3,5,3',5'-四(3-吡啶-3-基苯基)[1,1']联苯 | 1009033-94-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,5,3',5'-四(3-吡啶-3-基苯基)[1,1']联苯
• 英文名称: 3,5,3',5'-tetra(m-pyrid-3-yl)phenyl[1,1']biphenyl
• 英文别名: 3,5,3',5'-tetra(m-pyridin-3-yl)phenyl-[1,1']biphenyl；3,3',5,5'-Tetrakis[3-(3-pyridyl)phenyl]-1,1'-biphenyl；3-[3-[3-[3,5-bis(3-pyridin-3-ylphenyl)phenyl]-5-(3-pyridin-3-ylphenyl)phenyl]phenyl]pyridine
• CAS: 1009033-94-6
• 化学式: C₅₆H₃₈N₄
• 分子量: 766.945
• InChiKey: JOWLUTHJWQYFOH-UHFFFAOYSA-N

物化性质

• 熔点：
  191℃

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  60
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-[3-(4,4,5,5-四甲基-1,3,2-二氧代硼戊环-2-基)苯基]吡啶 、 3,3′,5,5′-四溴-1,1′-联苯 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 24.0h， 以75%的产率得到3,5,3',5'-四(3-吡啶-3-基苯基)[1,1']联苯
  参考文献：
  名称：

  新型的四吡啶苯武装的联苯作为磷光OLED的电子传输材料。

  摘要：

  设计并合成了一系列四吡啶基苯酚联苯衍生物，作为基于fac-tris（2-苯基吡啶）铱（Ir（PPy）3）的绿色磷光有机电子的电子输运和激子和空穴阻挡层发光器件（OLED），与三（8-羟基喹啉）铝（Alq3）的电子传输层和2,9-二甲基-4的激子和空穴阻挡层相比，效率得到了提高，7-二苯基菲咯啉（BCP）。

  DOI：

  10.1021/ol7030872

文献信息

• BIPIRIDINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT CONTAINING THE SAME
  申请人：Kimura Masato

  公开号：US20100327265A1

  公开（公告）日：2010-12-30

  The present invention provides a new bipyridine derivative which is suitable for an electron transport material of an organic electronics element and which has bipyridyl central rings as a core, and further provides an organic electroluminescence element containing the derivative. The bipyridine derivative is expressed by the following general formula. (where A 1 , A 2 : represent an aromatic heterocyclic group (except for a carbazolyl group) and an aromatic hydrocarbon group and the aromatic heterocyclic group may be combined; a, b=1 or 2; Ar 1 , Ar 2 : represent a divalent or trivalent aromatic hydrocarbon group which may be substituted by hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group; B 1 , B 2 : represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; and ring E 1 , ring E 2 : represent a pyridine ring, and may have hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group.), which is used as an electron transport material.

  本发明提供了一种新的联吡啶衍生物，适用于有机电子元件的电子传输材料，并且以联吡啶中心环为核心，并进一步提供了含有该衍生物的有机电致发光元件。该联吡啶衍生物由以下通用公式表示（其中A1、A2：表示芳香杂环基团（除了羰基苯胺基团）和芳香烃基团，芳香杂环基团可以结合；a、b=1或2；Ar1、Ar2：表示可以被氢原子、烷基基团、环烷基基团或烷氧基取代的二价或三价芳香烃基团；B1、B2：表示氢原子、烷基基团、环烷基基团、烷氧基、芳香烃基团或芳香杂环基团；环E1、环E2：表示吡啶环，并且可能带有氢原子、烷基基团、环烷基基团或烷氧基），该衍生物用作电子传输材料。
• [EN] NEW IRIDIUM COMPLEX AND ORGANIC LIGHT-EMITTING DEVICE CONTAINING SAME<br/>[FR] NOUVEAU COMPLEXE D'IRIDIUM ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE CONTENANT CELUI-CI
  申请人：CANON KK

  公开号：WO2011070990A1

  公开（公告）日：2011-06-16

  There is provided a new iridium complex including phenylpyridine as a ligand, the iridium complex having a basic skeleton in which a triazine ring is bonded to a phenyl ring.

  提供了一种新的铱配合物，其中包括苯基吡啶作为配体，该铱配合物具有一个基本骨架，三嗪环与苯环结合在一起。
• Bipiridine derivative and organic electroluminescence element containing the same
  申请人：Yamagata Promotional Organization for Industrial Technology

  公开号：EP2275409A1

  公开（公告）日：2011-01-19

  The present invention provides a new bipyridine derivative which is suitable for an electron transport material of an organic electronics element and which has bipyridyl central rings as a core, and further provides an organic electroluminescence element containing the derivative. The bipyridine derivative is expressed by the following general formula. (where A1, A2: represent an aromatic heterocyclic group (except for a carbazolyl group) and an aromatic hydrocarbon group and the aromatic heterocyclic group may be combined; a, b = 1 or 2; Ar1, Ar2: represent a divalent or trivalent aromatic hydrocarbon group which may be substituted by hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group; B1, B2: represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; and ring E1, ring E2: represent a pyridine ring, and may have hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group.), which is used as an electron transport material.

  本发明提供了一种新的联吡啶衍生物，适用于有机电子元件的电子传输材料，并且具有联吡啶中心环作为核心，并进一步提供了含有该衍生物的有机电致发光元件。联吡啶衍生物由以下一般公式表示（其中A1、A2：代表芳香杂环基团（除了吲哚基团）和芳香烃基团，芳香杂环基团可以结合；a，b = 1或2；Ar1，Ar2：代表可由氢原子、烷基、环烷基或烷氧基取代的二价或三价芳香烃基团；B1，B2：代表氢原子、烷基、环烷基、烷氧基、芳香烃基团或芳香杂环基团；环E1，环E2：代表吡啶环，并且可以具有氢原子、烷基、环烷基或烷氧基）。该衍生物用作电子传输材料。
• LIGHT EMITTING DEVICE AND DISPLAY UNIT
  申请人：HARADA Shigeyuki

  公开号：US20120032115A1

  公开（公告）日：2012-02-09

  A light emitting device having a substrate and a luminous layer provided overlying the substrate, which includes a semiconductor nanocrystal to which a carbazole derivative is coordination-bonded or attached, the carbazole derivative having aromatic rings of a compound represented by the chemical structure 1 having one to three substitution groups: where Ar 1 and Ar 2 independently represent substituted or non-substituted aryl groups that may share a linkage to form a ring with a benzene ring, heterocyclic groups, and hydrogen atoms and Ar 3 represents a substituted or non-substituted aryl group, the one to three substitution groups represented by the chemical structure 2: —X—Y—Z  Chemical Structure 2 where X represents a methylene group, a carbonyloxy group, an oxycarbonyl group, a carbonyl group, an oxygen atom, and a sulfur atom, Y represents a substituted or non-substituted alkylene group, and Z represents a carboxyl group, a hydroxyl group, and a thiol group.

  具有基板和位于基板上方的发光层的发光装置，其中发光层包括半导体纳米晶体，该半导体纳米晶体与联配或附加有一种咔唑衍生物，该咔唑衍生物具有化学结构式1所表示的化合物的芳香环，该化合物具有一至三个取代基：其中，Ar1和Ar2独立地表示取代或非取代芳基，可能与苯环共享连接以形成环，杂环基和氢原子，Ar3表示取代或非取代芳基，化学结构式2表示的一至三个取代基如下：—X—Y—Z  化学结构式2其中，X表示甲基基团、羰基氧基团、氧羰基基团、羰基基团、氧原子和硫原子，Y表示取代或非取代的烷基基团，Z表示羧基、羟基和硫醇基。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：KAWAMURA Masahiro

  公开号：US20150115225A1

  公开（公告）日：2015-04-30

  An organic electroluminescence device includes: a cathode; an anode; and an organic thin-film layer disposed between the cathode and the anode, the organic thin-film layer having one or more layers including an emitting layer, in which the emitting layer includes a first material represented by the following formula (1) and a second material in a form of a fluorescent dopant material.

  一种有机电致发光器件包括：阴极；阳极；以及位于阴极和阳极之间的有机薄膜层，该有机薄膜层具有一个或多个层，包括一个发射层，其中该发射层包括以下公式（1）表示的第一材料和荧光掺杂材料的形式的第二材料。