diphenylphosphinoethylamine | 41391-96-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenylphosphinoethylamine
• 英文别名: Aethylamino-diphenylphosphin；Diphenylphosphino-aethylamin；Diphenylphosphinoethylamin；N-diphenylphosphanylethanamine
• CAS: 41391-96-2
• 化学式: C₁₄H₁₆NP
• 分子量: 229.261
• InChiKey: GUUCXHCGYGTBLR-UHFFFAOYSA-N

物化性质

• 沸点：
  332.4±25.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  diphenylphosphinoethylamine 、 正丁基锂 以29%的产率得到
  参考文献：
  名称：

  KEAT, R.;MURRAY, L.;RYCROFT, D. S., J. CHEM. SOC. DALTON TRANS., 1982, N 8, 1503-1508

  摘要：

  DOI：

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• LIGAND BASED CHROMIUM CATALYST AND APPLICATION IN CATALYZING ETHYLENE OLIGOMERIZATION
  申请人：CHINA PETROLEUM & CHEMICAL CORPORATION

  公开号：US20170106358A1

  公开（公告）日：2017-04-20

  A ligand based chromium catalyst and application in catalyzing ethylene oligomerization are disclosed. The chromium catalyst is formed by a chromium compound and an organic ligand containing P and/or N. The substituents on N and P of the ligand can be replaced, whereby selective ethylene trimerization and tetramerization can be realized so as to produce 1-hexene and 1-octene at the same time.

  揭示了一种基于配体的铬催化剂及其在催化乙烯寡聚中的应用。该铬催化剂由铬化合物和含有P和/或N的有机配体形成。配体上的N和P的取代基可以被替换，从而可以实现选择性的乙烯三聚和四聚反应，同时产生1-己烯和1-辛烯。
• Synthesis and conformational studies of (diphenylphosphinoamino)-cyclodiphosph(III)azanes
  作者：Rodney Keat、Liam Murray、David S. Rycroft

  DOI：10.1039/dt9820001503

  日期：——

  hosph(III)azanes, [(Ph2P)RNPNBut]2[R = Me or Et (cis- and trans-isomers); R = Pri or But(cis-isomers)], have been prepared by the reactions of N-lithiated alkyl-N-(diphenylphosphino) amines, N (PPh2)(R)(Li), with 2-cis-4-dichloro-1,3-di-t-butylcyclodiphosph(III)azane, (ClPNBut)2, in benzene solution. Hydrogen-1, 13C and 31P n.m.r. spectroscopy show that these compounds are cyclodiphosph(III)azenes

  一系列2,4-双（二苯基膦基烷基氨基）-1,3-二叔丁基环二磷（III）氮烷，[（Ph 2 P）RNPNBu t ] 2 [R = Me或Et（顺式和反式异构体） ; R = Pr i或Bu t（顺式异构体）]，是通过N-烷基化的烷基-N-（二苯基膦基）胺N（PPh 2）（R）（Li）与2-顺式- 4-二氯-1,3-二叔丁基环二磷（III）氮烷（ClPNBu t）2在苯溶液中。氢1、13 C和31P NMR光谱表明，这些化合物是cyclodiphosph（III）azenes而不是亚磷（膦III）azenes，（PH 2 P）RNP NBU吨，在溶液中，和可变温度3升P NMR数据已启用的优选构象外-P要识别的-NP骨架。在的情况下，[（PH 2 P）RNPNBu吨] 2（R = PR我和BU吨）多于一种构象异构体可以在低于环境温度进行区分。
• New 4-substituted anthracyclinones and anthracycline glycosides and the process for preparing them
  申请人：FARMITALIA CARLO ERBA S.r.L.

  公开号：EP0366973A1

  公开（公告）日：1990-05-09

  4-substituted anthracyclinones of formula (I): wherein R represents a straight or branched alkyl, alkenyl or alkynyl group of up to 16 carbon atoms optionally substituted by (a) an aryl group which is unsubstituted or substituted by an inert group such as an alkyl, alkoxy or nitro group; (b) an alkoxy group; (c) a trialkylsilyl group, (d) an ester group or (e) an amido group, are intermediates in the preparation of antitumor anthracycline glycosides of formula (IX): wherein R is as defined above and R₁ is a hydrogen atom or a hydroxy group, and pharmaceutically acceptable salts thereof.

  式(I)的 4-取代的蒽环酮类化合物： 其中 R 代表最多 16 个碳原子的直链或支链烷基、烯基或炔基，可任选被以下基团取代：(a) 未被取代或被惰性基团如烷基、烷氧基或硝基取代的芳基；(b) 烷氧基；(c) 三烷基硅烷基；(d) 酯基或 (e) 氨基基： 其中 R 如上定义，R₁ 是氢原子或羟基，以及它们的药学上可接受的盐。
• Ligand based chromium catalyst and application in catalyzing ethylene oligomerization
  申请人：CHINA PETROLEUM & CHEMICAL CORPORATION

  公开号：US10179331B2

  公开（公告）日：2019-01-15

  A ligand based chromium catalyst and application in catalyzing ethylene oligomerization are disclosed. The chromium catalyst is formed by a chromium compound and an organic ligand containing P and/or N. The substituents on N and P of the ligand can be replaced, whereby selective ethylene trimerization and tetramerization can be realized so as to produce 1-hexene and 1-octene at the same time.

  本发明公开了一种基于配体的铬催化剂及其在催化乙烯低聚过程中的应用。该铬催化剂由铬化合物和含有 P 和/或 N 的有机配体组成，配体上 N 和 P 的取代基可以被替换，从而实现选择性乙烯三聚和四聚，以便同时生产 1-己烯和 1-辛烯。