1,2-bis(3,4-dimethylphenyl)diazene 1-oxide | 67666-02-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(3,4-dimethylphenyl)diazene 1-oxide
• 英文别名: Diazene, bis(3,4-dimethylphenyl)-, 1-oxide；(3,4-dimethylphenyl)-(3,4-dimethylphenyl)imino-oxidoazanium
• CAS: 67666-02-8
• 化学式: C₁₆H₁₈N₂O
• 分子量: 254.332
• InChiKey: NVDICYFEQBBCOH-UHFFFAOYSA-N

物化性质

• 沸点：
  422.8±55.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  41.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-硝基邻二甲苯 在 水 、 potassium hydroxide 作用下， 以 1,4-二氧六环 为溶剂， 20.0 ℃ 、100.0 kPa 条件下， 生成 1,2-bis(3,4-dimethylphenyl)diazene 1-oxide
  参考文献：
  名称：

  利用羟基石墨碳氮化物光催化从水中提取氢原子进行氢偶联反应

  摘要：

  使用水作为氢供体对于氢原子转移反应非常具有挑战性。与gCN相比，表面羟基化石墨氮化碳（gCN−OH）在可见光照射下表现出水中H−O键的活化，从而使水成为氢供体，进行涉及氢原子转移（HAT）步骤和水氧化成H 2 O 2 。

  DOI：

  10.1002/anie.202204256

文献信息

• Efficient Solar-Driven Hydrogen Transfer by Bismuth-Based Photocatalyst with Engineered Basic Sites
  作者：Yitao Dai、Chao Li、Yanbin Shen、Shujie Zhu、Mathias S. Hvid、Lai-Chin Wu、Jørgen Skibsted、Yongwang Li、J. W. Hans Niemantsverdriet、Flemming Besenbacher、Nina Lock、Ren Su

  DOI：10.1021/jacs.8b09796

  日期：2018.12.5

  Photocatalytic organic conversions involving a hydrogen transfer (HT) step have attracted much attention, but the efficiency and selectivity under visible light irradiation still needs to be significantly enhanced. Here we have developed a noble metal-free, basic-site engineered bismuth oxybromide [Bi24O31Br10(OH)(delta)] that can accelerate the photocatalytic HT step in both reduction and oxidation reactions, i.e., nitrobenzene to azo/azoxybenzene, quinones to quinols, thiones to thiols, and alcohols to ketones under visible light irradiation and ambient conditions. Remarkably, quantum efficiencies of 42% and 32% for the nitrobenzene reduction can be reached under 410 and 450 nm irradiation, respectively. The Bi24O31Br10(OH)(delta) photocatalyst also exhibits excellent performance in up-scaling and stability under visible light and even solar irradiation, revealing economic potential for industrial applications.
• US4168279A
  申请人：——

  公开号：US4168279A

  公开（公告）日：1979-09-18
• Photocatalytic Abstraction of Hydrogen Atoms from Water Using Hydroxylated Graphitic Carbon Nitride for Hydrogenative Coupling Reactions
  作者：Dongsheng Zhang、Pengju Ren、Wuwen Liu、Yaru Li、Sofia Salli、Feiyu Han、Wei Qiao、Yu Liu、Yingzhu Fan、Yi Cui、Yanbin Shen、Emma Richards、Xiaodong Wen、Mark H. Rummeli、Yongwang Li、Flemming Besenbacher、Hans Niemantsverdriet、Tingbin Lim、Ren Su

  DOI：10.1002/anie.202204256

  日期：2022.6.13

  Using water as hydrogen donor is very challenging for hydrogen atom transfer reaction. Compared with gCN, the surface hydroxylated graphitic carbon nitride (gCN−OH) shows the activation of H−O bonds in water under visible light irradiation, thus rendering water as hydrogen donor for multiple reductions involving a hydrogen atom transfer (HAT) step and the oxidation of water to H2O2.

  使用水作为氢供体对于氢原子转移反应非常具有挑战性。与gCN相比，表面羟基化石墨氮化碳（gCN−OH）在可见光照射下表现出水中H−O键的活化，从而使水成为氢供体，进行涉及氢原子转移（HAT）步骤和水氧化成H 2 O 2 。