6,18-Dibromo-10,14-dioxapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4(9),5,7,11,15(20),16,18-nonaene | 638132-14-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 6,18-Dibromo-10,14-dioxapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4(9),5,7,11,15(20),16,18-nonaene
• CAS: 638132-14-6
• 化学式: C₁₈H₈Br₂O₂
• 分子量: 416.068
• InChiKey: OZOVBYFGDTYBIE-UHFFFAOYSA-N

物化性质

• 沸点：
  314.6±22.0 °C(Predicted)
• 密度：
  1.858±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6,18-Dibromo-10,14-dioxapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4(9),5,7,11,15(20),16,18-nonaene 在 copper(l) iodide 、 四(三苯基膦)钯 potassium phosphate 、 sodium carbonate 、 trans-1,2-cyclohexanediamine 作用下， 以 1,4-二氧六环 、 乙二醇二甲醚 、 水 、 甲苯 为溶剂， 反应 18.0h， 生成 3-(18-Carbazol-9-yl-10,14-dioxapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4(9),5,7,11,15(20),16,18-nonaen-6-yl)-6,9-diphenylcarbazole
  参考文献：
  名称：

  EP2301921

  摘要：

  公开号：
• 作为产物：
  描述：

  1,5-二溴-2,4-二氟苯 在 四(三苯基膦)钯 N-溴代丁二酰亚胺(NBS) 、 三溴化硼 、 sodium carbonate 、 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 、 乙二醇二甲醚 、 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.0h， 生成 6,18-Dibromo-10,14-dioxapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4(9),5,7,11,15(20),16,18-nonaene
  参考文献：
  名称：

  HALOGEN COMPOUND, POLYCYCLIC COMPOUND, AND ORGANIC ELECTROLUMINESCENCE ELEMENT COMPRISING THE POLYCYCLIC COMPOUND

  摘要：

  公开号：

  EP2301926B1

文献信息

• Material for organic electroluminescence device and organic electroluminescence device using the same
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10020454B2

  公开（公告）日：2018-07-10

  Provided are an organic electroluminescence device, which shows high luminous efficiency, is free of any pixel defect, and has a long lifetime, and a material for an organic electroluminescence device for realizing the device. The material for an organic electroluminescence device is a compound having a π-conjugated heteroacene skeleton crosslinked with a carbon atom, nitrogen atom, oxygen atom, or sulfur atom. The organic electroluminescence device has one or more organic thin film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin film layers contains the material for an organic electroluminescence device.

  本文提供了一种发光效率高、无任何像素缺陷且使用寿命长的有机电致发光器件，以及一种用于实现该器件的有机电致发光器件材料。有机电致发光器件的材料是一种具有与碳原子、氮原子、氧原子或硫原子交联的π-共轭杂芳烯骨架的化合物。有机电致发光器件具有一层或多层有机薄膜层，包括阴极和阳极之间的发光层，有机薄膜层中至少有一层含有有机电致发光器件的材料。
• HALOGEN COMPOUND, POLYCYCLIC COMPOUND, AND ORGANIC ELECTROLUMINESCENCE ELEMENT COMPRISING THE POLYCYCLIC COMPOUND
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2301926B1

  公开（公告）日：2018-11-21
• EP2301921A1
  申请人：——

  公开号：EP2301921A1

  公开（公告）日：2011-03-30
• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：KATO Tomoki

  公开号：US20090309488A1

  公开（公告）日：2009-12-17

  Provided are an organic electroluminescence device, which shows high luminous efficiency, is free of any pixel defect, and has a long lifetime, and a material for an organic electroluminescence device for realizing the device. The material for an organic electroluminescence device is a compound having a n-conjugated heteroacene skeleton crosslinked with a carbon atom, nitrogen atom, oxygen atom, or sulfur atom. The organic electroluminescence device has one or more organic thin film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin film layers contains the material for an organic electroluminescence device.
• POLYCYCLIC COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICE EMPLOYING THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20130020563A1

  公开（公告）日：2013-01-24

  Provided are a polycyclic compound of a compound having such a structure that two benzene rings bond to a central benzene ring each other to form a fused ring and another fused ring bonds to a terminal thereof, and an organic electroluminescence device including one or more organic thin film layers containing a light emitting layer between a cathode and an anode, in which at least one of the organic thin film layers includes the polycyclic compound of the present invention. The organic electroluminescence device has high luminous efficiency, no defect in pixels, and long lifetime. In addition, provided is a polycyclic compound realizing the organic electroluminescence device.