catechol diacrylate | 50283-25-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: catechol diacrylate
• 英文别名: 1,2-Benzenediol, O,O'-diacryloyl-；(2-prop-2-enoyloxyphenyl) prop-2-enoate
• CAS: 50283-25-5
• 化学式: C₁₂H₁₀O₄
• 分子量: 218.209
• InChiKey: BKZFVHIMLVBUGP-UHFFFAOYSA-N

物化性质

• 熔点：
  35-36 °C(Solv: ligroine (8032-32-4))
• 沸点：
  353.0±12.0 °C(Predicted)
• 密度：
  1.161±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  catechol diacrylate 以 氯仿 为溶剂， 反应 18.0h， 生成 mono(2,2'-((1,2-phenylenebis(oxy))bis(3-oxopropane-3,1-diyl))bis(6,7-dimethoxy-2-methyl-1,2,3,4-tetrahydroisoquinolin-2-ium)) monoiodide
  参考文献：
  名称：

  Stenlake; Waigh; Dewar, European Journal of Medicinal Chemistry, 1983, vol. 18, # 3, p. 273 - 276

  摘要：

  DOI：
• 作为产物：
  描述：

  邻苯二酚 、 丙烯酰氯 在 三乙胺 作用下， 以 乙醚 为溶剂， 反应 0.5h， 以45%的产率得到catechol diacrylate
  参考文献：
  名称：

  Stenlake; Waigh; Dewar, European Journal of Medicinal Chemistry, 1983, vol. 18, # 3, p. 273 - 276

  摘要：

  DOI：

文献信息

• Backbone‐Enabled Directional Peptide Macrocyclization through Late‐Stage Palladium‐Catalyzed δ‐C(sp ² )−H Olefination
  作者：Zengbing Bai、Chuangxu Cai、Zonglun Yu、Huan Wang

  DOI：10.1002/anie.201807953

  日期：2018.10.15

  allows facile macrocyclization of peptides in the N‐to‐C direction. Combined with the previously developed β‐C(sp3)−H arylation method for peptide macrocyclization in the C‐to‐N direction, a pair of palladium‐catalyzed reactions were obtained that are directionally orthogonal, and the first example of one‐pot synthesis of bicyclic peptides via Pd‐catalyzed β‐C(sp3)−H and δ‐C(sp2)−H activation is demonstrated

  用于肽大环化的CH活化方法具有提供模拟肽和环状肽具有扩大的结构多样性的潜力。现在，已经开发出了一种通过后期钯催化苯丙氨酸残基的δ-C（sp 2）-H烯化反应来实现高度通用的肽大环化策略。该方法利用肽主链酰胺作为内部指导基团，并允许肽在N-C方向上容易地进行大环化。结合先前开发的β-C（sp 3）-H芳基化方法在C到N方向进行肽大环化，获得了一对钯催化的，方向正交的反应，这是第一个单罐的例子钯催化的β-C（sp 3）合成双环肽）-H和δ-C（sp 2）-H活化得到了证明。
• Composition for film formation and material for insulating film formation
  申请人：JSR CORPORATION

  公开号：US20020172652A1

  公开（公告）日：2002-11-21

  A composition for film formation capable of forming a coating film excellent in low dielectric constant characteristics, cracking resistance, modulus of elasticity, and adhesion to substrates and useful as an interlayer insulating film material in semiconductor devices, etc. The composition for film formation contains (A) at least one member selected from an aromatic polyarylene and an aromatic poly (arylene ether), (B) a polyvinylsiloxane, and (C) an organic solvent.

  一种用于制备薄膜的组合物，能够形成具有低介电常数特性、抗开裂性、弹性模量和对基底的附着力优异的涂层膜，并可用作半导体器件中的层间绝缘膜材料等。该制膜组合物包含（A）至少一种选自芳香族聚芳烃和芳香族聚（芳烃醚）的成员，（B）聚乙烯基硅氧烷和（C）有机溶剂。
• LAMINATE AND METHOD FOR FORMATION THEREOF, INSULATING FILM, SEMICONDUCTOR DEVICE, AND COMPOSITION FOR FORMING FILM
  申请人：JSR Corporation

  公开号：EP1679184A1

  公开（公告）日：2006-07-12

  A laminate having a low relative dielectric constant and exhibiting excellent adhesion, a method of forming the laminate, an insulating film, a semiconductor device, and a film-forming composition are provided. A laminate according to the invention includes: a first silica-based film; a second silica-based film; and an organic film, wherein the second silica-based film includes a monovalent organic group containing a carbon-carbon double bond or a carbon-carbon triple bond. A method of forming a laminate according to the invention includes: forming a first coating for a first silica-based film on a substrate; forming a second coating for a second silica-based film on the first coating, the second coating including a monovalent organic group containing a carbon-carbon double bond or a carbon-carbon triple bond; forming a third coating for an organic film on the second coating; and curing a multilayer film including the first to third coatings.

  本发明提供了一种具有低相对介电常数并表现出优异附着力的层压板、一种形成该层压板的方法、一种绝缘膜、一种半导体器件和一种成膜组合物。 根据本发明的层压板包括：第一硅基薄膜；第二硅基薄膜；以及有机薄膜，其中第二硅基薄膜包括含有碳碳双键或碳碳三键的一价有机基团。 根据本发明形成层压板的方法包括：在基底上形成第一硅基薄膜的第一涂层；在第一涂层上形成第二硅基薄膜的第二涂层，第二涂层包括含有碳碳双键或碳碳三键的一价有机基团；在第二涂层上形成有机薄膜的第三涂层；以及固化包括第一至第三涂层的多层薄膜。
• Photocurable composition, pattern forming method, and method for manufacturing device
  申请人：FUJIFILM Corporation

  公开号：US10739678B2

  公开（公告）日：2020-08-11

  Provided are a photocurable composition capable of suppressing both deformation (change in line width roughness (ΔLWR)) of a pattern after etching and breakage of a pattern after etching, a pattern forming method, and a method for manufacturing a device. Disclosed is a photocurable composition including a monofunctional (meth)acrylate represented by the following General Formula (I) and a photopolymerization initiator, where R1 represents a hydrogen atom or a methyl group; R2 represents an alkyl group which may be substituted with a fluorine atom, R3 represents a hydrogen atom, a linear alkyl group which may be substituted with a fluorine atom, or a branched alkyl group which may be substituted with a fluorine atom, R4 to R8 each independently represent a hydrogen atom, a halogen atom, a linear alkyl group having 1 to 4 carbon atoms, or a branched alkyl group having 3 or 4 carbon atoms, the total number of carbon atoms included in R2 and R3 is 1 to 6, and R2 and R3, or R2 and R4 may be bonded to each other and form a ring.

  本发明提供了一种能够同时抑制蚀刻后图案变形（线宽粗糙度（ΔLWR）的变化）和蚀刻后图案破损的光固化组合物、一种图案形成方法和一种制造设备的方法。本发明公开了一种光固化组合物，该组合物包括由下式（I）表示的单官能团（甲基）丙烯酸酯和光聚合引发剂，其中 R1 代表氢原子或甲基；R2 代表可被氟原子取代的烷基，R3 代表氢原子、可被氟原子取代的直链烷基或可被氟原子取代的支链烷基，R4 至 R8 各自独立地代表氢原子、卤素原子、具有 1 至 4 个碳原子的直链烷基或具有 3 或 4 个碳原子的支链烷基，R2 和 R3 中包含的碳原子总数为 1 至 6，且 R2 和 R3 或 R2 和 R4 可相互键合并形成环。
• Polymer, process for production, composition for film formation containing the same, method of film formation, and insulating film
  申请人：JSR CORPORATION

  公开号：US20020161173A1

  公开（公告）日：2002-10-31

  a composition for film formation which can be cured in a short time period and give a film having a low dielectric constant and excellent in heat resistance, adhesion and cracking resistance, a polymer for use in the composition and a process for producing the polymer. The composition prepared by dissolving the polymer having specific repeating units in a solvent has excellent film-forming properties. The polymer has repeating units represented by the following general formula (1): 1 wherein Z and Y are as defined hereinabove.

  一种可在短时间内固化并能形成具有低介电常数和优异耐热性、粘附性和抗裂性的薄膜的成膜组合物、一种用于该组合物的聚合物以及一种生产该聚合物的工艺。将具有特定重复单元的聚合物溶解在溶剂中制备的组合物具有优异的成膜性能。该聚合物具有由以下通式（1）表示的重复单元： 1 其中 Z 和 Y 如上文所定义。