Oct-1-en-4-ylsulfonylbenzene | 67100-47-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Oct-1-en-4-ylsulfonylbenzene
• CAS: 67100-47-4
• 化学式: C₁₄H₂₀O₂S
• 分子量: 252.378
• InChiKey: WTCFHNYBPHJFPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Oct-1-en-4-ylsulfonylbenzene 以92%的产率得到
  参考文献：
  名称：

  CORBEL B.; DECESARE J. M.; DURST T., CAN. J. CHEM., 1978, 56, NO 4, 505-511

  摘要：

  DOI：
• 作为产物：
  描述：

  (but-3-en-1-ylsulfonyl)benzene 以77%的产率得到
  参考文献：
  名称：

  CORBEL B.; DECESARE J. M.; DURST T., CAN. J. CHEM., 1978, 56, NO 4, 505-511

  摘要：

  DOI：

文献信息

• Corbel,B. et al., Canadian Journal of Chemistry, 1978, vol. 56, p. 505 - 511
  作者：Corbel,B. et al.

  DOI：——

  日期：——
• PROCESS FOR THE PREPARATION OF 2- ALKYL(ARYL)]SULFONYLBENZENE-SULFONYL CHLORIDES AND THEIR INTERMEDIATES
  申请人：Wyeth

  公开号：EP1442012A1

  公开（公告）日：2004-08-04
• [EN] PROCESS FOR THE PREPARATION OF 2-[ALKYL(ARYL)]SULFONYLBENZENE-SULFONYL CHLORIDES AND THEIR INTERMEDIATES<br/>[FR] PROCEDE DE PREPARATION DE CHLORURES DE 2-[ALKYL(ARYL)]SULFONYLBENZENE-SULFONYLE ET DE LEURS PRODUITS INTERMEDIAIRES
  申请人：WYETH CORP

  公开号：WO2003040087A1

  公开（公告）日：2003-05-15

  A process for the preparation of 2-[alkyl(aryl)]sulfonylbenzene sulfonyl chlorides of the formula (I), in which R is alkyl or aryl substituted at the ortho or meta positions with alkyl, aryl, NHAc or alkoxy, comprising the steps of: a) reacting 2-chloronitrobenzene, 2-fluoronitrobenzene or 2-bromonitrobenzene with a compound of the following formula: RSO2-M+ wherein R is defined above; and M is sodium, potassium, lithium, ammonium or quaternary ammonium, in a polar aprotic solvent at a temperature of about 50 to 190°C; b) reacting the material prepared in step (a) with hydrogen at a pressure of about 20 to about 60 psi in a polar aprotic solvent at a temperature of about 20 to about 60°C; and c) diazotizing the material prepared in step (b) with sodium nitrite in the presence of hydrochloric acid and reacting the resulting diazonium salt with sulfur dioxide in the presence of copper (I) or copper (II) compounds or a mixture thereof, in water.
• CORBEL B.; DECESARE J. M.; DURST T., CAN. J. CHEM., 1978, 56, NO 4, 505-511
  作者：CORBEL B.、 DECESARE J. M.、 DURST T.

  DOI：——

  日期：——