N-(1,10-phenanthrolin-5-yl)-N'-(3-trimethoxysilylpropyl)thiourea | 909109-37-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: N-(1,10-phenanthrolin-5-yl)-N'-(3-trimethoxysilylpropyl)thiourea
• 英文别名: 1-(1,10-Phenanthrolin-5-yl)-3-(3-trimethoxysilylpropyl)thiourea；1-(1,10-phenanthrolin-5-yl)-3-(3-trimethoxysilylpropyl)thiourea
• CAS: 909109-37-1
• 化学式: C₁₉H₂₄N₄O₃SSi
• 分子量: 416.576
• InChiKey: LKYVVOYJECEAAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  28
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  110
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N-(1,10-phenanthrolin-5-yl)-N'-(3-trimethoxysilylpropyl)thiourea 、 [Ru(bipy)2(phenNCS)]Cl2 以 甲醇 、 水 为溶剂， 生成 [Ru(bipy)2(phenNHCSNHC3H6Si(OMe)3)]Cl2
  参考文献：
  名称：

  Organic-inorganic hybrids in the system ruthenium tris(diimine) complexes-silica

  摘要：

  Organic-inorganic composites in which ruthenium(II) complexes are covalently bound to the silicate matrix were prepared by the sol-gel method. The physicomechanical and optical properties of the monolithic samples obtained were studied.

  DOI：

  10.1134/s1070427207030032
• 作为产物：
  描述：

  1,10-菲罗啉-5-氨基 在 sodium acetate 作用下， 以 二氯甲烷 、 N,N-二甲基乙酰胺 、 水 、 丙酮 、 正戊烷 为溶剂， 反应 0.25h， 生成 N-(1,10-phenanthrolin-5-yl)-N'-(3-trimethoxysilylpropyl)thiourea
  参考文献：
  名称：

  Synthesis of 5-isothiocyanato-1,10-phenanthroline

  摘要：

  Reduction of 5-nitro-1,10-phenanthroline with hydrogen over Pd/C, followed by the treatment of 1,10-phenanthrolin-5-amine with thiophosgene in the presence of sodium acetate, gave 5-isothiocyanato-1,10-phenanthroline which is a thermally stable highly reactive ligand capable of quantitatively forming covalently bonded nanohybrid structures in a system transition metal complex-silica under mild conditions.

  DOI：

  10.1134/s1070428006040129

文献信息

• Organic-inorganic hybrids in the system ruthenium tris(diimine) complexes-silica
  作者：N. N. Khimich、A. V. Zdravkov、M. A. Aleksashkina、L. F. Chepik

  DOI：10.1134/s1070427207030032

  日期：2007.3

  Organic-inorganic composites in which ruthenium(II) complexes are covalently bound to the silicate matrix were prepared by the sol-gel method. The physicomechanical and optical properties of the monolithic samples obtained were studied.
• Synthesis of 5-isothiocyanato-1,10-phenanthroline
  作者：N. N. Khimich、N. P. Obrezkov、L. A. Koptelova

  DOI：10.1134/s1070428006040129

  日期：2006.4

  Reduction of 5-nitro-1,10-phenanthroline with hydrogen over Pd/C, followed by the treatment of 1,10-phenanthrolin-5-amine with thiophosgene in the presence of sodium acetate, gave 5-isothiocyanato-1,10-phenanthroline which is a thermally stable highly reactive ligand capable of quantitatively forming covalently bonded nanohybrid structures in a system transition metal complex-silica under mild conditions.