N-(4-biphenylyl)-N-(9,9-dimethyl-9H-fluoren-2-yl)-9-phenyl-9H-carbazol-3-amine | 866119-16-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-biphenylyl)-N-(9,9-dimethyl-9H-fluoren-2-yl)-9-phenyl-9H-carbazol-3-amine
• 英文别名: N-(9,9-dimethylfluoren-2-yl)-9-phenyl-N-(4-phenylphenyl)carbazol-3-amine
• CAS: 866119-16-6
• 化学式: C₄₅H₃₄N₂
• 分子量: 602.778
• InChiKey: WNKDSFXZPWGXFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-碘-9苯基咔唑 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 10.0h， 生成 N-(4-biphenylyl)-N-(9,9-dimethyl-9H-fluoren-2-yl)-9-phenyl-9H-carbazol-3-amine
  参考文献：
  名称：

  Carbazole-based compound and organic light-emitting diode comprising the same

  摘要：

  公开号：

  EP2554545B1

文献信息

• COMPOSITION FOR OPTOELECTRONIC DEVICE AND ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20200266357A1

  公开（公告）日：2020-08-20

  A composition for an organic optoelectronic device an organic optoelectronic device, and a display device, the composition including a first compound; a second compound; and a third compound, wherein the first compound, the second compound, and the third compound are different from each other, the first compound is represented by Chemical Formula I, the second compound is represented by Chemical Formula I, and the third compound is represented by Chemical Formula II or Chemical Formula III:

  一种用于有机光电器件的组合物，有机光电器件以及显示器件，该组合物包括第一化合物；第二化合物；和第三化合物，其中第一化合物，第二化合物和第三化合物彼此不同，第一化合物由化学式I表示，第二化合物由化学式I表示，第三化合物由化学式II或化学式III表示。
• [EN] ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPOSÉ ORGANIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2018167606A1

  公开（公告）日：2018-09-20

  A novel organic compound is provided. That is, a novel organic compound that is effective in improving reliability of a light-emitting element is provided. The organic compound includes a condensed ring including a pyrimidine ring and is represented by General Formula (G1). In General Formula (G1), A represents a group having 6 to 100 carbon atoms and includes at least one of an aromatic ring and a heteroaromatic ring. The aromatic ring and the heteroaromatic ring may each include a substituent. Furthermore, Q represents oxygen or sulfur. A ring X represents a substituted or unsubstituted naphthalene ring or a substituted or unsubstituted phenanthrene ring.

  提供了一种新的有机化合物。也就是说，提供了一种能够提高发光元件可靠性的新型有机化合物。该有机化合物包括一个包含嘧啶环的缩合环，并由通用式（G1）表示。在通用式（G1）中，A代表含有6至100个碳原子的基团，并且至少包括一个芳香环和一个杂芳环中的一个。芳香环和杂芳环中每个都可以包括一个取代基。此外，Q代表氧或硫。环X代表取代或未取代的萘环或取代或未取代的菲环。
• [EN] LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] ÉLÉMENT ÉLECTROLUMINESCENT, APPAREIL ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2020053689A1

  公开（公告）日：2020-03-19

  To provide a light-emitting device not only including a light-emitting layer in which energy is efficiently transferred from a host material to a guest material but also having high reliability. The light-emitting device not only includes a light-emitting layer in which the T1 levels and the S1 levels of a host material and a guest material fall within certain ranges so that energy can be efficiently transferred from the host material to the guest material and but also has improved reliability.

  为了提供一种发光装置，不仅包括一个发光层，其中能量从主体材料有效地转移到客体材料，而且具有很高的可靠性。这种发光装置不仅包括一个发光层，其中主体材料和客体材料的T1能级和S1能级落在一定范围内，以便能量可以有效地从主体材料转移到客体材料，而且还具有改善的可靠性。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20170092881A1

  公开（公告）日：2017-03-30

  A novel organometallic complex with high reliability is provided. The organometallic complex includes iridium and ligands coordinated to the iridium. The ligands are a dipivaloylmethanato ligand and a ligand including a phenyl group to which an alkyl group is bonded and which is bonded to the 5-position of a pyrazine ring. In the formula, Ar represents a substituted or unsubstituted arylene group having 6 to 13 carbon atoms; and R1 and R2 each independently represent a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms. R3 to R6 each independently represent any of hydrogen, halogen, a cyano group, a substituted or unsubstituted amino group, a substituted or unsubstituted hydroxyl group, a substituted or unsubstituted mercapto group, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 13 carbon atoms, and a substituted or unsubstituted heteroaryl group having 3 to 12 carbon atoms.

  提供了一种具有高可靠性的新型有机金属配合物。这种有机金属配合物包括铱和配体与铱配位。配体是二戊酰丙酮配体和包括苯基与烷基键合并与吡啶环的5位键合的配体。在公式中，Ar代表具有6到13个碳原子的取代或未取代芳基基团；R1和R2分别独立地代表具有1到6个碳原子的取代或未取代烷基基团。R3到R6分别独立地代表氢、卤素、氰基、取代或未取代氨基、取代或未取代羟基、取代或未取代巯基、具有1到6个碳原子的取代或未取代烷基基团、具有6到13个碳原子的取代或未取代芳基基团以及具有3到12个碳原子的取代或未取代杂环基团中的任意一种。
• [EN] ORGANOMETALLIC COMPLEX, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2018109621A1

  公开（公告）日：2018-06-21

  A novel organometallic complex with high emission efficiency is provided. The organometallic complex, which is represented by General Formula (G1), includes iridium and a ligand including an aryl group including a cyano group at the 1-position of a benzimidazole skeleton and a phenyl group at the 2-position of the benzimidazole skeleton. (In the formula, Ar1 represents an aryl group having one or more substituents and 6 to 13 carbon atoms, and Arl includes at least one cyano group as the substituent. Each of R1 to R8 separately represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 13 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 12 carbon atoms, and a cyano group.)

  提供了一种具有高发射效率的新型有机金属配合物。该有机金属配合物由通用公式（G1）表示，包括铱和一种配体，其中该配体包括一个芳基团，在苯并咪唑骨架的1-位置带有一个氰基团和在苯并咪唑骨架的2-位置带有一个苯基团。（在公式中，Ar1代表具有一个或多个取代基和6到13个碳原子的芳基团，Arl至少包括一个氰基作为取代基。R1至R8中的每一个分别代表氢、具有1到6个碳原子的取代或未取代烷基基团、具有3到6个碳原子的取代或未取代环烷基基团、具有6到13个碳原子的取代或未取代芳基基团、具有3到12个碳原子的取代或未取代杂环芳基基团和一个氰基。）