2,9-Dipyridin-4-yl-1,10-phenanthroline | 1094209-13-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,9-Dipyridin-4-yl-1,10-phenanthroline
• 英文别名: 2,9-dipyridin-4-yl-1,10-phenanthroline
• CAS: 1094209-13-8
• 化学式: C₂₂H₁₄N₄
• 分子量: 334.38
• InChiKey: KNDZGWLWFKOKAZ-UHFFFAOYSA-N

物化性质

• 沸点：
  577.9±45.0 °C(Predicted)
• 密度：
  1.280±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  、 2,9-Dipyridin-4-yl-1,10-phenanthroline 以 CH₂Cl₂ 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Coordination Chemistry-Assembled Porphyrinic Catenanes

  摘要：

  Non covalent [2]catenanes were synthesized in high yield as kinetic products or as thermodynamic products after completion of an equilibrium. These sophisticated architectures were assembled in two steps, from an oblique bis-zinc(II) porphyrin and two different dipyridyl chelates, by using Cu(I)-N interactions to assemble acyclic complexes and Zn(II)-N interactions to generate rings. H-1 NMR including 2D COSY and ROESY experiments were used to characterize each compound. Spectrophotometric titrations highlight the influence of geometry in terms of distances and angles in non covalent coordinated assemblies. In fact, it was proved that a perfect fit leads to highly stable coordination chemistry-assembled species.

  DOI：

  10.1021/ja910747h
• 作为产物：
  描述：

  吡啶-4-硼酸 、 2,9-二氯-1,10-菲罗啉 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 以84%的产率得到2,9-Dipyridin-4-yl-1,10-phenanthroline
  参考文献：
  名称：

  Coordination Chemistry-Assembled Porphyrinic Catenanes

  摘要：

  Non covalent [2]catenanes were synthesized in high yield as kinetic products or as thermodynamic products after completion of an equilibrium. These sophisticated architectures were assembled in two steps, from an oblique bis-zinc(II) porphyrin and two different dipyridyl chelates, by using Cu(I)-N interactions to assemble acyclic complexes and Zn(II)-N interactions to generate rings. H-1 NMR including 2D COSY and ROESY experiments were used to characterize each compound. Spectrophotometric titrations highlight the influence of geometry in terms of distances and angles in non covalent coordinated assemblies. In fact, it was proved that a perfect fit leads to highly stable coordination chemistry-assembled species.

  DOI：

  10.1021/ja910747h

文献信息

• Quantitative formation of a tetraporphyrin [2]catenane via copper and zinc coordination
  作者：Maryline Beyler、Valérie Heitz、Jean-Pierre Sauvage

  DOI：10.1039/b811013a

  日期：——

  A [2]catenane is formed quantitatively by mixing substituted 1,10-phenanthroline-based chelates with copper(I) acting as central template, the ring-forming reaction being based on the coordination of pyridinic bidentate ligands onto the zinc atoms of the four porphyrins surrounding the core of the molecule.

  通过将取代的1,10-菲咯啉基螯合物与作为中心模板的铜（I）混合，定量形成[2]环戊烷，成环反应基于吡啶二齿双齿配体与四个锌原子的配位作用分子核心周围的卟啉。
• Coordination Chemistry-Assembled Porphyrinic Catenanes
  作者：Maryline Beyler、Valérie Heitz、Jean-Pierre Sauvage

  DOI：10.1021/ja910747h

  日期：2010.3.31

  Non covalent [2]catenanes were synthesized in high yield as kinetic products or as thermodynamic products after completion of an equilibrium. These sophisticated architectures were assembled in two steps, from an oblique bis-zinc(II) porphyrin and two different dipyridyl chelates, by using Cu(I)-N interactions to assemble acyclic complexes and Zn(II)-N interactions to generate rings. H-1 NMR including 2D COSY and ROESY experiments were used to characterize each compound. Spectrophotometric titrations highlight the influence of geometry in terms of distances and angles in non covalent coordinated assemblies. In fact, it was proved that a perfect fit leads to highly stable coordination chemistry-assembled species.