4-[2-(Ethenyloxy)ethoxy]phenol | 127396-01-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-[2-(Ethenyloxy)ethoxy]phenol
• 英文别名: 4-(2-ethenoxyethoxy)phenol
• CAS: 127396-01-4
• 化学式: C₁₀H₁₂O₃
• 分子量: 180.203
• InChiKey: PHYHXTWPWNCBQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-[2-(Ethenyloxy)ethoxy]phenol 、 4-(4-(vinyloxy)butoxy)benzoic acid 在 4-吡咯烷基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 120.0h， 生成 4-<4-(Vinyloxy)butyloxy>-4-<2-(vinyloxy)ethyloxy>phenylbenzoate
  参考文献：
  名称：

  Synthesis and Photopolymerization of Bifunctjonal Liquid Crystalline Vinyl Ether Monomers

  摘要：

  Highly ordered densely crosslinked liquid crystalline poly(vinyl ether) films have been prepared by in situ photopolymerization of oriented bifunctional mesogenic vinyl ether monomers. Orientation was achieved by a simple surface treatment, using a unidirectionally rubbed polyimide film. Polymerization from various monomer phases resulted in LC polymer network films with different molecular organizations. The films were analyzed with small-angle x-ray scattering, polarized light microscopy and infrared-dichroism measurements. It was shown that films with nematic, smectic A and smectic B structures were obtained, the latter having a very high degree of orientation.

  DOI：

  10.1080/10587259408037773
• 作为产物：
  描述：

  2-(vinyloxy)ethyl 4-methylbenzenesulfonate 、 对苯二酚 在 氢氧化钾 、 sodium dithionite 作用下， 以 乙醇 为溶剂， 以38%的产率得到4-[2-(Ethenyloxy)ethoxy]phenol
  参考文献：
  名称：

  Synthesis and Photopolymerization of Bifunctjonal Liquid Crystalline Vinyl Ether Monomers

  摘要：

  Highly ordered densely crosslinked liquid crystalline poly(vinyl ether) films have been prepared by in situ photopolymerization of oriented bifunctional mesogenic vinyl ether monomers. Orientation was achieved by a simple surface treatment, using a unidirectionally rubbed polyimide film. Polymerization from various monomer phases resulted in LC polymer network films with different molecular organizations. The films were analyzed with small-angle x-ray scattering, polarized light microscopy and infrared-dichroism measurements. It was shown that films with nematic, smectic A and smectic B structures were obtained, the latter having a very high degree of orientation.

  DOI：

  10.1080/10587259408037773

文献信息

• Main chain type liquid crystal polyester, liquid crystalline composition, method for producing liquid crystal film, optical film and display
  申请人：——

  公开号：US20040171788A1

  公开（公告）日：2004-09-02

  Provided is a main chain type liquid crystal polyester which comprises at least two units selected from an aromatic diol unit, an aromatic dicarboxylic acid unit, and an aromatic hydroxycarboxylic acid unit as essential units and a structural unit having a cationically polymerizable unit in at least one of the terminal ends. The main chain type liquid crystalline polyester, when used as an optical material, is excellent in the capability of retaining a liquid crystal orientation having been aligned and fixed under practical service conditions and exhibits an excellent mechanical strength.

  提供的是一种主链型液晶聚酯，其中至少包括两种选自芳香二元醇单元、芳香二羧酸单元和芳香羟基羧酸单元的基本单元，以及至少在末端之一具有阳离子聚合单元的结构单元。当用作光学材料时，这种主链型液晶聚酯在实际使用条件下具有保持已对齐和固定的液晶取向能力，并表现出优异的机械强度。
• MAIN CHAIN TYPE LIQUID CRYSTAL POLYESTER LIQUID CRYSTALLINE COMPOSITION METHOD FOR PRODUCING LIQUID CRYSTAL FILM OPTICAL FILM AND DISPLAY
  申请人：Nippon Oil Corporation

  公开号：EP1422255A1

  公开（公告）日：2004-05-26

  Provided is a main chain type liquid crystal polyester which comprises at least two units selected from an aromatic diol unit, an aromatic dicarboxylic acid unit, and an aromatic hydroxycarboxylic acid unit as essential units and a structural unit having a cationically polymerizable unit in at least one of the terminal ends. The main chain type liquid crystalline polyester, when used as an optical material, is excellent in the capability of retaining a liquid crystal orientation having been aligned and fixed under practical service conditions and exhibits an excellent mechanical strength.

  本发明提供了一种主链型液晶聚酯，它包括至少两个选自芳香族二元醇单元、芳香族二羧酸单元和芳香族羟基羧酸单元的基本单元，以及至少一个末端具有阳离子可聚合单元的结构单元。这种主链型液晶聚酯用作光学材料时，在实际使用条件下可保持液晶取向的一致性和固定性，并表现出优异的机械强度。
• LIQUID-CRYSTALLINE COMPOSITION WITH IMPROVED ADHESION, LIQUID-CRYSTAL FILM COMPRISING THE COMPOSITION, AND LIQUID-CRYSTAL DISPLAY ELEMENT EMPLOYING THE FILM
  申请人：Nippon Oil Corporation

  公开号：EP2006351A2

  公开（公告）日：2008-12-24

  The present invention provides a liquid crystal film with improved adhesivity to a tacky adhesive or an adhesive, formed from a liquid crystalline composition comprising a specific (meth)acrylic compound having an oxetane group and a liquid crystalline compound having an oxetane group.

  本发明提供了一种对粘性粘合剂或粘合剂具有更好粘合性的液晶膜，该液晶膜由液晶组合物形成，该液晶组合物包括具有氧杂环丁烷基团的特定（甲基）丙烯酸化合物和具有氧杂环丁烷基团的液晶化合物。
• Liquid Crystalline Composition with Improved Adhesivity, Liquid Crystal Film Comprising the Composition, and Liquid Crystal Display Device Equipped with the Film
  申请人：Seki Takashi

  公开号：US20090208673A1

  公开（公告）日：2009-08-20

  The present invention provides a liquid crystal film with improved adhesivity to a tacky adhesive or an adhesive, formed from a liquid crystalline composition comprising a specific (meth)acrylic compound having an oxetane group and a liquid crystalline compound having an oxetane group.
• US6894141B2
  申请人：——

  公开号：US6894141B2

  公开（公告）日：2005-05-17