.12.036
• 作为产物：
  描述：

  2-(((2-((2-hydroxyethyl)amino)ethyl)imino)methyl)phenol 在 sodium tetrahydroborate 、 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 4.0h， 生成 N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethylethylenodiamine
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity toward dye decolorization by manganese (II) mononuclear complexes

  摘要：

  Manganese(II) perchlorate reacts with L1=N,N,N'-tris(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine and L2=N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine in ethanol to form the corresponding complexes [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. Both complexes crystallize in the monoclinic system and space group P 2(1)/n. In [MnL1(H2O)](2+) and [MnL2](+) the manganese(II) ion is heptacoordinated and hexacoordinated, respectively. FTIR, elemental analysis and conductance measurements were all in accordance with the molecular structures of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. The ability of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4 to catalyze the oxidation of the dyes methyl orange and reactive orange 16 was studied in aqueous alkaline solution (carbonate/bicarbonate buffer). Both complexes were active catalysts promoting significant enhancement of dye solution decolorization in comparison to control reactions. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2012.12.036

文献信息

• Neves, Ademir; Romanowski, Stela Maris de Moraes; Vencato, Ivo, Journal of the Chemical Society, Dalton Transactions, 1998, # 4, p. 617 - 622
  作者：Neves, Ademir、Romanowski, Stela Maris de Moraes、Vencato, Ivo、Mangrich, Antonio Salvio

  DOI：——

  日期：——
• Neves, Ademir; Maris de Moraes Romanowski, Stela; Vencato, Ivo, Journal of the Chemical Society, Dalton Transactions
  作者：Neves, Ademir、Maris de Moraes Romanowski, Stela、Vencato, Ivo、Mangrich, Antonio Salvio

  DOI：——

  日期：——
• Synthesis, characterization and catalytic activity toward dye decolorization by manganese (II) mononuclear complexes
  作者：Camila A. Wegermann、Paola Strapasson、Stela M.M. Romanowski、Adailton Bortoluzzi、Ronny R. Ribeiro、Fábio S. Nunes、Sueli M. Drechsel

  DOI：10.1016/j.apcata.2012.12.036

  日期：2013.3

  Manganese(II) perchlorate reacts with L1=N,N,N'-tris(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine and L2=N-(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)-N'-hydroxyethyl-ethylenodiamine in ethanol to form the corresponding complexes [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. Both complexes crystallize in the monoclinic system and space group P 2(1)/n. In [MnL1(H2O)](2+) and [MnL2](+) the manganese(II) ion is heptacoordinated and hexacoordinated, respectively. FTIR, elemental analysis and conductance measurements were all in accordance with the molecular structures of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4. The ability of [MnL1(H2O)](ClO4)(2) and [MnL2]ClO4 to catalyze the oxidation of the dyes methyl orange and reactive orange 16 was studied in aqueous alkaline solution (carbonate/bicarbonate buffer). Both complexes were active catalysts promoting significant enhancement of dye solution decolorization in comparison to control reactions. (C) 2013 Elsevier B.V. All rights reserved.