(2,6-Cl2C6H3NHCH2CH2)2NMe | 335248-24-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,6-Cl2C6H3NHCH2CH2)2NMe
• 英文别名: N'-[2-(2,6-dichloroanilino)ethyl]-N-(2,6-dichlorophenyl)-N'-methylethane-1,2-diamine
• CAS: 335248-24-3
• 化学式: C₁₇H₁₉Cl₄N₃
• 分子量: 407.17
• InChiKey: IRTMNSMJLOPGLW-UHFFFAOYSA-N

物化性质

• 沸点：
  540.3±50.0 °C(Predicted)
• 密度：
  1.385±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  27.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (2,6-Cl2C6H3NHCH2CH2)2NMe 以 甲苯 、 苯 为溶剂， 生成 [ZrCl2((2,6-Cl2C6H3NCH2CH2)2NMe)]
  参考文献：
  名称：

  锆和铪配合物的评价含有吸电子二酰氨/供体配体[（2,6-氯2 ç 6 ħ 3 NCH 2 CH 2）2 NCH 3）] 2 - 1-己烯的聚合

  摘要：

  三胺（2,6-Cl 2 C 6 H 3 NHCH 2 CH 2）2 NMe（H 2 [Ar Cl N 2 NMe]）可通过Pd催化2-溴-1,3-二氯苯之间的偶合反应制得。和（H 2 NCH 2 CH 2）2 NH，得到（2,6-Cl 2 C 6 H 3 NHCH 2 CH 2）2 NH，然后用MeI甲基化中心氮。制备的锆和ha络合物包括[Ar Cl N2 NMe] M（NMe 2）2（M = Hf或Zr），[Ar Cl N 2 NMe] MCl 2，[Ar Cl N 2 NMe] MMe 2，[Ar Cl N 2 NMe] HfCl（i-Bu） [氩氯ñ 2 NME] HfMe（I-丁基），和[氩氯ñ 2 NME]铪（I-丁基）2。X射线晶体结构显示[Ar Cl N 2 NMe] Hf（i-Bu）2为方锥，其中异丁基之一位于顶端位置。用{Ph 3 C} {B（C 6F 5）4 }，B（C

  DOI：

  10.1021/om040113h

文献信息

• New Yttrium Complexes Bearing Diamidoamine Ligands as Efficient and Diastereoselective Catalysts for the Intramolecular Hydroamination of Alkenes and Alkynes
  作者：Kai C. Hultzsch、Frank Hampel、Thomas Wagner

  DOI：10.1021/om030679q

  日期：2004.5.1

  amine donor and coordinated THF molecule in [Y(Mes2N2NMe)N(SiHMe2)2}(THF)] and both amine donors in [Y(2,6-Et2C6H3)2N2NMe}(o-C6H4CH2NMe2)] occupy axial positions. All complexes catalyze intramolecular hydroamination of aminoalkynes and aminoalkenes. Those having bis(trimethylsilyl)amido or (o-C6H4CH2NMe2) ligands show significantly higher activity than the complex containing the bis(dimethylsilyl)amido

  新的二氨基胺钇配合物[Y（Mes 2 N 2 NMe）N（SiHMe 2）2 }（THF）]（Mes 2 N 2 NMe 2 - =（2,4,6-Me 3 C 6 H 2 NCH 2 CH 2）2 NMe 2 -），[Y（Ar 2 N 2 NMe）N（SiMe 3）2 }]和[Y（Ar 2 N 2 NMe）（o -C 6 H 4 CH 2 NMe 2）]（氩2 Ñ 2 NME 2 - =（ArNCH 2 CH 2）2 NME 2 -用Ar = 2,4,6-ME 3 c ^ 6 ħ 2，2,6-的Et 2 ç 6 ħ 3，2，从相应的三酰胺基或三芳基钇配合物开始，通过转氨或消除芳烃反应制备6-Cl 2 C 6 H 3）。[Y（Mes 2 N 2 NMe）N（SiHMe 2）2 }（THF）]和[Y （2,6-Et 2X射线晶体学显示C 6 H 3）2 N 2 NMe}（o -C 6 H
• CH Bond Activation in Cations of the Type {[(2,4,6-Me₃C₆H₂NCH₂CH₂)₂NMe]ZrR}⁺ and a Simple Solution that Yields a Catalyst for the Living Polymerization of 1-Hexene
  作者：Richard R. Schrock、Peter J. Bonitatebus、Yann Schrodi

  DOI：10.1021/om000972f

  日期：2001.3.1

  [(MesNCH(2)CH(2))(2)NMe]ZrMe}[B(C6F5)(4)] and intermediates in the polymerization reaction of 1-hexene that are formed from it decompose as a consequence of CH activation in an ortho methyl group in the mesityl substituent. The intermediates in the polymerization reaction decompose significantly more readily than does [(MesrNCH(2)CH(2))(2)NMe]ZrMe }[B(C6F5)(4)] On the other hand, analogous cationic complexes that contain the [(2,6-Cl2C6H3NCH2 CH2)(2)NMe](2-) ligand a re re la ti very stable and will consume 1-hexene in a strictly first-order and apparently living manner at 0 degreesC in chlorobenzene.
• Evaluation of Zirconium and Hafnium Complexes that Contain the Electron-Withdrawing Diamido/Donor Ligand [(2,6-Cl₂C₆H₃NCH₂CH₂)₂NCH₃)]²^- for the Polymerization of 1-Hexene
  作者：Richard R. Schrock、Jennifer Adamchuk、Klaus Ruhland、L. Pia H. Lopez

  DOI：10.1021/om040113h

  日期：2005.2.1

  rate of consumption of 1-hexene followed a first-order dependence on 1-hexene (and hafnium or zirconium), and zirconium was faster than hafnium. Although poly[1-hexene] generated by the zirconium catalyst was characteristic of a living system, significant β-hydride elimination was observed in polymerizations by hafnium catalysts. The hafnium product of β-hydride elimination was observed to reinitiate

  三胺（2,6-Cl 2 C 6 H 3 NHCH 2 CH 2）2 NMe（H 2 [Ar Cl N 2 NMe]）可通过Pd催化2-溴-1,3-二氯苯之间的偶合反应制得。和（H 2 NCH 2 CH 2）2 NH，得到（2,6-Cl 2 C 6 H 3 NHCH 2 CH 2）2 NH，然后用MeI甲基化中心氮。制备的锆和ha络合物包括[Ar Cl N2 NMe] M（NMe 2）2（M = Hf或Zr），[Ar Cl N 2 NMe] MCl 2，[Ar Cl N 2 NMe] MMe 2，[Ar Cl N 2 NMe] HfCl（i-Bu） [氩氯ñ 2 NME] HfMe（I-丁基），和[氩氯ñ 2 NME]铪（I-丁基）2。X射线晶体结构显示[Ar Cl N 2 NMe] Hf（i-Bu）2为方锥，其中异丁基之一位于顶端位置。用Ph 3 C} B（C 6F 5）4 }，B（C