di-sec-butyl-methyl-amine | 26819-66-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: di-sec-butyl-methyl-amine
• 英文别名: Di-sec-butyl-methyl-amin；Methyl-di-sek.-butyl-amin；di(sec-butyl)methylamine；Methyl-di-sec-butylamin；N-Methyl-di-s-butylamin；Methyldi-s-butylamin；N-butan-2-yl-N-methylbutan-2-amine
• CAS: 26819-66-9
• 化学式: C₉H₂₁N
• 分子量: 143.272
• InChiKey: ZBGZVIGUXBTBGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  di-sec-butyl-methyl-amine 、 碘甲烷 以 苯 为溶剂， 以38%的产率得到Di-sec-butyldimethylammonium Iodide
  参考文献：
  名称：

  Ring-opening reactions. 3. Mechanistic path vs. ring-strain control in elimination and substitution reactions of 1,1-dimethyl cyclic ammonium ions and their .alpha.,.alpha.'-dimethyl-substituted derivatives

  摘要：

  DOI：

  10.1021/jo00327a021
• 作为产物：
  描述：

  N-甲基异丁胺 、 丁酮 在 水 、 铂 作用下， 生成 di-sec-butyl-methyl-amine
  参考文献：
  名称：

  Skita; Keil; Havemann, Chemische Berichte, 1933, vol. 66, p. 1400,1409

  摘要：

  DOI：

文献信息

• BIS(6-METHYL-3-SULPHOPHENYL)PHENYLPHOSPHINE, AMMONIUM SALT THEREOF, AND METHOD FOR PRODUCING SAME
  申请人：HOKKO CHEMICAL INDUSTRY CO., LTD.

  公开号：US20160052947A1

  公开（公告）日：2016-02-25

  Provided are a water-soluble triarylphosphine for a palladium catalyst, which has high selectivity in a telomerization reaction and can be recovered with efficiency, an ammonium salt thereof, and a method for efficiently producing the same. Specifically, provided are bis(6-methyl-3-sulphophenyl)phenylphosphine; a bis(6-methyl-3-sulphonatophenyl)phenylphosphine diammonium salt obtained by reacting the phosphine with a tertiary amine having a total of 3 to 27 carbon atoms in groups bonded to one nitrogen atom; and a method for producing the same.

  提供了一种水溶性三芳基膦钯催化剂，其在缩聚反应中具有高选择性，并且可以高效回收，以及其铵盐，以及一种高效生产该化合物的方法。具体提供了双(6-甲基-3-磺酸苯基)苯基膦；通过将膦与含有3至27个碳原子的基团与一个氮原子键合的三级胺反应而得到的双(6-甲基-3-磺酸苯基)苯基膦二铵盐；以及一种生产该化合物的方法。
• 2-W-diaminocarboxylic acid compounds
  申请人：Rentzea Costin

  公开号：US20050085516A1

  公开（公告）日：2005-04-21

  2,ω-Diaminocarboxylic acid compounds of formula (I), where X, X 1 , Ar ω , Ar 2 and Y are as defined in claim 1, and their use as herbicides, are described.

  公式（I）中的2,ω-二氨基羧酸化合物，其中X，X1，Arω，Ar2和Y如权利要求1所定义，并描述了它们作为除草剂的用途。
• METHOD FOR PRODUCING 2,7-OCTADIEN-1-OL
  申请人：KURARAY CO., LTD.

  公开号：US20160046549A1

  公开（公告）日：2016-02-18

  Provided is a simple and industrially advantageous method for producing 2,7-octadien-1-ol, in which an expensive palladium catalyst is recovered in high efficiency and the reaction rate per atom of palladium is enhanced. Specifically, provided is a method for producing 2,7-octadien-1-ol by subjecting butadiene and water to a telomerization in the presence of a palladium catalyst containing a water-soluble triarylphosphine having two or more sulfonate groups in the molecule and a palladium compound, a tertiary amine, and carbon dioxide, including a step of mixing the telomerization solution obtained by the telomerization with an organic solvent having a dielectric constant at 25° C. of 2 to 18, followed by carrying out phase separation in the presence of carbon dioxide, thereby obtaining 2,7-octadien-1-ol from an organic phase while recovering an aqueous phase including the palladium catalyst. By this production method, the selectivity for 2,7-octadien-1-ol is enhanced.

  提供了一种简单且在工业上具有优势的生产2,7-辛二烯-1-醇的方法，其中昂贵的钯催化剂以高效率回收，并且增强了每个钯原子的反应速率。具体而言，提供了一种通过在存在包含具有两个或更多磺酸基团的水溶性三芳基膦和钯化合物、三级胺和二氧化碳的钯催化剂的情况下，使丁二烯和水经过缩聚反应来生产2,7-辛二烯-1-醇的方法，包括将通过缩聚反应获得的缩聚溶液与在25°C时具有介电常数为2到18的有机溶剂混合的步骤，然后在二氧化碳的存在下进行相分离，从而从有机相中获得2,7-辛二烯-1-醇，同时回收包括钯催化剂的水相。通过这种生产方法，对2,7-辛二烯-1-醇的选择性得到增强。
• 2-Phenyl-2h-pyridazine-3-ones
  申请人：——

  公开号：US20030162662A1

  公开（公告）日：2003-08-28

  The invention relates to 2-phenyl-2H-pyridazin-3-ones of the general formula I 1 in which the variables R 1 , R 2 , X, Y and Z have the following meanings: X is halogen; Y is fluorine or chlorine; Z is oxygen; R 1 is hydrogen or C 1 -C 4 -alkyl; R 2 is chlorine, OR 3 or NR 4 R 5 , in which R 3 , R 4 and R 5 have the meanings indicated in claim 1, Z can also be a group NR 6 if R 2 is a group OR 7 , in which R 6 and R 7 have the meanings indicated in claim 1, and to the agriculturally utilizable salts of compounds of the formula I. The invention furthermore relates to the use of compounds I and their salts as herbicides and/or for the desiccation and/or defoliation of plants, herbicidal compositions and compositions for the desiccation and/or defoliation of plants, which contain the compounds I and/or their salts as active substances, and processes for controlling undesired vegetation (weeds) and for the desiccation and/or defoliation of plants using the compounds I and/or their salts.

  该发明涉及一般式I中的2-苯基-2H-吡啶并三酮，其中变量R1、R2、X、Y和Z具有以下含义：X为卤素；Y为氟或氯；Z为氧；R1为氢或C1-C4-烷基；R2为氯、OR3或NR4R5，其中R3、R4和R5具有权利要求1中所指的含义，如果R2为OR7，则Z也可以是NR6基团，其中R6和R7具有权利要求1中所指的含义，并且该发明还涉及一般式I化合物的农业可利用盐。此外，该发明涉及将化合物I及其盐用作除草剂和/或用于植物脱水和/或落叶，含有化合物I和/或其盐作为活性物质的除草剂组合物和用于植物脱水和/或落叶的组合物，以及利用化合物I和/或其盐控制不受欢迎的植被（杂草）和对植物进行脱水和/或落叶的过程。
• [EN] BENZIMIDAZOLE DERIVATIVES AND USE THEREOF AS PEPTIDE DEFORMYLASE INHIBITORS<br/>[FR] DERIVES DE BENZIMIDAZOLE ET LEUR APPLICATION COMME INHIBITEURS DE LA PEPTIDE-DEFORMYLASE
  申请人：ARPIDA AS

  公开号：WO2005037272A1

  公开（公告）日：2005-04-28

  Benzimidazole compounds of the general formula (I) and pharmaceutically acceptable salts or esters thereof are peptide deformylase inhibitors useful in the treatment or prevention of infections and other diseases in which peptide deformylases are involved, especially in the treatment of bacterial and parasitic infections, for example infections fully or partly caused by microorganisms belonging to Staphylococcus, Enterococcus, Streptococcus, Haemophilus, Moraxella, Escherichia, Mycobacterium, Mycoplasma, Pseudomonas, Chlamydia, Rickettsia, Klebsiella, Shigella, Salmonella, Bordetella, Clostridium, helicobacter, Campylobacter, Legionella, or Neisseria.

  通用公式（I）的苯并咪唑化合物及其药用可接受的盐或酯是肽变形酶抑制剂，在治疗或预防涉及肽变形酶的感染和其他疾病方面具有用处，特别是在治疗细菌和寄生虫感染方面，例如完全或部分由属于葡萄球菌、肠球菌、链球菌、流感嗜血杆菌、嗜莫克菌、大肠杆菌、支原体、支原体、假单胞菌、沙眼衣原体、立克次体、克雷伯菌、志贺菌、沙门氏菌、百白破杆菌、梭菌、幽门螺杆菌、空肠弯曲菌、军团菌或莫拉克细菌引起的感染。