2-Phenyl-1-heptafluoropropyl-2-propene | 99930-47-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Phenyl-1-heptafluoropropyl-2-propene
• 英文别名: 4,4,5,5,6,6,6-heptafluorohex-1-en-2-ylbenzene
• CAS: 99930-47-9
• 化学式: C₁₂H₉F₇
• 分子量: 286.192
• InChiKey: OIMHREWONYBMAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2-phenyl-2-heptafluorobutyryloxy-1-heptafluoropropyl propane 生成 2-Phenyl-1-heptafluoropropyl-2-propene
  参考文献：
  名称：

  用双（七氟丁酰基）过氧化物对富含电子的烯烃进行七氟丙基化

  摘要：

  双（七氟丁酸）过氧化物与富电子烯烃反应，以良好的收率得到 C3F7CO2 和 C3F7 基团的加合物。过氧化物应该是将七氟丙基部分引入烯烃的有用试剂。

  DOI：

  10.1246/cl.1985.755

文献信息

• Method for manufacture of fluorine-containing aromatic derivatives
  申请人：Nippon Oils & Fats Company, Ltd.

  公开号：US04956123A1

  公开（公告）日：1990-09-11

  Fluorine-containing aromatic derivatives are produced by the reaction of di(haloacyl)peroxide represented by the general formula: ##STR1## (wherein X stands for a fluorine, chlorine, or hydrogen atom and n for an integer of the value of 1 to 10) with aromatic unsaturated monomers represented by the general formula: ##STR2## (wherein Y stands for hydrogen atom, methyl, ethyl, propyl, acetyl, propionyl, acetyloxy, propionyloxy, methoxy, ethoxy, propoxy, vinyl, isopropenyl, or nitro group, or a halogen atom, R.sup.1 for hydrogen atom, methyl, ethyl, propyl, or butyl group, R.sup.2 for hydrogen atom, methyl or phenyl group, and m for an integer of the value of 1 to 5).

  含氟芳香衍生物是通过以下反应产生的：将通式表示为：##STR1##（其中X代表氟、氯或氢原子，n为1至10的整数）的二（卤代酰）过氧化物与通式表示为：##STR2##（其中Y代表氢原子、甲基、乙基、丙基、乙酰、丙酰、乙酰氧、丙酰氧、甲氧基、乙氧基、丙氧基、乙烯基、异丙烯基、或硝基基团，或卤原子，R1代表氢原子、甲基、乙基、丙基或丁基基团，R2代表氢原子、甲基或苯基团，m为1至5的整数）。
• Culture vessel
  申请人：Menicon Co., Ltd.

  公开号：EP0890636A1

  公开（公告）日：1999-01-13

  A culture vessel wherein at least a part of the vessel is made of a gas permeable plastic material. In accordance with the present invention, it is provided the culture vessel which can be constantly and sufficiently supplied with a gas such as oxygen necessary for metabolism of cells without an oxygenator, and the like, and which is not contamined with bacteria and is easily transported.

  一种培养容器，其中至少有一部分是由可渗透气体的塑料材料制成的。根据本发明，所提供的培养容器可持续、充分地供应细胞新陈代谢所需的氧气等气体，无需增氧机等设备，而且不会受到细菌污染，便于运输。
• PROCESS FOR PRODUCING CONTACT LENS WITH HYDROPHILIC SURFACE AND CONTACT LENS OBTAINED THEREBY
  申请人：MENICON CO., LTD.

  公开号：EP0892297A1

  公开（公告）日：1999-01-20

  A process for producing a contact lens having a hydrophilic surface comprising subjecting a contact lens material comprising a copolymer prepared by copolymerizing a monomer mixture containing a polymerizable monomer (A) which is at least one member selected from a sugar ketal-containing (meth)acrylate and a sugar glycerol ketal-containing (meth)acrylate, and a polymerizable monomer (B) which is copolymerizable with the polymerizable monomer (A) to acid treatment, wherein the polymerizable monomer (B) contains a hydrophobic monomer which is at least one member selected from a silicon-containing monomer, a fluorine-containing monomer and a silicon- and fluorine-containing monomer, and a contact lens which has high oxygen permeability and of which surface shows stably excellent hydrophilic property and which is excellent in deposit resistance at the same time.

  一种生产具有亲水性表面的隐形眼镜的工艺，包括将隐形眼镜材料进行酸处理，该隐形眼镜材料包含通过共聚单体混合物制备的共聚物，该单体混合物包含可聚合单体(A)和可聚合单体(B)，可聚合单体(A)是至少一种选自含糖酮基(甲基)丙烯酸酯和含糖甘油酮基(甲基)丙烯酸酯的成员，可聚合单体(B)可与可聚合单体(A)共聚、其中，可聚合单体（B）含有一种疏水性单体，该疏水性单体至少选自含硅、含氟和含硅、含氟单体中的一种。
• YOSHIDA, MASATO;MORIYA, KOJI;SAWADA, HEIDEO;KOBAYASHI, MICHIO, CHEM. LETT., 1985, N 6, 755-758
  作者：YOSHIDA, MASATO、MORIYA, KOJI、SAWADA, HEIDEO、KOBAYASHI, MICHIO

  DOI：——

  日期：——
• US4956123A
  申请人：——

  公开号：US4956123A

  公开（公告）日：1990-09-11