perfluorodimorpholinoethane | 117402-36-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: perfluorodimorpholinoethane
• 英文别名: 4,4'-(1,1,2,2-Tetrafluoroethane-1,2-diyl)bis(octafluoromorpholine)；2,2,3,3,5,5,6,6-octafluoro-4-[1,1,2,2-tetrafluoro-2-(2,2,3,3,5,5,6,6-octafluoromorpholin-4-yl)ethyl]morpholine
• CAS: 117402-36-5
• 化学式: C₁₀F₂₀N₂O₂
• 分子量: 560.09
• InChiKey: UXMGLGDVLJBPIH-UHFFFAOYSA-N

物化性质

• 熔点：
  50.5-51.5 °C
• 沸点：
  171.5-172.5 °C
• 密度：
  1.95±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  34
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  24

反应信息

• 作为反应物：
  描述：

  perfluorodimorpholinoethane 、 硫酸 、 三氧化硫 以12%的产率得到
  参考文献：
  名称：

  HAYASHI, EIJI;ABE, TAKASHI;NAGASE, SHUNJI, CHEM. EXPRESS., 3,(1988) N, C. 359-362

  摘要：

  DOI：
• 作为产物：
  描述：

  4,4'-(1,2-乙亚基)双吗啉 在 氢氟酸 作用下， 以28%的产率得到perfluorodimorpholinoethane
  参考文献：
  名称：

  On the electrochemical fluorination of derivatives of morpholine and piperidine

  摘要：

  Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.

  DOI：

  10.1016/s0022-1139(00)80306-1

文献信息

• HAYASHI, EIJI;ABE, TAKASHI;NAGASE, SHUNJI, CHEM. EXPRESS., 3,(1988) N, C. 359-362
  作者：HAYASHI, EIJI、ABE, TAKASHI、NAGASE, SHUNJI

  DOI：——

  日期：——
• NAYASHI, EIJI;ABE, TAKASHI;BABA, HAJINE;NAGASE, SHUNJI, CHEM. EXPRESS., 3,(1988) N, C. 191-194
  作者：NAYASHI, EIJI、ABE, TAKASHI、BABA, HAJINE、NAGASE, SHUNJI

  DOI：——

  日期：——
• HAYASHI, EIJI;ABE, TAKASHI;NAGASE, SHUNJI, NAGOYA KOGE GIDZYUTSU SIKEHNDZE XOKOKU, 37,(1988) N 6, S. 176-181
  作者：HAYASHI, EIJI、ABE, TAKASHI、NAGASE, SHUNJI

  DOI：——

  日期：——
• On the electrochemical fluorination of derivatives of morpholine and piperidine
  作者：H. Meinert、R. Fackler、J. Mader、P. Reuter、W. Rohlke

  DOI：10.1016/s0022-1139(00)80306-1

  日期：1991.1

  Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.