Polyamide molding compositions with improved optical properties and use of colorants therein
申请人:BASF SE
公开号:US11155692B2
公开(公告)日:2021-10-26
Disclosed is a method of reducing a haze value in molding compositions including use of colorants selected from anthraquinone colorants, benzimidazolone colorants and perinone colorants. The molding compositions include at least one polyamide and at least one compound of the general formula (I)
where x is 1, 2 or 3; R1 and R2 are mutually independently selected from hydrogen, linear C1-C7-alkyl, branched C3-C10-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C3-C12-cycloalkyl-C1-C4-alkyl, unsubstituted or substituted aryl and unsubstituted or substituted aryl-C1-C4-alkyl; and Z is selected from C3-C10-alkanediyl, unsubstituted or substituted arylene, unsubstituted or substituted arylene-C1-C4-alkylene-arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted heteroarylene-C1-C4-alkylene-heteroarylene, unsubstituted or substituted C5-C8-cyclo-alkylene, unsubstituted or substituted C5-C8-cycloalkylene-C1-C4-alkylene-C5-C8-cycloalkylene, unsubstituted or substituted heterocycloalkylene and unsubstituted or substituted heterocycloalkylene-C1-C4-alkylene-heterocycloalkylene.
本发明公开了一种降低模塑组合物雾度值的方法,包括使用选自蒽醌类着色剂、苯并咪唑酮类着色剂和哌啶酮类着色剂的着色剂。模塑组合物包括至少一种聚酰胺和至少一种通式 (I) 的化合物
其中 x 是 1、2 或 3;R1 和 R2 相互独立地选自氢、直链 C1-C7 烷基、支链 C3-C10 烷基、未取代或取代的 C3-C12 环烷基、未取代或取代的 C3-C12 环烷基-C1-C4-烷基、未取代或取代的芳基和未取代或取代的芳基-C1-C4-烷基;和 Z 选自 C3-C10- 烷二基、未取代或取代的芳基、未取代或取代的芳基-C1-C4-亚烷基芳基、未取代或取代的杂芳基、未取代或取代的杂芳基-C1-C4-亚烷基异芳基、未取代或取代的 C5-C8-Cyclo-alkylene 、未取代或取代的 C5-C8-Cycloalkylene-C1-C4-alkylene-C5-C8-Cycloalkylene 、未取代或取代的杂环亚烷基和未取代或取代的杂环亚烷基-C1-C4-alkylene-heterocycloalkylene。