2-ethyl-1,4-naphthalenediyl diacetate | 24168-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-ethyl-1,4-naphthalenediyl diacetate
• 英文别名: 1,4-diacetoxy-2-ethyl-naphthalene；(2-Aethyl-naphthalindiyl-(1.4))-diacetat；(2-Aethyl-naphthylen-(1.4))-diacetat；1,4-Diacetoxy-2-aethyl-naphthalin；(4-Acetyloxy-3-ethylnaphthalen-1-yl) acetate
• CAS: 24168-38-5
• 化学式: C₁₆H₁₆O₄
• 分子量: 272.301
• InChiKey: PWERJRGTPRIEBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-ethyl-1,4-naphthalenediyl diacetate 在 2,6-二甲基吡啶 、 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 、 对叔丁基邻苯二酚 作用下， 以 四氯化碳 、 氯仿 为溶剂， 生成 6,13-dimethyl-6,13-dihydro-pentacene-5,7,12,14-tetraone
  参考文献：
  名称：

  Storck,W.; Manecke,G., Chemische Berichte, 1969, vol. 102, p. 3584 - 3588

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-二羟基萘 在 chromium(VI) oxide 、 二硫化碳 、 氢氧化钾 、 三氯化铝 、 溶剂黄146 、 锌 作用下， 生成 2-ethyl-1,4-naphthalenediyl diacetate
  参考文献：
  名称：

  Sah, Recueil des Travaux Chimiques des Pays-Bas, 1940, vol. 59, p. 1029,1034

  摘要：

  DOI：

文献信息

• Naphthoquinones of the Vitamin K₁ Type of Structure
  作者：Louis F. Fieser、William P. Campbell、Edward M. Fry、Marshall D. Gates

  DOI：10.1021/ja01266a068

  日期：1939.11
• Substituted benzoquinones and process for their production
  申请人：MERCK &

  公开号：US02376984A1

  公开（公告）日：1945-05-29
• Synthesis and Cytotoxicity of 9‐Substituted Benzo[<i>de</i>]chromene‐7,8‐dione and 5‐Benzyl‐9‐substituted Benzo[<i>de</i>]chromene‐7,8‐dione
  作者：Shi‐Liang Huang、Yi Luo、Zhi‐Shu Huang、Xing‐Yuan Wang、Xian‐Zhang Bu、Pei‐Qing Liu、Lin Ma、Bing‐Fen Xie、Zong‐Chao Liu、Yue‐Ming Li、Albert S. C. Chan

  DOI：10.1080/00397910600764683

  日期：2006.9

  New Mansonone analogues of 9-substitued benzo[ de] chromene-7,8-dione 5b-e and 5-benzyl-9-substitued benzo[ de] chromene-7,8-dione 6a-e were prepared through a modified route. The first step involved a bulky base t-butylamine mediated regioselective deacetylation of 2-substituted-1,4-naphth-diyl diacetate, resulting in obtaining of monoacetate 4-acetate 2 in high yield. The mechanism of cyclization, debenzylation, and oxidation for the formation of 5a - e and 6a - e were discussed. The cytotoxicity of the prepared compounds 5 and 6 were comparable with naturally occurring Mansonone F.
• ALBEROLA, A.;GONZALEZ, NOGAL, A. M.;MARTINEZ, DE, ILARDUYA, J. A.;PULIDO,+, AN. QUIM. PUBL. REAL SOC. ESP. QUIM., 1982, 78, N 2, 175-179
  作者：ALBEROLA, A.、GONZALEZ, NOGAL, A. M.、MARTINEZ, DE, ILARDUYA, J. A.、PULIDO,+

  DOI：——

  日期：——
• RADICAL POLYMERIZATION CONTROL AGENT AND RADICAL POLYMERIZATION CONTROL METHOD
  申请人：Kawasaki Kasei Chemicals Ltd.

  公开号：US20210122692A1

  公开（公告）日：2021-04-29

  A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization. Thus, radical polymerization of the radical polymerizable compound is easily initiated without increasing the amount of a radical polymerization initiator. That is, the radical polymerization control agent of the present invention is a radical polymerization control agent which is a corn pound having an effect to inhibit radical polymerization of a radical polymerizable compound and which loses the radical polymerization inhibiting effect under irradiation with light rays containing light within a wavelength range of from 300 nm to 500 nm.