2-Aminoaethyl-borsaeure | 2932-96-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硼酸衍生物
• 英文名称: 2-Aminoaethyl-borsaeure
• 英文别名: 2-Aminoethylboronic acid
• CAS: 2932-96-9
• 化学式: C₂H₈BNO₂
• 分子量: 88.902
• InChiKey: CYRNMIDKGLHITL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.58
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.5
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N,N-bis(trimethylsilyl)-ethyleneamine 在 dimethyl sulfide borane 、 水 作用下， 以 二氯甲烷 、 四氢呋喃 为溶剂， 反应 2.0h， 生成 2-Aminoaethyl-borsaeure 、 1-氨基乙基硼酸
  参考文献：
  名称：

  Synthesis and NMR properties of derivatives of 5,6-dihydroborauracil and 5,6-dihydroborathymine

  摘要：

  Novel boron compounds, a series of 4-hydroxy-5,6-dihydroborauracil and 4-hydroxy-5,6-dihydroborathymine derivatives containing various substituents at 3-, 5-and 6-positions, is presented. The spectroscopic properties, along with analyses of NMR-controlled boron compound-alcohol and boron compound-amine interactions, proves the existence of sp(3)-hybridized, stable B, B-bis-methoxy-5,6-dihydroborauracils and pyridine-/n-butylamine-5,6-dihydroborauracils ate-complexes in solution. (C) 2009 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.bioorg.2009.07.004

文献信息

• Synthesis and NMR properties of derivatives of 5,6-dihydroborauracil and 5,6-dihydroborathymine
  作者：Tomasz Ruman、Karolina Długopolska、Anna Kuśnierz、Wojciech Rode

  DOI：10.1016/j.bioorg.2009.07.004

  日期：2009.10

  Novel boron compounds, a series of 4-hydroxy-5,6-dihydroborauracil and 4-hydroxy-5,6-dihydroborathymine derivatives containing various substituents at 3-, 5-and 6-positions, is presented. The spectroscopic properties, along with analyses of NMR-controlled boron compound-alcohol and boron compound-amine interactions, proves the existence of sp(3)-hybridized, stable B, B-bis-methoxy-5,6-dihydroborauracils and pyridine-/n-butylamine-5,6-dihydroborauracils ate-complexes in solution. (C) 2009 Elsevier Inc. All rights reserved.